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Journal of Polymer Research

Erschienen in:

01.04.2015 | Original Paper

Self-healing polymers based on a photo-active reversible addition-fragmentation chain transfer (RAFT) agent

verfasst von: Chuanjie Cheng, Xiongxiong Bai, Xu Zhang, Hongxia Li, Qinghua Huang, Yuanming Tu

Erschienen in: Journal of Polymer Research | Ausgabe 4/2015

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Abstract

A symmetric photo-active trithiocarbonate was designed and synthesized, which can act not only as a functional reversible addition-fragmentation chain transfer (RAFT) agent, but also as a crosslinker in crosslinking poly(methyl methacrylate-co-hydroxy ethyl acrylate) (poly(MMA-co-HEA)) due to interactions of benzophenone moieties of trithiocarbonate and hydroxyl groups of poly(MMA-co-HEA) under UV irradiation. In addition, the crosslinked poly(MMA-co-HEA) demonstrates photo-promoted self-healing properties by reshuffling C-S bonds of trithiocarbonate.

Vorheriger Artikel SiO2/polyvinylimidazole hybrid polymer as a sorbent for extraction by matrix solid-phase dispersion (MSPD): synthesis, characterization, and evaluation

Nächster Artikel Investigation of nanocomposite membranes based on crosslinked poly(vinyl alcohol)–sulfosuccinic acid ester and hexagonal boron nitride

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Titel: Self-healing polymers based on a photo-active reversible addition-fragmentation chain transfer (RAFT) agent
verfasst von: Chuanjie Cheng
Xiongxiong Bai
Xu Zhang
Hongxia Li
Qinghua Huang
Yuanming Tu
Publikationsdatum: 01.04.2015
Verlag: Springer Netherlands
Erschienen in: Journal of Polymer Research / Ausgabe 4/2015
Print ISSN: 1022-9760
Elektronische ISSN: 1572-8935
DOI: https://doi.org/10.1007/s10965-015-0691-9

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