nach oben

Adsorption

Erschienen in:

09.12.2016

Stepped water isotherm and breakthrough curves on aluminium fumarate metal–organic framework: experimental and modelling study

verfasst von: Belgin Bozbiyik, Tom Van Assche, Jeroen Lannoeye, Dirk E. De Vos, Gino V. Baron, Joeri F. M. Denayer

Erschienen in: Adsorption | Ausgabe 1/2017

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config

KI-gestützte Suche

Aus

Abstract

Adsorption of water vapour on the Al-fumarate metal–organic framework (MOF) was studied in static and dynamic conditions, by performing gravimetric and fixed bed experiments. A two-step, type IV water isotherm is obtained, which reveals the complexity and the duality of the hydrophilic/hydrophobic behaviour of this MOF. Breakthrough experiments with feed conditions corresponding to three different zones in the water adsorption isotherm were performed to study the effect of isotherm shape on the column dynamics. At low partial pressure of water in the feed, a single breakthrough step is observed while a stepped profile is observed at higher partial pressure of water. These breakthrough curves could be described qualitatively with a simple model accounting for the isotherm shape.

Vorheriger Artikel Study of a novel rapid vacuum pressure swing adsorption process with intermediate gas pressurization for producing oxygen

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

über 102.000 Bücher
über 537 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Finance + Banking
Management + Führung
Marketing + Vertrieb
Maschinenbau + Werkstoffe
Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

über 67.000 Bücher
über 390 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Maschinenbau + Werkstoffe

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Nur mit Berechtigung zugänglich

Alvarez, E., Guillou, N., Martineau, C., Bueken, B., Van De Voorde, B., Le Guillouzer, C., Fabry, P., Nouar, F., Taulelle, F., De Vos, D., Chang, J., Cho, K.H., Ramsahye, N., Devic, T., Daturi, M., Maurin, G., Serre, C.: The structure of the aluminum fumarate metal–organic framework A520. Angew. Chem. Int. Ed. 54, 3664–3668 (2015)CrossRef

Bon, V., Senkovska, I., Baburin, I.A., Kaskel, S.: Zr- and Hf-based metal–organic frameworks: tracking down the polymorphism. Cryst. Growth Des. 13, 1231–1237 (2013)CrossRef

Borjigin, T., Sun, F., Zhang, J., Cai, K., Ren, H., Zhu, G.: A microporous metal-organic framework with high stability for GC separation of alcohols from water. Chem. Commun. 48, 7613–7615 (2012)CrossRef

Bozbiyik, B., Duerinck, T., Lannoeye, J., De Vos, D.E., Baron, G.V., Denayer, J.F.M.: Adsorption and separation of n-hexane and cyclohexane on the UiO-66 metal–organic framework. Microporous Mesoporous Mater. 183, 143–149 (2014)CrossRef

Bozbiyik, B., Lannoeye, J., De Vos, D.E., Baron, G.V., Denayer, J.F.M.: Shape selective properties of the Al-fumarate metal-organic framework in the adsorption and separation of n-alkanes, iso-alkanes, cyclo-alkanes and aromatic hydrocarbons. Phys. Chem. Chem. Phys. 18, 3294–3301 (2016)CrossRef

Burtch, N.C., Jasuja, H., Walton, K.S.: Water stability and adsorption in metal–organic frameworks. Chem. Rev. 114, 10575–10612 (2014)CrossRef

Canivet, J., Fateeva, A., Guo, Y., Coasne, B., Farrusseng, D.: Water adsorption in MOFs: fundamentals and applications. Chem. Soc. Rev. 43, 5594–5617 (2014aaaa)CrossRef

Canivet, J., Bonnefoy, J., Daniel, C., Legrand, A., Coasne, B., Farrusseng, D.: Structure–property relationships of water adsorption in metal–organic frameworks. New J. Chem. 38, 3102–3111 (2014bbbb)CrossRef

Coelho, J.A., Ribeiro, A.M., Ferreira, A.F.P., Lucena, S.M.P., Rodrigues, A.E., de Azevedo, D.C.S.: Stability of an Al-fumarate MOF and its potential for CO₂ capture from wet stream. Ind. Eng. Chem. Res. 55, 2134–2143 (2016)CrossRef

