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2017 | OriginalPaper | Buchkapitel

3. Robust Mesoporous Polymers Derived from Cross-Linked Block Polymer Precursors

verfasst von : Myungeun Seo

Erschienen in: Submicron Porous Materials

Verlag: Springer International Publishing

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Abstract

Well-defined mesoporous polymers whose pore size and structure are well controlled, are potentially useful for advanced applications including filtration, separation, and catalysis. Such porous polymers can be derived from microphase-separated block polymer precursors by the selective removal of sacrificial blocks. This chapter focuses on robust cross-linked mesoporous polymers with greatly improved pore stability produced by cross-linking of the matrix block in the precursor. The chapter surveys various approaches for synthesizing cross-linked block polymer precursors, examines mechanisms that can arrest transient morphologies using the competition between cross-linking and ordering kinetics, and discusses how the stability of the resulting mesopore structures can be enhanced by cross-linking.

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Titel: Robust Mesoporous Polymers Derived from Cross-Linked Block Polymer Precursors
verfasst von: Myungeun Seo
Verlag: Springer International Publishing
Buch: Submicron Porous Materials
Print ISBN: 978-3-319-53033-8

Electronic ISBN: 978-3-319-53035-2

Copyright-Jahr: 2017
DOI: https://doi.org/10.1007/978-3-319-53035-2_3

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