nach oben

Journal of Materials Science

Erschienen in:

03.03.2021 | Chemical routes to materials

Self-healing polymeric ionic liquid hydrogels with high mechanical strength and ionic conductivity

verfasst von: Xiaoling He, Xiaoqian Sun, Hongyan Meng, Shiyu Deng, Tingting He, Hongjun Zang, Dongsheng Wei

Erschienen in: Journal of Materials Science | Ausgabe 17/2021

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config

KI-gestützte Suche

Aus

Abstract

The poor mechanical properties of self-healing hydrogels limited their applications in the fields of biomedicine and industry. Here, a series of self-healing polymeric ionic liquid (PIL) hydrogels with high mechanical strength and electrical conductivity were prepared through hydrophobic association. Hydrophilic monomer vinyl ionic liquids (VILs) based on choline and amino acids, acrylamide (AAm) and hydrophobic monomers stearyl methacrylate (C18) were copolymerized in a micellar solution of sodium dodecyl sulfate (SDS); meanwhile, bacterial cellulose was introduced to enhance the mechanical strength of hydrogels. The resultant hydrogels exhibited excellent mechanical strength (5.8 MPa), extensive elongation at break (4250%) and outstanding self-healing efficiency (85%) without any external intervention. Even after healing, the tensile strength of most hydrogels could reach 2.5–3.9 MPa. At the same time, the incorporation of ILs endowed hydrogels with good electrical conductivity (a maximum of 1.258 S/m). These excellent properties predicted the potential application of the obtained PIL hydrogels in the fields of biomedicine and industry.

Graphical abstract

Vorheriger Artikel Preparation of polyvinylidene fluoride modified membrane by tannin and halloysite nanotubes for dyes and antibiotics removal

Nächster Artikel Nanoscale investigation and control of photothermal action of gold nanostructure-coated surfaces

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

über 102.000 Bücher
über 537 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Finance + Banking
Management + Führung
Marketing + Vertrieb
Maschinenbau + Werkstoffe
Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

über 67.000 Bücher
über 390 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Maschinenbau + Werkstoffe

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Nur mit Berechtigung zugänglich

Fantner GE, Oroudjev E, Schitter G, Golde LS, Thurner P, Finch MM, Turner P, Gutsmann T, Morse DE, Hansma H, Hansma PK (2006) Sacrificial bonds and hidden length: unraveling molecular mesostructures in tough materials. Biophys J 90:1411–1418CrossRef

Araya-Hermosilla R, Lima GMR, Raffa P, Fortunato G, Pucci A, Moreno-Villoslada I, Broekhuis AA, Picchioni F (2016) Intrinsic self-healing thermoset through covalent and hydrogen bonding interactions. Eur Polym J 81:186–197CrossRef

Hao X, Liu H, Xie Y, Fang C, Yang H (2013) Thermal-responsive self-healing hydrogel based on hydrophobically modified chitosan and vesicle. Colloid Polym Sci 291:1749–1758CrossRef

Xu Y, Wu Q, Sun Y, Bai H, Shi G (2010) Three-dimensional self-assembly of graphene oxide and DNA into multifunctional hydrogels. ACS Nano 4:7358–7362CrossRef

Appel EA, Biedermann F, Rauwald U, Jones ST, Zayed JM, Scherman OA (2010) Supramolecular cross-Linked networks via host-guest complexation with cucurbit[8]uril. J Am Chem Soc 132:14251–14260CrossRef

Haraguchi K, Uyama K, Tanimoto H (2011) Self-healing in nanocomposite hydrogels. Rapid Commun 32:1253–1258CrossRef

Froimowicz P, Klinger D, Landfester K (2011) Photoreactive nanoparticles as nanometric building blocks for the generation of self-healing hydrogel thin films. Chem Eur J 17:12465–12475CrossRef

Shao CY, Chang HL, Wang M, Xu F, Yang J (2017) High-strength, tough, and self-healing nanocomposite physical hydrogels based on the synergistic effects of dynamic hydrogen bond and dual coordination bonds. ACS Appl Mater Interfaces 9:28305–28318CrossRef

Sun JY, Zhao X, Illeperuma WRK, Chaudhuri O, Oh KH, Money DJ, Vlassak JJ, Suo Z (2012) Highly stretchable and tough hydrogels. Nature 489:133–136CrossRef

10.