DeCoste, J.B., Peterson, G.W., Jasuja, H., Glover, T.G., Huang, Y., Walton, K.S.: Stability and degradation mechanisms of metal-organic frameworks containing the Zr₆O₄(OH)₄ secondary building unit. J. Mater. Chem. A. 1, 5642–5650 (2013)CrossRef

DeVault, D.: The theory of chromatography. J. Am. Chem. Soc. 65, 532–540 (1943)CrossRef

Dietzel, P.D.C., Panella, B., Hirscher, M., Blom, R., Fjellvag, H.: Hydrogen adsorption in a nickel based coordination polymer with open metal sites in the cylindrical cavities of the desolvated framework. Chem. Commun. 9, 959–961 (2006)CrossRef

Ehrenmann, J., Henninger, S.K., Janiak, C.: Water adsorption characteristics of MIL-101 for heat-transformation applications of MOFs. Eur. J. Inorg. Chem. 2011, 471–474 (2011)CrossRef

Elsayed, E., AL-Dadah, R., Mahmoud, S., Elsayed, A., Anderson, P.A.: Aluminium fumarate and CPO-27(Ni) MOFs: characterization and thermodynamic analysis for adsorption heat pump applications. Appl. Therm. Eng. 99, 802–812 (2016)CrossRef

Furukawa, H., Gándara, F., Zhang, Y.-B., Jiang, J., Queen, W.L., Hudson, M.R., Yaghi, O.M.: Water adsorption in porous metal–organic frameworks and related materials. J. Am. Chem. Soc. 136, 4369–4381 (2014)CrossRef

Glueckauf, E.: Theory of chromatography. VII. The general theory of two solutes following non-linear isotherms. Discuss. Faraday Soc. 7, 12–25 (1949)CrossRef

Green, D.W., Perry, R.H.: Perry’s Chemical Engineers Handbook, 8th edn. McGraw-Hill, New York (2008)

Helfferich, F.G., Carr, P.W.: Non-linear waves in chromatography. I. Waves, shocks, and shapes. J. Chromatogr. A. 629, 97–122 (1993)CrossRef

Janiak, C., Henninger, S.K.: Porous coordination polymers as novel sorption materials for heat transformation processes. Chim. Int. J. Chem. 67, 419–424 (2013)CrossRef

Jeremias, F., Fröhlich, D., Janiak, C., Henninger, S.K.: Advancement of sorption-based heat transformation by a metal coating of highly-stable, hydrophilic aluminium fumarate MOF. RSC Adv. 4, 24073 (2014aaaaa)CrossRef

Jeremias, F., Frohlich, D., Janiak, C., Henninger, S.K.: Water and methanol adsorption on MOFs for cycling heat transformation processes. New J. Chem. 38, 1846–1852 (2014bbbbb)CrossRef

Karmakar, S., Dechnik, J., Janiak, C., De, S.: Aluminium fumarate metal-organic framework: a super adsorbent for fluoride from water. J. Hazard. Mater. 303, 10–20 (2016)CrossRef

Kiener, C., Muller, U., Schubert, M.: Organometallic aluminum fumarate backbone material. US Pat. App. 12/297, 666, 1, 1–9 (2009)

Ko, N., Hong, J., Sung, S., Cordova, K.E., Park, H.J., Yang, J.K., Kim, J.: A significant enhancement of water vapour uptake at low pressure by amine-functionalization of UiO-67. Dalt. Trans. 44, 2047–2051 (2015)CrossRef

Küsgens, P., Rose, M., Senkovska, I., Fröde, H., Henschel, A., Siegle, S., Kaskel, S.: Characterization of metal-organic frameworks by water adsorption. Microporous Mesoporous Mater. 120, 325–330 (2009)CrossRef

Lannoeye, J., Van de Voorde, B., Bozbiyik, B., Reinsch, H., Denayer, J., De Vos, D.: An aliphatic copper metal-organic framework as versatile shape selective adsorbent in liquid phase separations. Microporous Mesoporous Mater. 226, 292–298 (2016)CrossRef

