Skip to main content
Fachgebiete
Automobil + Motoren Bauwesen + Immobilien Business IT + Informatik Elektrotechnik + Elektronik Energie + Nachhaltigkeit Finance + Banking Management + Führung Marketing + Vertrieb Maschinenbau + Werkstoffe Versicherung + Risiko
DE
EN
Bücher
Zeitschriften
Themenseiten
Organisationspsychologie Projektmanagement Marketing Smart Manufacturing
Weitere Formate
Podcasts Webinare Technik Webinare Wirtschaft Kongresse Veranstaltungskalender Awards
Jetzt Einzelzugang starten
Zugang für Unternehmen
Referenzkunden
SLX-Digitalkonferenz: Zukunftswerkstatt 2024

Mehr Umsatz mit Top-Kontakten

Am 7. Mai erfahren Sie, wie Vertriebsteams Leadgenerierung, Leadnurturing und Leadstrategien effizient steuern können.
Erweiterte Suche
Anmelden
nach oben
Journal of Materials Science
Erschienen in: Journal of Materials Science 12/2015

01.06.2015 | Original Paper

Solvothermal self-assembly of magnetic Fe3O4 nanochains by ethylenediamine functionalized nanoparticles for chromium(VI) removal

verfasst von: Hong Ni, Xiaowen Sun, Yadong Li, Chunxia Li

Erschienen in: Journal of Materials Science | Ausgabe 12/2015

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config
loading …

Abstract

In this study, one-dimensional amino-functionalized magnetic Fe3O4 nanochains (MNCs) consisting of self-assembled Fe3O4 nanoparticles (NPs) were synthesized via a facile one-pot solvothermal route at 180 °C using FeCl3·6H2O as the iron source and ethylenediamine as the surfactant without the use of any external magnetic fields or templates. The synthesized MNCs consist of nanospheres with a diameter of 120 nm assembled from Fe3O4 NPs and have good water dispersibility with a high Brunauer–Emmett–Teller surface area (44.028 m2 g−1). The magnetic measurements revealed the superparamagnetic nature of the as-prepared MNCs with a saturation magnetization of 70.9 emu g−1 at room temperature. The nanochain formation mechanism was proposed as a magnetic dipole–dipole interaction and caused by the effects of the ethylenediamine surfactants. These MNCs were confirmed to be efficient adsorbents for chromium(VI) removal. The adsorption isotherm conformed to the Langmuir model at a Cr(VI) ion concentration higher than 40 mg L−1, and the maximum removal capacity was 60.25 mg g−1 at a solid-to-liquid ratio of 1:1000 g/mL.
Vorheriger Artikel Deformation and fracture behaviour of electroplated Sn–Bi/Cu solder joints
Nächster Artikel Dinonylphenyl end-capped poly(ethylene glycol)-b-polystyrene: synthesis and its unusual crystalline and self-assembly behaviors

