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19.02.2021 | Original Research

Soy meal adhesive with high strength and water resistance via carboxymethylated wood fiber-induced crosslinking

verfasst von: Huiwen Pang, Yuyang Wang, Zhiwei Chang, Changlei Xia, Chunrui Han, Hongguang Liu, Jianzhang Li, Shifeng Zhang, Liping Cai, Zhenhua Huang

Erschienen in: Cellulose | Ausgabe 6/2021

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Abstract

Soy meal-based wood adhesive has received much interest for its environmentally friendly properties, as it is thought to provide an effective alternative to conventional formaldehyde-based wood adhesives. However, the abundant hydrophilic groups and weak internal structure result in poor water resistance and low bonding strength of soy meal-based wood adhesives. In this study, bio-based carboxymethylated wood fibers (CMWFs) were used to develop a high-performance soy meal-based adhesive. Wood fibers (WFs) were pre-treated via carboxymethylation to endow WFs with abundant carboxyl groups and facilitate their dispersion in soy protein matrix. CMWFs containing abundant carboxyl groups served as a multiple “crosslinking core” and effectively cross-linked with soy protein side-chain, resulting in the construction of a stable adhesive system. The modified soy meal-based adhesive exhibited excellent bonding strength and water resistance. In particular, tension tests indicated that the water-resistant bonding strength of the adhesive modified with CMWFs reached 1.69 MPa, which was 160% higher compared with the unmodified adhesive; the wood failure percentage of the plywood bonded by CMWF-modified soy meal-based adhesive was as high as 100%. Moisture uptake and residual rate tests indicated that high water resistance of the adhesive was achieved. This design provides a facile and sustainable strategy for developing high-performance soy meal-based adhesives.

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Vorheriger Artikel Cellulose/carbon nanotube/MnO2 composite electrodes with high mass loadings for symmetric supercapacitors

Nächster Artikel Facile in situ synthesis of ZIF-67/cellulose hybrid membrane for activating peroxymonosulfate to degrade organic contaminants

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Titel: Soy meal adhesive with high strength and water resistance via carboxymethylated wood fiber-induced crosslinking
verfasst von: Huiwen Pang
Yuyang Wang
Zhiwei Chang
Changlei Xia
Chunrui Han
Hongguang Liu
Jianzhang Li
Shifeng Zhang
Liping Cai
Zhenhua Huang
Publikationsdatum: 19.02.2021
Verlag: Springer Netherlands
Erschienen in: Cellulose / Ausgabe 6/2021
Print ISSN: 0969-0239
Elektronische ISSN: 1572-882X
DOI: https://doi.org/10.1007/s10570-021-03732-x

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