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Journal of Materials Science

Erschienen in:

23.04.2021 | Chemical routes to materials

Spectroscopic investigations of gamma-ray irradiation effects on metal organic framework

verfasst von: Abdul G. Al Lafi, Bassem Assfour, Thaer Assaad

Erschienen in: Journal of Materials Science | Ausgabe 21/2021

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Abstract

The chemical and physical features of metal organic frameworks (MOFs) at a molecular level are of great merit to understand structure–property relationships and, consequently, to aid in the design of improved high value products. This paper reports on the processing of one MOF-type material, namely MIL-101(Cr), by γ-ray irradiation at low doses up to 30 kGy. The optimum dose is determined to be 15 kGy, at which an increase in the adsorption of iodine of more than 40% is achieved in comparison with thermally activated un-irradiated MIL-101(Cr). Scanning electron microscopy, X-ray diffraction and the Brunauer−Emmett−Teller (BET) isotherms indicate a significant particle agglomeration and a preservation of both the unit cell topology as well as the mesoporous structure of MOF. Two-dimensional correlation Fourier transformation infrared and X-ray diffraction reveals that orientation is the driving force for structural alterations including water type, bonding and contents. These effects account for the increasing adsorption capacity of MOF after irradiation and suggest further exploitation of irradiation as a promising method for MOFs activation.

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Vorheriger Artikel In-situ resource utilisation manufacturing of optically transparent glass from lunar regolith simulant

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Titel: Spectroscopic investigations of gamma-ray irradiation effects on metal organic framework
verfasst von: Abdul G. Al Lafi
Bassem Assfour
Thaer Assaad
Publikationsdatum: 23.04.2021
Verlag: Springer US
Erschienen in: Journal of Materials Science / Ausgabe 21/2021
Print ISSN: 0022-2461
Elektronische ISSN: 1573-4803
DOI: https://doi.org/10.1007/s10853-021-06051-5

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