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Journal of Sol-Gel Science and Technology
Erschienen in: Journal of Sol-Gel Science and Technology 1/2018

15.08.2018 | Original Paper: Nano-structured materials (particles, fibers, colloids, composites, etc.)

Sol-gel synthesis of cerium dioxide nanoparticles coated with stimuli-responsive components and the application for conversion of d-(−)-fructose into platform molecules

verfasst von: Chao Fan, Wanli Pan, Wanqin Wang, Qifan Rao, Anzhi Yan, Shouxu Chen, Aqun Zheng, Yu Li, Benhua Huang, Yang Sun

Erschienen in: Journal of Sol-Gel Science and Technology | Ausgabe 1/2018

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Abstract

A series of nanosized cerium dioxide particles coated with Pluronic P123, poly(vinyl alcohol) (PVA) or titanium oxide are prepared through a sol-gel process. Characterizations reveal sizes of cerium dioxide particles are maintained below 15 nm along with good crystallinity, and their crystal forms could be modulated by calcination. Furthermore, the organic components such as Pluronic P123 and PVA could be incorporated during sol-gel and affect sample porosity, while loading of titanium into cerium dioxide improves acid amount of sol-gel product. Catalysis reveals both PVA and titanium components show obvious and significant thermo- and pH-responsive properties for conversion of d-(−)-fructose into 5-(hydroxymethyl)-furfural, which mean a lot to the future large-scale production of biomass-derived fine chemicals. This work would not only contribute to the development of stimuli-responsive materials, but also show their promising application for conversion of biomass to platform molecules.
Vorheriger Artikel Mechanical reinforced fiber needle felt/silica aerogel composite with its flammability
Nächster Artikel Synthesis of highly efficient Co3O4 catalysts by heat treatment ZIF-67 for CO oxidation

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Metadaten
Titel
Sol-gel synthesis of cerium dioxide nanoparticles coated with stimuli-responsive components and the application for conversion of d-(−)-fructose into platform molecules
verfasst von
Chao Fan
Wanli Pan
Wanqin Wang
Qifan Rao
Anzhi Yan
Shouxu Chen
Aqun Zheng
Yu Li
Benhua Huang
Yang Sun
Publikationsdatum
15.08.2018
Verlag
Springer US
Erschienen in
Journal of Sol-Gel Science and Technology / Ausgabe 1/2018
Print ISSN: 0928-0707
Elektronische ISSN: 1573-4846
DOI
https://doi.org/10.1007/s10971-018-4771-2

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