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Jetzt informieren
Anhänge
Nur mit Berechtigung zugänglich
Literatur
1.
Yi DK, Lee SS, Ying JY (2006) Synthesis and applications of magnetic nanocomposite catalysts. Chem Mater 18:2459–2461CrossRef
2.
Frey NA, Peng S, Cheng K, Sun S (2009) Magnetic nanoparticles: synthesis, functionalization, and applications in bioimaging and magnetic energy storage. Chem Soc Rev 38:2532–2542CrossRef
3.
Gao J, Gu H, Xu B (2009) Multifunctional magnetic nanoparticles: design, synthesis, and biomedical applications. Acc Chem Res 42:1097–1107CrossRef
4.
Shen H, Chen J, Dai H, Wang L, Hu M, Xia Q (2013) New insights into the sorption and detoxification of chromium(VI) by tetraethylenepentamine functionalized nanosized magnetic polymer adsorbents: mechanism and pH effect. Ind Eng Chem Res 52:12723–12732CrossRef
5.
Gao MR, Zhang SR, Jiang J, Zheng YR, Tao DQ, Yu SH (2011) One-pot synthesis of hierarchical magnetite nanochain assemblies with complex building units and their application for water treatment. J Mater Chem 21:16888–16892CrossRef
6.
Zhu J, Wei S, Chen M, Gu H, Rapole SB, Pallavkar S, Ho TC, Hopper J, Guo Z (2013) Magnetic nanocomposites for environmental remediation. Adv Powder Technol 24:459–467CrossRef
7.
8.
9.
He Q, Yuan T, Zhu J, Luo Z, Haldolaarachchige N, Sun L, Khasanov A, Li Y, Young DP, Wei S, Guo Z (2012) Magnetic high density polyethylene nanocomposites reinforced with in situ synthesized Fe@FeO core-shell nanoparticles. Polymer 53:3642–3652CrossRef
10.
Dui J, Zhu G, Zhou S (2013) Facile and economical synthesis of large hollow ferrites and their applications in adsorption for As(V) and Cr(VI). ACS Appl Mater Interfaces 5:10081–10089CrossRef
11.
Cui S, Shen X, Lin B (2006) Surface organic modification of Fe3 O4 nanoparticles by silane-coupling agents. Rare Met 25:426–430CrossRef
12.
Liu HL, Ko SP, Wu JH, Jung MH, Min JH, Lee JH, An BH, Kim YK (2007) One-pot polyol synthesis of monosize PVP-coated sub-5 nm Fe3O4 nanoparticles for biomedical applications. J Magn Magn Mater 310:e815–e817CrossRef
13.
Takami S, Sato T, Mousavand T, Ohara S, Umetsu M, Adschiri T (2007) Hydrothermal synthesis of surface-modified iron oxide nanoparticles. Mater Lett 61:4769–4772CrossRef
14.
Liu ZL, Liu YJ, Yao KL, Ding ZH, Tao J, Wang X (2002) Synthesis and magnetic properties of Fe3O4 nanoparticles. J Mater Synth Process 10:83–87CrossRef
15.
Sun S, Zeng H, Robinson DB, Raoux S, Rice PM, Wang SX, Li G (2004) Monodisperse MFe2O4 (M) = Fe Co, Mn) Nanoparticles. J Am Chem Soc 126:273–279CrossRef
16.
Gan N, Jia L, Zheng L (2011) A novel sandwich electrochemical immunosensor based on the DNA-derived magnetic nanochain probes for alpha-fetoprotein. J Autom Methods Manag Chem 2011:957805CrossRef
17.
Zhou SM, Zhang XT, Gong HC, Zhang B, Wu ZS, Du ZL, Wu SX (2008) Magnetic enhancement of pure gamma Fe2O3 nanochains by chemical vapor deposition. J Phys 20:075217
18.
Laurent S, Forge D, Port M, Roch A, Robic C, Elst LV, Muller RN (2008) Magnetic iron oxide nanoparticles: synthesis, stabilization, vectorization, physicochemical characterizations, and biological applications. Chem Rev 108:2064–2110CrossRef
19.
Wei S, Wang Q, Zhu J, Sun L, Lin H, Guo Z (2011) Multifunctional composite core-shell nanoparticles. Nanoscale 3:4474–4502CrossRef
20.
Liu Y, Chen Q (2008) Synthesis of magnetosome chain-like structures. Nanotechnology 19:475603CrossRef
21.
