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Erschienen in: Cellulose 10/2020

22.04.2020 | Original Research

Self-assembly of phosphonate-metal complex for superhydrophobic and durable flame-retardant polyester–cotton fabrics

verfasst von: Longxiang Liu, Ying Pan, Yuyu Zhao, Wei Cai, Zhou Gui, Yuan Hu, Xin Wang

Erschienen in: Cellulose | Ausgabe 10/2020

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Abstract

Poor washing durability still poses a big challenge to the practical applications of flame-retardant fabrics. Herein, a facile and eco-friendly dip-coating approach is proposed to fabricate durable flame-retardant and superhydrophobic polyester–cotton (PTCO) fabrics. Self-assembled depositions of diethylenetriamine penta(methylene-phosphonic acid) (DTPMP) and ferric ion (Fe3+) were applied on PTCO fabrics through coordination interaction. Owing to the intumescent effect of DTPMP–Fe3+ complexes, DTPMP–Fe3+-coated fabric self-extinguished in the horizontal flame testing. Polydimethylsiloxane (PDMS) was then applied on DTPMP–Fe3+ complexes to impart the flame-retardant PTCO fabrics with superhydrophobicity (water contact angle: 155.6°) and self-cleaning properties. Especially, the washing durability of DTPMP–Fe3+-coated PTCO fabrics was improved by the modification of PDMS. The DT/Fe-8BL@PDMS sample still achieved self-extinguishing in the horizontal flame testing even after 12 laundering cycles.

Graphic abstract

Flame-retardant and superhydrophobic polyester–cotton fabrics are fabricated through the deposition of DTPMP–Fe3+ complexes and further modification of PDMS.

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Metadaten
Titel
Self-assembly of phosphonate-metal complex for superhydrophobic and durable flame-retardant polyester–cotton fabrics
verfasst von
Longxiang Liu
Ying Pan
Yuyu Zhao
Wei Cai
Zhou Gui
Yuan Hu
Xin Wang
Publikationsdatum
22.04.2020
Verlag
Springer Netherlands
Erschienen in
Cellulose / Ausgabe 10/2020
Print ISSN: 0969-0239
Elektronische ISSN: 1572-882X
DOI
https://doi.org/10.1007/s10570-020-03148-z

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