Tuncaboylu DC, Sari M, Oppermann W, Okay O (2011) Tough and self-healing hydrogels formed via hydrophobic interactions. Macromolecules 44:4997–5005CrossRef

11.

Tuncaboylu DC, Argun A, Sahin M, Sari M, Okay O (2012) Structure optimization of self-healing hydrogels formed via hydrophobic interactions. Polymer 53:5513–5522CrossRef

12.

Tuncaboylu DC, Sahin M, Argun A, Oppermann W, Okay O (2012) Dynamics and large strain behavior of self-healing hydrogels with and without surfactants. Macromolecules 45:1991–2000CrossRef

13.

Gulyuz U, Okay O (2013) Self-healing polyacrylic acid hydrogels. Soft Matter 43:10287–10293CrossRef

14.

Akay G, Hassan-Raeisi A, Tuncaboylu DC, Orakdogen N, Abdurrahmanoglu S, Oppermann W, Okay O (2013) Self-healing hydrogels formed in catanionic surfactant solutions. Soft Matter 7:2254–2261CrossRef

15.

Gulyuz U, Okay O (2015) Self-healing poly(N-isopropylacrylamide) hydrogels. Eur Polym J 72:12–22CrossRef

16.

Gulyuz U, Okay O (2014) Self-healing poly(acrylic acid) hydrogels with shape memory behavior of high mechanical strength. Macromolecules 47:6889–6899CrossRef

17.

Zhao JS, Zhang C, Zou D, Liu XK, Cai LX, Li XY, Shi MX (2019) A structured design for highly stretchable electronic skin. Adv Mater Technol 10:1900492CrossRef

18.

Wei Y, Zeng Q, Hu Q (2018) Self-cleaned electrochemical protein imprinting biosensor basing on a thermo-responsive memory hydrogel. Biosens Bioelectron 99:136–141CrossRef

19.

Shi Y, Wang M, Ma C, Wang Y, Li X, Yu G (2015) A conductive self-healing hybrid gel enabled by metal ligand supramolecule and nanostructured conductive polymer. Nano Lett 15:6276–6281CrossRef

20.

Lim C, Shin Y, Jung J (2019) Stretchable conductive nanocomposite based on alginate hydrogel and silver nanowires for wearable electronics. APL Mater 3:031502CrossRef

21.

Dev A, Mohanbhai SJ, Kushwaha AC (2020) Kappa-carrageenan-C- phycocyanin based smart injectable hydrogels for accelerated wound recovery and real-time monitoring. Acta Biomater 109:121–131CrossRef

22.

Yang WX, Shao BW, Liu TY, Zhang YY, Huang R, Chen F, Fu Q (2018) Robust and mechanically and electrically self-healing hydrogel for efficient. ACS Appl Mater Inter 10:8245–8257CrossRef

23.

Wang Y, Maurel G, Couty M, Detcheverry F, Merabia S (2019) Implicit medium model for fractal aggregate polymer nanocomposites: linear viscoelastic properties. Macromolecules 5:2021–2032CrossRef

24.

Gunduz G, Kiziltas EE, Kiziltas A, Gencer A, Aydemir D, Asik N (2019) Production of bacterial cellulose fibers in the presence of effective microorganism. J Nat Fibers 16:567–575CrossRef

25.

Chen P, Cho SY, Jin HJ (2010) Modification and applications of bacterial celluloses in polymer science. Macromol Res 18:309–320CrossRef

26.

Ul-Islam M, Khan S, Ullah MW, Park JK (2015) Bacterial cellulose composites: synthetic strategies and multiple applications in bio-medical and electro-conductive fields. Biotechnol J 12:1847–1861CrossRef

27.

