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Journal of Materials Science
Erschienen in: Journal of Materials Science 13/2017

20.03.2017 | Original Paper

Shape and structural effects of R5-templated Pd nanomaterials as potent catalyst for oxygen electroreduction in alkaline media

verfasst von: Hongyu Yang, Chengwei Wen, Zhenghua Tang, Likai Wang, Qiannan Wang, Wei Yan, Wen Wu, Shaowei Chen

Erschienen in: Journal of Materials Science | Ausgabe 13/2017

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Abstract

Bio-inspired metal nanomaterials are receiving increasing research attentions in catalytic field recently, while peptide-based method represents new revenues to fabricate stable and reactive catalyst under mild and environmental friendly conditions. Among all kinds of noble metals, peptide-based palladium nanomaterials have demonstrated excellent catalytic capabilities in a variety of organic reactions. However, their electrocatalytic properties have not been systematically studied. Herein, R5-templated Pd nanomaterials have been fabricated and employed as potent catalysts for oxygen reduction reaction (ORR). The shape and morphology of these Pd nanomaterials were manipulated by tuning the metal-to-R5 ratio. The as-prepared Pd nanomaterials demonstrated excellent ORR activity in alkaline media. R5-Pd-90 exhibited the best activity which is superior than commercial Pt/C, in terms of onset potential, diffusion-limited current density as well as long-term stability. The correlation between the shape and/or morphology of the peptide-templated Pd nanomaterials and their ORR activity has been successfully established.
Vorheriger Artikel Surface modification of an austenitic stainless steel wire by a multi-pulse treatment with a high-power electric current
Nächster Artikel Preparation of surface-imprinted microspheres using ionic liquids as novel cross-linker for recognizing an immunostimulating peptide

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Metadaten
Titel
Shape and structural effects of R5-templated Pd nanomaterials as potent catalyst for oxygen electroreduction in alkaline media
verfasst von
Hongyu Yang
Chengwei Wen
Zhenghua Tang
Likai Wang
Qiannan Wang
Wei Yan
Wen Wu
Shaowei Chen
Publikationsdatum
20.03.2017
Verlag
Springer US
Erschienen in
Journal of Materials Science / Ausgabe 13/2017
Print ISSN: 0022-2461
Elektronische ISSN: 1573-4803
DOI
https://doi.org/10.1007/s10853-017-1004-y

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