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2024 | Buch

Spectral Theory and Quantum Mechanics

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This textbook presents the spectral theory of self-adjoint operators on Hilbert space and its applications in quantum mechanics. Based on a course taught by the author in Paris, the book not only covers the mathematical theory but also provides its physical interpretation, offering an accessible introduction to quantum mechanics for students with a background in mathematics. The presentation incorporates numerous physical examples to illustrate the abstract theory. The final two chapters present recent findings on Schrödinger’s equation for systems of particles.

While primarily designed for graduate courses, the book can also serve as a valuable introduction to the subject for more advanced readers. It requires no prior knowledge of physics, assuming only a graduate-level understanding of mathematical analysis from the reader.

Inhaltsverzeichnis

Frontmatter
Chapter 1. Introduction to Quantum Mechanics: The Hydrogen Atom
Abstract
This chapter is an introduction to the mathematical formalism of quantum mechanics. It presents the modeling of a quantum particle such as the electron in the hydrogen atom. The approach is purely variational and the role played by spectral theory is only hinted at.
Mathieu Lewin
Chapter 2. Self-adjointness
Abstract
We introduce the concept of self-adjoint operators in infinite dimension. Several examples are presented, including the momentum and the Laplacian on an interval of the real line, or on the whole space in any dimension.
Mathieu Lewin
Chapter 3. Self-adjointness Criteria: Rellich, Kato and Friedrichs
Abstract
We first present a result of Rellich and Kato, that provides the self-adjointness of operators in the form \(A+B\) on the same domain as that of A, under simple assumptions on the perturbation B. This is followed by a discussion of Friedrich’s theory of quadratic forms, that allows one to construct self-adjoint extensions that are natural from a physical point of view.
Mathieu Lewin
Chapter 4. Spectral Theorem and Functional Calculus
Abstract
This chapter contains the spectral theorem (diagonalization of any self-adjoint operator) and the construction of functional calculus. Numerous consequences are discussed: spectral projectors, powers, Stone’s theorem, Schrödinger’s equation, heat equation, wave equation, etc.
Mathieu Lewin
Chapter 5. Spectrum of Self-adjoint Operators
Abstract
This chapter contains multiple tools for studying the spectrum of a self-adjoint operator. First, we discuss how the spectrum is modified when a small perturbation is added to a given operator. Next, we define the different types of spectrum (point, continuous, essential, discrete) and present criteria due to Weyl in order to identify them. Compact and compact-resolvent operators are treated as examples. The Courant-Fischer formula and the Lieb-Thirring inequality are then used to quantify the number and size of eigenvalues below the essential spectrum. The chapter concludes with a short introduction to semi-classical analysis.
Mathieu Lewin
Chapter 6. N-particle Systems, Atoms, Molecules
Abstract
We discuss the modeling of a system containing several quantum particles interacting with each other, such as the electrons in a molecule or an atom. Recent results are described for the case of large atoms.
Mathieu Lewin
Chapter 7. Periodic Schrödinger Operators, Electronic Properties of Materials
Abstract
We study Schrödinger operators comprising a periodic potential. Bloch-Floquet theory is used to explain differences in the electrical behavior of solids, depending on the shape of the spectrum.
Mathieu Lewin
Backmatter
Metadaten
Titel
Spectral Theory and Quantum Mechanics
verfasst von
Mathieu Lewin
Copyright-Jahr
2024
Electronic ISBN
978-3-031-66878-4
Print ISBN
978-3-031-66877-7
DOI
https://doi.org/10.1007/978-3-031-66878-4