Skip to main content
Fachgebiete
Automobil + Motoren Bauwesen + Immobilien Business IT + Informatik Elektrotechnik + Elektronik Energie + Nachhaltigkeit Finance + Banking Management + Führung Marketing + Vertrieb Maschinenbau + Werkstoffe Versicherung + Risiko
DE
EN
Bücher
Zeitschriften
Themenseiten
Organisationspsychologie Projektmanagement Marketing Smart Manufacturing
Weitere Formate
Podcasts Webinare Technik Webinare Wirtschaft Kongresse Veranstaltungskalender Awards
Jetzt Einzelzugang starten
Zugang für Unternehmen
Referenzkunden
SLX-Digitalkonferenz: Zukunftswerkstatt 2024

Mehr Umsatz mit Top-Kontakten

Am 7. Mai erfahren Sie, wie Vertriebsteams Leadgenerierung, Leadnurturing und Leadstrategien effizient steuern können.
Erweiterte Suche
Anmelden
nach oben
Journal of Sol-Gel Science and Technology
Erschienen in: Journal of Sol-Gel Science and Technology 3/2018

05.02.2018 | Original Paper: Sol-gel and hybrid materials for catalytic, photoelectrochemical and sensor applications

Selective catalytic reduction of NO x by CO over LaMnO3 nano perovskites prepared by microwave and ultrasound assisted sol–gel method

verfasst von: Seyed Ali Hosseini, Behrouz Mehri, Aligholi Niaei, Behrang Izadkhah, Consuelo Alvarez-Galvan, Jose G. Luis Fierro

Erschienen in: Journal of Sol-Gel Science and Technology | Ausgabe 3/2018

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config
loading …

Abstract

A series of LaMnO3 perovskites as catalysts for selective reduction of NO by CO were synthesized using microwave and ultrasound assisted sol-gel method. The catalysts were characterized by BET area measurements, Scanning Electron Microscopy (SEM), X-Ray diffraction (XRD) and X-ray Photoelectron Spectroscopy (XPS) techniques. XRD results showed revealed the orthorhobic crystalline structure and with very high purity. SEM analyses proved lower particle size for ultrasound (US) assisted synthesized LaMnO3. In addition, US assisted synthesized LaMnO3 presented higher surface area respect to other catalysts, synthesized by the other methods. Results revealed that the ultrasound assisted synthesized catalyst determines the lowest crystallite size, the highest surface area and the highest concentration of O-vacancies and, as a consequence, the highest catalytic activity.
Vorheriger Artikel Natural clay attapulgite as the raw material for synthesis of Al/Ti/Mg-containing mesoporous silicates with cubic, 3D hexagonal, and lamellar mesostructures
Nächster Artikel Screening trials for the encapsulation of laccase enzymatic extract in silica sol-gel