Meziane R, Bonnet JP, Courty M, Djellab K, Armand M (2011) Single-ion polymer electrolytes based on adelocalized polyanion for lithium batteries. Electrichim Acta 57:14–19CrossRef

28.

Sugimura R, Qiao K, Tomida D, Yokoyama C (2007) Immobilization of acidic ionic liquids by copolymerization with styrene and their catalytic use for acetal formation. Catal Commun 5:770–772CrossRef

29.

Nakajima H, Ohno H (2005) Preparation of thermally stable polymer electrolytes from imidazolium-type ionic liquid derivatives. Polymer 46:11499–11504CrossRef

30.

Tang HD, Tang JB, Ding SJ (2005) Atom transfer radical polymerization of styrenic ionic liquid monomers and carbon dioxide absorption of the polymerized ionic liquids. J Polym Sci Pol Chem 43:1432–1443CrossRef

31.

Ohno H, Fukumoto K (2007) Amino acid ionic liquids. Accounts Chem Res 11:1122–1129CrossRef

32.

Qian WJ, Texter J, Yan F (2017) Frontiers in poly(ionic liquid)s: syntheses and applications. Chem Soc Rev 46:1124–1159CrossRef

33.

Chen H, Elabd YA (2009) Polymerized ionic liquids: solution properties and electrospinning. Macromolecules 42:3368–3373CrossRef

34.

Bandomir J, Schulz A, Taguchi S, Schmitt L, Ohno H, Sternberg K, Schmitz KP, Kragl U (2014) Synthesis and characterization of polymerized ionic liquids: mechanical and thermal properties of a novel type of hydrogels. Macromol Chem Phys 215:716–724CrossRef

35.

Men Y, Schlaad H, Voelkel A, Yuan J (2014) Thermoresponsive polymerized gemini dicationic ionic liquid. Polym Chem 5:3719–3724CrossRef

36.

Li SL, Gao Y, Jiang HC, Duan LJ, Gao GH (2018) Tough, sticky and remoldable hydrophobic association hydrogel regulated by polysaccharide and sodium dodecyl sulfate as emulsifiers. Carbohyd Polym 201:591–598CrossRef

37.

Zhang Q, Wu M, Hu X (2020) A novel double-network, self-healing hydrogel based on hydrogen bonding and hydrophobic effect. Macromol Chem Phys 3:1900320CrossRef

38.

Wan J, Tang F, Wang Y, Lu QP, Liu SQ, Li LD (2020) Self-healing and highly stretchable gelatin hydrogel for self-powered strain sensor. ACS Appl Mater Interfaces 1:1558–1566

39.

Wen J, Zhang X, Pan M (2020) A robust, tough and multifunctional polyurethane/tannic acid hydrogel fabricated by physical-chemical dual crosslinking. Polymers 1:239CrossRef

40.

Wei D, Yang J, Zhu L, Chen F, Tang Z, Qin G, Chen Q (2018) Semicrystalline hydrophobically associated hydrogels with integrated high performances. ACS Appl Mater Interfaces 10:2946–2956CrossRef

41.

Zhang B, Gao Z, Gao G, Zhao W, Li J, Ren X (2018) Highly mechanical and fatigue-resistant double network hydrogels by dual physically hydrophobic association and ionic crosslinking. Macromol Mater Eng 303:1800072CrossRef

42.

Xia S, Jia F, Gao GH (2019) A flexible, adhesive and self-healable hydrogel -based wearable strain sensor for human motion and physiological signal monitoring. J Mater Chem B 7(30):4638–4648CrossRef

43.

Ye L, Lv Q, Sun XY, Liang YZ, Fang PW, Yuan XY, Li M, Zhang XZ, Shang XF, Liang HY (2020) Fully physically cross-linked double network hydrogels with strong mechanical properties, good recovery and self-healing properties. Soft Matter 16(7):1840–1849CrossRef

44.