Korth BD, Keng P, Shim I, Bowles SE, Tang C, Kowalewski T, Nebesny KW, Pyun J (2006) Polymer-coated ferromagnetic colloids from well-defined macromolecular surfactants and assembly into nanoparticle chains. J Am Chem Soc 128:6562–6563CrossRef
22.
He Q, Yuan T, Yan X, Luo Z, Haldolaarachchige N, Young DP, Wei S, Guo Z (2014) One-pot synthesis of size- and morphology-controlled 1-D iron oxide nanochains with manipulated magnetic properties. Chem Commun 50:201–203CrossRef
23.
He Q, Yuan T, Wei S, Haldolaarachchige N, Luo Z, Young DP, Khasanov A, Guo Z (2012) Morphology-andphase-controlled iron oxide nanoparticles stabilized with maleic anhydride grafted polypropylene. Angew Chem 51:8842–8845CrossRef
24.
Jia B, Gao L (2008) Morphological transformation of Fe3O4 spherical aggregates from solid to hollow and their self-assembly under an external magnetic field. J Phys Chem C 112:666–671CrossRef
25.
Wang H, Chen QW, Sun XL, Qi HP, Yang X, Zhou S, Xiong J (2009) Magnetic-field-induced formation of one-dimensional magnetite nanochains. Langmuir 25:7135–7139CrossRef
26.
Ma M, Zhang Q, Dou J, Zhang H, Yin D, Geng W, Zhou Y (2012) Fabrication of one-dimensional Fe3O4/P(GMA–DVB) nanochains by magnetic-field-induced precipitation polymerization. J Colloid Interface Sci 374:339–344CrossRef
27.
Zhang Y, Sun L, Fu Y, Huang ZC, Bai XJ, Zhai Y, Du J, Zhai HR (2009) The shape anisotropy in the magnetic field-assisted self-assembly chain-like structure of magnetite. J Phys Chem C 113:8152–8157CrossRef
28.
Kim Y, Choi YS, Lee HJ, Yoon H, Kim YK, Oh M (2014) Self-assembly of fluorescent and magnetic Fe3O4@coordination polymer nanochains. Chem Commun 50:7617–7620CrossRef
29.
Yu SH, Yoshimura M (2002) Ferrite/metal composites fabricated by soft solution processing. Adv Funct Mater 12:10–15
30.
Zhang J, Wan J, Huang S, Du J, Zhu J, Zhang D, Yin Q, Wu Y (2010) Solvothermal synthesis and magnetic property of magnetic chains self-assembled by Fe3O4 microoctahedrons. Chin J Chem 28:1607–1612CrossRef
31.
Bhaumik M, Maity A, Srinivasu VV, Onyango MS (2012) Removal of hexavalent chromium from aqueous solution using polypyrrole-polyaniline nanofibers. Chem Eng J 181–182:323–333CrossRef
32.
Gu H, Rapole SB, Huang Y, Cao D, Luo Z, Wei S, Guo Z (2013) Synergistic interactions between multi-walled carbon nanotubes and toxic hexavalent chromium. J Mater Chem A 1:2011–2021CrossRef
33.
Kulkarni PS, Kalyani V, Mahajani VV (2007) Removal of hexavalent chromium by membrane-based hybrid processes. Ind Eng Chem Res 46:8176–8182CrossRef
34.
Wang J, Zhao L, Duan W, Han L, Chen Y (2012) Adsorption of aqueous Cr(VI) by novel fibrous adsorbent with amino and quaternary ammonium groups. Ind Eng Chem Res 51:13655–13662CrossRef
35.
Hu JS, Zhong LS, Song WG, Wan LJ (2008) Synthesis of hierarchically structured metal oxides and their application in heavy metal ion removal. Adv Mater 20:2977–2982CrossRef
36.
Zhao YG, Shen HY, Pan SD, Hu MQ, Xia QH (2010) Preparation and characterization of amino-functionalized nano-Fe3O4 magnetic polymer adsorbents for removal of chromium(VI) ions. J Mater Sci 45:5291–5301. doi:10.​1007/​s10853-010-4574-5 CrossRef
37.
Ni H, Xiong Z, Ye T, Zhang Z, Ma X, Li L (2012) Biosorption of copper (II) from aqueous solutions using volcanic rock matrix-immobilized Pseudomonas putida cells with surface-displayed cyanobacterial metallothioneins. Chem Eng J 204–206:264–271CrossRef
38.
