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Journal of Materials Science
Erschienen in: Journal of Materials Science 10/2017

06.02.2017 | Original Paper

Enzyme-free uric acid electrochemical sensors using β-cyclodextrin-modified carboxylic acid-functionalized carbon nanotubes

verfasst von: Mulugeta B. Wayu, Margaret A. Schwarzmann, Samuel D. Gillespie, Michael C. Leopold

Erschienen in: Journal of Materials Science | Ausgabe 10/2017

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Abstract

Carboxylic acid-functionalized multi-walled carbon nanotubes (COOH-MWCNT) were modified via ultrasonication with β-cyclodextrin (β-CD) to obtain a COOH-MWCNT:β-CD nanocomposite material for the purpose of developing an enzyme-free electrochemical sensor for uric acid—a clinically relevant molecule implemented in pregnancy-induced hypertension diagnosis. The nanocomposite material is deposited onto glassy carbon electrodes and subsequently capped with layers of Nafion and Hydrothane polyurethane. The surface morphology and electronic structure of the nanocomposite material were characterized using UV–Vis, TEM, and FTIR. The performance of the electrochemical sensor was measured through direct injection of UA during amperometry. With the high surface area of the COOH-MWCNT in concert with the selectivity provided by β-CD, the composite system outperforms similar COOH-MWCNT systems, displaying enhanced UA sensitivity versus films with only COOH-MWCNT. With the improved sensitivity (4.28 ± 0.11 µA mM−1) and fast response time (4.0 ± 0.5 s), the sensors offer wide detection of UA across clinically relevant ranges (100–700 μM) as well as demonstrated selectivity against various interferents.
Vorheriger Artikel A numerical model for a hypoeutectic alloy droplet deposition with non-equilibrium solidification
Nächster Artikel Influence of plastic deformation on the precipitation sequence in an AA6061 alloy

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Metadaten
Titel
Enzyme-free uric acid electrochemical sensors using β-cyclodextrin-modified carboxylic acid-functionalized carbon nanotubes
verfasst von
Mulugeta B. Wayu
Margaret A. Schwarzmann
Samuel D. Gillespie
Michael C. Leopold
Publikationsdatum
06.02.2017
Verlag
Springer US
Erschienen in
Journal of Materials Science / Ausgabe 10/2017
Print ISSN: 0022-2461
Elektronische ISSN: 1573-4803
DOI
https://doi.org/10.1007/s10853-017-0844-9

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