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Jetzt informieren
Literatur
1.
Khristova M, Petrović S, Terlecki-Baričević A, Mehandjiev D (2009) Catalytic reduction of NO by CO over Pd—doped Perovskite-type catalysts. Open Chem 7:857–863CrossRef
2.
Wang Y, Zhu A, Zhang Y, Au C, Yang X, Shi C (2008) Catalytic reduction of NO by CO over NiO/CeO2 catalyst in stoichiometric NO/CO and NO/CO/O2 reaction. Appl Catal B 81:141–149CrossRef
3.
Ciambelli P, Cimino S, Lasorella G, Lisi L, De Rossi S, Faticanti M, Minelli G, Porta P (2002) CO oxidation and methane combustion on LaAl1− xFexO3 perovskite solid solutions. Appl Catal B 37:231–241CrossRef
4.
Lian H, Jia M, Pan W, Li Y, Zhang W, Jiang D (2005) Gold-base catalysts supported on carbonate for low-temperature CO oxidation. Catal Commun 6:47–51CrossRef
5.
Royer S, Duprez D (2011) Catalytic oxidation of carbon monoxide over transition metal oxides. ChemCatChem 3:24–65CrossRef
6.
Allian AD, Takanabe K, Fujdala KL, Hao X, Truex TJ, Cai J, Buda C, Neurock M, Iglesia E (2011) Chemisorption of CO and mechanism of CO oxidation on supported platinum nanoclusters. J Am Chem Soc 133:4498–4517CrossRef
7.
Daly F, Schmitt J, Sturm E (1986) Molybdenum-support interaction and its effect on nitric oxide chemisorption and temperature-programmed desorption. J Catal 97:248–251CrossRef
8.
Mizuno N, Misono M (1998) Heterogeneous catalysis. Chem Rev 98:199–218CrossRef
9.
Pena M, Fierro J (2001) Chemical structures and performance of perovskite oxides. Chem Rev 101:1981–2018CrossRef
10.
Tejuca LG, Fierro J (2000) Properties and applications of perovskite-type oxides. CRC Press, New York
11.
Russo U, Nodari L, Faticanti M, Kuncser V, Filoti G (2005) Local interactions and electronic phenomena in substituted LaFeO3 perovskites. Solid State Ion 176:97–102CrossRef
12.
Bernard C, Dauzet G, Mathieu F, Durand B, Puech-Costes E (2005) Optimization of the hydrothermal synthesis of La0.7Sr 0.3MnO3+ δ using an original optimal experimental design. Mater Lett 59:2615–2620CrossRef
13.
Teraoka Y, Nii H, Kagawa S, Jansson K, Nygren M (2005) Influence of the simultaneous substitution of Cu and Ru in the perovskite-type (La, Sr) MO3 (M = Al, Mn, Fe, Co) on the catalytic activity for CO oxidation and CO–NO reactions. Appl Catal A 194:35–41
14.
Giannakas A, Leontiou A, Ladavos A, Pomonis P (2006) Characterization and catalytic investigation of NO + CO reaction on perovskites of the general formula Lax M1− x FeO3 (M = Sr and/or Ce) prepared via a reverse micelles microemulsion route. Appl Catal A 309:254–262CrossRef
15.
Nandi M, Sarkar K, Seikh M, Bhaumik A (2011) Mesoporous lanthanum–manganese oxides with nanoscale periodicity, high surface area and ferromagnetic property. Micro Mesopor Mater 143:392–397CrossRef
16.
Shi D, Hu R, Zhou Q, Yang L (2016) Catalytic activities of supported perovskite promoter catalysts La2NiMnO6–CuCl2/γ-Al2O3 and La1.7K0.3NiMnO6–CuCl2/γ-Al2O3 for ethane oxychlorination. Chem Eng J 288:588–595CrossRef
17.
Giannakas AE, Ladavos AK, Pomonis PJ (2004) Preparation, characterization and investigation of catalytic activity for NO + CO reaction of LaMnO3 and LaFeO3 perovskites prepared via microemulsion method. Appl Catal B 49:147–158CrossRef
18.
Aman D, Zaki T, Mikhail S, Selim S (2011) Synthesis of a perovskite LaNiO3 nanocatalyst at a low temperature using single reverse microemulsion. Catal Today 164:209–213CrossRef
19.
Giroir-Fendler A, Alves-Fortunato M, Richard M, Wang C, Díaz JA, Gil S, Zhang C, Can F, Bion N, Guo Y (2016) Synthesis of oxide supported LaMnO3 perovskites to enhance yields in toluene combustion. Appl Catal B 180:29–37CrossRef
20.
Tsuji M, Hashimoto M, Nishizawa Y, Kubokawa M, Tsuji T (2005) Microwave‐assisted synthesis of metallic nanostructures in solution. Chem Eur J 11:440–452CrossRef
21.
22.
Mason T, Lorimer J (2002) Applied sonochemistry: Uses of power ultrasound in chemistry. Wiley-VCH verlag GmbH, WeinheimCrossRef
23.
Suslick KS, Hammerton DA, Cline RE (1986) Sonochemical hot spot. J Am Chem Soc 108:5641–5642CrossRef
24.
Suslick K, Fang M, Hyeon T, Mdleleni M (1999) Applications of sonochemistry to materials synthesis. In: Crum LA et al. (eds) Sonochemistry and sonoluminescence, Springer, New York, pp 291–320
25.
Mohideen MI, Allan PK, Chapman KW, Hriljac JA, Morris RE (2014) Ultrasound-driven preparation and pair distribution function-assisted structure solution of a copper-based layered coordination polymer. Dalton Trans 43:10438–10442CrossRef
26.
Suslick KS, Hyeon T, Fang M (1996) Nanostructured materials generated by high-intensity ultrasound: sonochemical synthesis and catalytic studies. Chem Mater 8:2172–2179CrossRef
27.
Suslick K, Doktycz S (1990) Effect of ultrasound on surfaces and solids. Adv Sonochem 1:197–230
28.
Ahluwalia V, Kidwai M (2004) Ultrasound assisted green synthesis. In: Javed Iqbal (ed) New trends in green chemistry. Springer, New York, NY
29.
Bang JH, Suslick KS (2010) Applications of ultrasound to the synthesis of nanostructured materials. Adv Mater 22:1039–1059CrossRef
30.
Ayas N, Yilmaz O (2015) Catalytic esterification and transesterification reaction of high acidic value waste oil by microwave heating. Environ Prog Sustain Energy 34:575–581CrossRef
31.
Kingman S (2006) Recent developments in microwave processing of minerals. Int Mater Rev 51:1–12CrossRef
32.
Zhang H, Ding J, Zhao Z (2012) Microwave assisted esterification of acidified oil from waste cooking oil by CERP/PES catalytic membrane for biodiesel production. Bioresour Technol 123:72–77CrossRef
33.
Azcan N, Danisman A (2008) Microwave assisted transesterification of rapeseed oil. Fuel 87:1781–1788CrossRef
34.
Hernando J, Leton P, Matia MP, Novella J, Alvarez-Builla J (2007) Biodiesel and FAME synthesis assisted by microwaves: homogeneous batch and flow processes. Fuel 86:1641–1644CrossRef
35.
Prado-Gonjal J, Gutiérrez-Seijas J, Ansorregui IH, Morán E, Terry I, Schmidt R (2016) The role of defects in microwave and conventionally synthesized LaCoO3 perovskite. J Eur Ceram Soc 36:1197–1206CrossRef
36.
Arefi Oskoui S, Niaei A, Tseng HH, Salari D, Izadkhah B, Hosseini SA (2013) Modeling preparation condition and composition–activity relationship of perovskite-type LaxSr 1–x FeyCo1–yO3 nano catalyst. ACS Comb Sci 15:609–621CrossRef
37.
Alifanti M, Kirchnerova J, Delmon B (2003) Effect of substitution by cerium on the activity of LaMnO3 perovskite in methane combustion. Appl Catal A 245:231–243CrossRef
38.
Celorrio V, Calvillo L, Dann E, Granozzi G, Aguadero A, Kramer D, Russell AE, Fermín DJ (2016) Oxygen reduction reaction at LaxCa1−xMnO3 nanostructures: interplay between A-site segregation and B-site valency. Catal Sci Technol 6:7231–7238CrossRef
Metadaten
Titel
Selective catalytic reduction of NO x by CO over LaMnO3 nano perovskites prepared by microwave and ultrasound assisted sol–gel method
verfasst von
Seyed Ali Hosseini
Behrouz Mehri
Aligholi Niaei
Behrang Izadkhah
Consuelo Alvarez-Galvan
Jose G. Luis Fierro
Publikationsdatum
05.02.2018
Verlag
Springer US
Erschienen in
Journal of Sol-Gel Science and Technology / Ausgabe 3/2018
Print ISSN: 0928-0707
Elektronische ISSN: 1573-4846
DOI
https://doi.org/10.1007/s10971-017-4568-8

