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Erschienen in: Metallurgical and Materials Transactions A 5/2015

01.05.2015

SDAS, Si and Cu Content, and the Size of Intermetallics in Al-Si-Cu-Mg-Fe Alloys

verfasst von: Tharmalingam Sivarupan, John Andrew Taylor, Carlos Horacio Cáceres

Erschienen in: Metallurgical and Materials Transactions A | Ausgabe 5/2015

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Abstract

Plates of Al-(a)Si-(b)Cu-Mg-(c)Fe alloys with varying content of (mass pct) Si (a = 3, 4.5, 7.5, 9, 10, or 11), Cu (b = 0, 1, or 4), and Fe (c = 0.2, 0.5 or 0.8) were cast in sand molds with a heavy chill at one end to ensure quasi-directional solidification over a wide range of Secondary Dendrite Arm Spacing (SDAS). Statistical analysis on the size of the β-Al5FeSi, α-Al8Fe2Si, or Al2Cu intermetallics on Backscattered Electron images showed that a high Si content reduced the size of the β platelets in alloys with up to 0.5 Fe content regardless of the SDAS, whereas at small SDAS the refining effect extended up to 0.8 Fe, and involved α-phase intermetallics which replaced the beta platelets at those concentrations. At low Si contents, a high Cu level appeared to have similar refining effects as increased Si, through the formation of α-phase particles in the post-eutectic stage which agglomerated with the Al2Cu intermetallics. A high content of Si appears to make the overall refining process less critical in terms of SDAS/cooling rate.

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Fußnoten
1
The level of Fe in these alloys (0.8 pct) was higher than that of the initial study described in Figure 1 (0.5 pct) and was carried out at a much larger (~50 µm) SDAS.
 
2
The reading of this excellent piece of work is marred by the use of an ordinal rather than the commonly used nominative phase identification scheme.
 
3
The electron-matter interaction depth[13] in pure Al, Si, Cu, and Fe for the 20 keV electrons is estimated to be 4.2, 4.7, 1.5, and 1.6 μm, respectively, although the effective BSE depth is far more less than these. Only X-ray signals (EDX/EDS) come from this much deeper region where as the backscattered electrons and secondary electrons come from the actual surface,[14,15] after the incident electron interaction, so the error due to under the surface detection seemed to be minor, especially considering the high density of the α-Al8Fe2Si and β-Al5Fe2Si phases (3695 and 3429 kg/m3, respectively).[16,17]
 
4
Ignoring the nature of the particles in favor of their size is consistent with the initial goal of this work, that of minimizing the deleterious effects of the intermetallics on the alloys ductility, which mostly are determined by particle size.[1,18,19] Actual identification of the intermetallic phases involved in the quantitative metallography was carried out as described in Appendix B.
 
5
The 0.8 Fe alloy at large SDAS is the case for some of the experiments of Reference 4.
 
6
Gorny et al.[8] also discussed superheat effects on the nature of the phases formed in Al-11 SiFe alloys using the results by Awano and Shimizu.[21]
 
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Metadaten
Titel
SDAS, Si and Cu Content, and the Size of Intermetallics in Al-Si-Cu-Mg-Fe Alloys
verfasst von
Tharmalingam Sivarupan
John Andrew Taylor
Carlos Horacio Cáceres
Publikationsdatum
01.05.2015
Verlag
Springer US
Erschienen in
Metallurgical and Materials Transactions A / Ausgabe 5/2015
Print ISSN: 1073-5623
Elektronische ISSN: 1543-1940
DOI
https://doi.org/10.1007/s11661-015-2808-5

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