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Journal of Sol-Gel Science and Technology
Erschienen in: Journal of Sol-Gel Science and Technology 2/2018

28.03.2018 | Original Paper: Fundamentals of sol-gel and hybrid materials processing

Sol-assisted spray-drying synthesis of porous Li3V2(PO4)3/C microspheres as high-activity cathode materials for lithium-ion batteries

verfasst von: Xiaoyu Liu, Xuejiao Feng, Xiaoning Xu, Fei Wang, Yanming Wang

Erschienen in: Journal of Sol-Gel Science and Technology | Ausgabe 2/2018

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Abstract

Herein, porous Li3V2(PO4)3/C microspheres made of nanoparticles are obtained by a combination of sol spray-drying and subsequent-sintering process. Beta-cyclodextrin serves as a special chelating agent and carbon source to obtain carbon-coated Li3V2(PO4)3 grains with the size of ca. 30–50 nm. The unique porous structure and continuous carbon skeleton facilitate the fast transport of lithium ion and electron. The Li3V2(PO4)3/C microspheres offer an outstanding electrochemical performance, which present a discharge capacity of 122 mAh g−1 at 2 C with capacity retention of 96% at the end of 1000 cycles and a high-rate capacity of 113 mAh g−1 at 20 C in the voltage window of 3.0–4.3 V. Moreover, the Li3V2(PO4)3/C microspheres also give considerable cycling stability and high-rate reversible capacity at a higher end-of-charge voltage of 4.8 V.
Vorheriger Artikel Production of monodisperse cerium oxide microspheres with diameters near 100 µm by internal-gelation sol–gel methods
Nächster Artikel Color and fastness of natural dyes encapsulated by a sol-gel process for dyeing natural and synthetic fibers

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Metadaten
Titel
Sol-assisted spray-drying synthesis of porous Li3V2(PO4)3/C microspheres as high-activity cathode materials for lithium-ion batteries
verfasst von
Xiaoyu Liu
Xuejiao Feng
Xiaoning Xu
Fei Wang
Yanming Wang
Publikationsdatum
28.03.2018
Verlag
Springer US
Erschienen in
Journal of Sol-Gel Science and Technology / Ausgabe 2/2018
Print ISSN: 0928-0707
Elektronische ISSN: 1573-4846
DOI
https://doi.org/10.1007/s10971-018-4644-8

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