Weitere Artikel der Ausgabe 3/2018

Journal of Sol-Gel Science and Technology 3/2018 Zur Ausgabe

Original Paper: Sol-gel and hybrid materials for energy, environment and building applications

Improving the thermoelectric performance and thermal stability of Ca3Co4O9 + δ ceramics by sintering in oxygen atmosphere

Original Paper: Nano-structured materials (particles, fibers, colloids, composites, etc.)

Formation mechanism of the rutile-phase of TiO2 nanorods on Ti foil substrate by gel-calcination method

Original Paper: Sol-gel and hybrid materials for dielectric, electronic, magnetic and ferroelectric applications

Influence of erbium on the structural, optical and magnetic properties of sol–gel Ce: YIG films

Original Paper: Nano-structured materials (particles, fibers, colloids, composites, etc.)

Natural clay attapulgite as the raw material for synthesis of Al/Ti/Mg-containing mesoporous silicates with cubic, 3D hexagonal, and lamellar mesostructures

Original Paper: Functional coatings, thin films and membranes (including deposition techniques)

Carbonaceous nickel oxide composite films with homogenously dispersed metallic Ni nanoparticles by a facile sol–gel method

Original Paper: Sol-gel and hybrid materials for catalytic, photoelectrochemical and sensor applications

Preparation and characterization of the system NiMn2O4/TiO2 by sol–gel: application to the photodegradation of benzamide under visible light

Premium Partner

    Marktübersichten

    Die im Laufe eines Jahres in der „adhäsion“ veröffentlichten Marktübersichten helfen Anwendern verschiedenster Branchen, sich einen gezielten Überblick über Lieferantenangebote zu verschaffen. 

    Zur Marktübersicht
    Bildnachweise