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Journal of Nanoparticle Research
Erschienen in: Journal of Nanoparticle Research 8/2014

01.08.2014 | Research Paper

Selective synthesis of clinoatacamite Cu2(OH)3Cl and tenorite CuO nanoparticles by pH control

verfasst von: Christian Engelbrekt, Phillip Malcho, Jonas Andersen, Lijuan Zhang, Kenny Ståhl, Bin Li, Jun Hu, Jingdong Zhang

Erschienen in: Journal of Nanoparticle Research | Ausgabe 8/2014

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Abstract

Copper nanomaterials play a role as catalysts in sustainable energy technology and sensor devices. We present a one-pot synthesis for the selective preparation of phase-pure clinoatacamite (Cu2(OH)3Cl) and cupric oxide (CuO) nanoparticles by controlling the pH of the solution. The effect of pH on the phase of the product was systematically investigated utilizing 2-(N-morpholino)ethanesulfonic acid (MES) buffer. Here, the MES buffer was crucial for the synthesis. It not only allowed for selective synthesis by controlling pH but also guided the morphology of the CuO nanoparticles. In addition, it directed the growth of Cu2(OH)3Cl to provide pure clinoatacamite without the presence of related polymorphs. The products were characterized by transmission electron microscopy, infrared spectroscopy, ultraviolet–visible light spectroscopy, X-ray powder diffraction (XRD), scanning transmission X-ray microscopy and atomic force microscopy. Infrared spectroscopy was essential for characterization of closely related polymorphs of Cu2(OH)3Cl indistinguishable by XRD. A plausible mechanism has been proposed and discussed for the formation of the CuO and Cu2(OH)3Cl nanostructures.
Vorheriger Artikel Synthesis and application of non-agglomerated ITO nanocrystals via pyrolysis of indium–tin stearate without using additional organic solvents
Nächster Artikel Length reduction of multi-walled carbon nanotubes via high energy ultrasonication and its effect on their dispersibility

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Metadaten
Titel
Selective synthesis of clinoatacamite Cu2(OH)3Cl and tenorite CuO nanoparticles by pH control
verfasst von
Christian Engelbrekt
Phillip Malcho
Jonas Andersen
Lijuan Zhang
Kenny Ståhl
Bin Li
Jun Hu
Jingdong Zhang
Publikationsdatum
01.08.2014
Verlag
Springer Netherlands
Erschienen in
Journal of Nanoparticle Research / Ausgabe 8/2014
Print ISSN: 1388-0764
Elektronische ISSN: 1572-896X
DOI
https://doi.org/10.1007/s11051-014-2562-4

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