Zheng JG, Zhang Y, Zhai Y, Yang HW (2010) TEM and EBSD study of Fe3O4 particle chains grown and assembled in external magnetic field. Microsc Microanal 16:1790–1791CrossRef
39.
Descostes M, Mercier F, Thromat N, Beaucaire C, Gautier-Soyer M (2000) Use of XPS in the determination of chemical environment and oxidation state of iron and sulfur samples: constitution of a data basis in binding energies for Fe and S reference compounds and applications to the evidence of surface species of an oxidized pyrite in a carbonate medium. Appl Surf Sci 165:288–302CrossRef
40.
Rondinone AJ, Samia ACS, Zhang ZJ (1999) Superparamagnetic relaxation and magnetic anisotropy energy distribution in CoFe2O4 spinel ferrite nanocrystallites. J Phys Chem B 103:6876–6880CrossRef
41.
Yuan H, Wang Y, Zhou S, Lou S (2011) Fabrication of superparamagnetic Fe3O4 hollow microspheres with a high saturation magnetization. Chem Eng J 175:555–560CrossRef
42.
Yi Tan, Zhuang Z, Peng Q, Li Y (2008) Room-temperature soft magnetic iron oxide nanocrystals: synthesis, characterization, and size-dependent magnetic properties. Chem Mater 20:5029–5034CrossRef
43.
Wang L, Bao J, Wang L, Zhang F, Li Y (2006) One-pot synthesis and bioapplication of amine-functionalized magnetite nanoparticles and hollow nanospheres. Chem Eur J 12:6341–6347CrossRef
44.
Liu Y, Wang Y, Zhou S, Lou S, Yuan L, Gao T, Wu X, Shi X, Wang K (2012) Synthesis of high saturation magnetization superparamagnetic Fe3O4 hollow microspheres for swift chromium removal. ACS Appl Mater Interfaces 4:4913–4920CrossRef
45.
Willard MA, Kurihara LK, Carpenter EE, Calvin S, Harris VG (2004) Chemically prepared magnetic nanoparticles. Int Mater Rev 49:125–170CrossRef
46.
Yan K, Li H, Li P, Zhu H, Shen J, Yi C, Wu S, Yeung KW, Xu Z, Xu H, Chu PK (2014) Self-assembled magnetic fluorescent polymeric micelles for magnetic resonance and optical imaging. Biomaterials 35:344–355CrossRef
Metadaten
Titel
Solvothermal self-assembly of magnetic Fe3O4 nanochains by ethylenediamine functionalized nanoparticles for chromium(VI) removal
verfasst von
Hong Ni
Xiaowen Sun
Yadong Li
Chunxia Li
Publikationsdatum
01.06.2015
Verlag
Springer US
Erschienen in
Journal of Materials Science / Ausgabe 12/2015
Print ISSN: 0022-2461
Elektronische ISSN: 1573-4803
DOI
https://doi.org/10.1007/s10853-015-8979-z

Weitere Artikel der Ausgabe 12/2015

Journal of Materials Science 12/2015 Zur Ausgabe

Original Paper

Storage time-dependent alteration of molecular interaction–property relationships of whey protein isolate-based films and coatings

Original Paper

An evaluation of the saturation hardness in an ultrafine-grained aluminum 7075 alloy processed using different techniques

Original Paper

Polyacrylamide gel synthesis, structure and optical properties of LaP3O9:Eu3+ phosphors

Original Paper

Influence of Zn interlayer addition on microstructure and mechanical properties of friction stir welded AZ31 Mg alloy

Original Paper

PVP-assisted synthesis of shape-controlled CuFeS2 nanocrystals for Li-ion batteries

Original Paper

Synthesis of polymer-based hybrid materials via Mn(II) oxidation with N-bromosulphonamide polymer and their characterization

Premium Partner

    Marktübersichten

    Die im Laufe eines Jahres in der „adhäsion“ veröffentlichten Marktübersichten helfen Anwendern verschiedenster Branchen, sich einen gezielten Überblick über Lieferantenangebote zu verschaffen. 

    Zur Marktübersicht
    Bildnachweise