Pan JZ, Jin Y, Lai SQ, Shi LJ, Fan WH, Shen YC (2019) An antibacterial hydrogel with desirable mechanical, self-healing and recyclable properties based on triple-physical crosslinking. Chem Eng J 370:1228–1238CrossRef

45.

Ying Y, Urban MW (2018) Self-Healing of polymers via supramolecular chemistry. Adv Mater Interfaces 5(17):1800384CrossRef

46.

Chen H, Hao BB, Ge PH, Chen SJ (2020) Highly stretchable, self-healing, and 3D printing prefabricatable hydrophobic association hydrogels with the assistance of electrostatic interaction. Polym Chem 11(29):4741–4748CrossRef

47.

Liang XX, Ding HY, Wang Q, Sun GX (2019) Tough physical hydrogels reinforced by hydrophobic association with remarkable mechanical property, rapid stimuli-responsiveness and fast self-recovery capability. Eur Polym J 120:109278CrossRef

48.

Sohrabi M, Yekta BE, Rezaie HR, Naimi-Jamal MR (2020) Rheology, injectability, and bioactivity of bioactive glass containing chitosan/gelatin nano pastes. Polym Sci 41:e49240

49.

Chen YY, Lu KY, Song YH, Han JQ, Yue YY, Biswas SK, Wu QL, Xiao HN (2019) A skin-inspired stretchable, self-healing and electro-conductive hydrogel with a synergistic triple network for wearable strain sensors applied in human-motion detection. Nanomaterials 12:1737CrossRef

50.

Dai XY, Zhang YY, Gao LN, Bai T, Wang W, Cui YL, Liu WG (2015) A mechanically strong, highly stable, thermoplastic, and self-healable supramolecular polymer hydrogel. Adv Mater 23:3566–3571CrossRef

51.

Vilela C, Sousa N, Pinto RJB, Silvestre AJD, Figueiredo FML, Freire CSR (2017) Exploiting poly(ionic liquids) and nanocellulose for the development of bio-based anion-exchange membranes. Biomass Bioenerg 100:116–125CrossRef

52.

Zhang HT, Wu XJ, Qin ZH, Sun X, Zhang H, Yu QY, Yao MM, He SS, Dong XR, Yao FL, Li JJ (2020) Dual physically cross-linked carboxymethyl cellulose-based hydrogel with high stretchability and toughness as sensitive strain sensors. Cellulose 27:9975–9989CrossRef

Titel: Self-healing polymeric ionic liquid hydrogels with high mechanical strength and ionic conductivity
verfasst von: Xiaoling He
Xiaoqian Sun
Hongyan Meng
Shiyu Deng
Tingting He
Hongjun Zang
Dongsheng Wei
Publikationsdatum: 03.03.2021
Verlag: Springer US
Erschienen in: Journal of Materials Science / Ausgabe 17/2021
Print ISSN: 0022-2461
Elektronische ISSN: 1573-4803
DOI: https://doi.org/10.1007/s10853-021-05930-1

Premium Partner

Marktübersichten

Die im Laufe eines Jahres in der „adhäsion“ veröffentlichten Marktübersichten helfen Anwendern verschiedenster Branchen, sich einen gezielten Überblick über Lieferantenangebote zu verschaffen.

Zur Marktübersicht

Springer Professional

Abstract

Graphical abstract

Bitte loggen Sie sich ein, um Zugang zu Ihrer Lizenz zu erhalten.

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Springer Professional "Technik"

Weitere Artikel der Ausgabe 17/2021

Preparation of refreshable membrane by partially sacrificial hydrophilic coating

Tailoring the electromagnetic properties of perovskite La0.7Sr0.3MnO3 ceramics by Co doping

Facile synthesis of Mg-formate MOF-derived mesoporous carbon for fast capacitive deionization

Relationship between physicochemical evolution and the failure process of flax fibers aged in water

Polarization-induced phase structure transition and change of photoluminescence in Er3+-doped (Ba, Ca)(Ti, Sn)O3-based multifunctional ceramics

Plasma processed tungsten for fusion reactor first-wall material

Premium Partner

Marktübersichten