Low, J.J., Benin, A.I., Jakubczak, P., Abrahamian, J.F., Faheem, S.A., Willis, R.R.: Virtual high throughput screening confirmed experimentally: porous coordination polymer hydration. J. Am. Chem. Soc. 131, 15834–15842 (2009)CrossRef

Park, I., Knaebel, K.S.: Adsorption breakthrough behavior: unusual effects and possible causes. AIChE J. 38, 660–670 (1992)CrossRef

Plessius, R., Kromhout, R., Ramos, A.L.D., Ferbinteanu, M., Mittelmeijer-Hazeleger, M.C., Krishna, R., Rothenberg, G., Tanase, S.: Highly selective water adsorption in a lanthanum metal-organic framework. Chemistry. 20, 7922–7925 (2014)CrossRef

Reinsch, H., van der Veen, M.A., Gil, B., Marszalek, B., Verbiest, T., de Vos, D., Stock, N.: Structures, sorption characteristics, and nonlinear optical properties of a new series of highly stable aluminum MOFs. Chem. Mater. 25, 17–26 (2013)CrossRef

Ruthven, D.M.: Principle of Adsorption and Adsorption Processes. Wiley, New York (1984)

Schmidt-Traub, H., Schulte, M., Seidel-Morgenstern, A.: Preparative Chromatography: Second Edition. Wiley, New York (2013)

Schoenecker, P.M., Carson, C.G., Jasuja, H., Flemming, C.J.J., Walton, K.S.: Effect of water adsorption on retention of structure and surface area of metal–organic frameworks. Ind. Eng. Chem. Res. 51, 6513–6519 (2012)CrossRef

Schweich, D., Sardin, M.: Adsorption, partition, ion exchange and chemical reaction in batch reactors or in columns—a review. J. Hydrol. 50, 1–33 (1981)CrossRef

Sircar, S., Kumar, R.: Adiabatic adsorption of bulk binary gas mixtures. Analysis by constant pattern model. Ind. Eng. Chem. Process Des. Dev. 22, 271–280 (1983)CrossRef

Soubeyrand-Lenoir, E., Vagner, C., Yoon, J.W., Bazin, P., Ragon, F., Hwang, Y.K., Serre, C., Chang, J.S., Llewellyn, P.L.: How water fosters a remarkable 5-fold increase in low-pressure CO₂ uptake within mesoporous MIL-100(Fe). J. Am. Chem. Soc. 134, 10174–10181 (2012)CrossRef

Thommes, M., Kaneko, K., Neimark, A.V., Olivier, J.P., Rodriguez-Reinoso, F., Rouquerol, J., Sing, K. S.W.: Physisorption of gases, with special reference to the evaluation of surface area and pore size distribution (IUPAC Technical Report). Pure Appl. Chem. 87, 1051–1069 (2015)CrossRef

Tondeur, D., Rodrigues, A.E.: Percolation Processes: Theory and Applications. Sijthoff and Noordhoff, Rockville (1981)

Van Assche, T.R.C., Duerinck, T., Gutiérrez Sevillano, J.J., Calero, S., Baron, G.V., Denayer, J.F.M.: High adsorption capacities and two-step adsorption of polar adsorbates on copper–benzene-1,3,5-tricarboxylate metal–organic framework. J. Phys. Chem. C. 117, 18100–18111 (2013)CrossRef

Van de Voorde, B., Damasceno Borges, D., Vermoortele, F., Wouters, R., Bozbiyik, B., Denayer, J., Taulelle, F., Martineau, C., Serre, C., Maurin, G., De Vos, D.: Isolation of renewable phenolics by adsorption on ultrastable hydrophobic MIL-140 metal–organic frameworks. ChemSusChem. 8, 3159–3166 (2015)CrossRef

Yan, J., Yu, Y., Ma, C., Xiao, J., Xia, Q., Li, Y., Li, Z.: Adsorption isotherms and kinetics of water vapor on novel adsorbents MIL-101(Cr)@GO with super-high capacity. Appl. Therm. Eng. 84, 118–125 (2015)CrossRef

Yot, P.G., Vanduyfhuys, L., Alvarez, E., Rodriguez, J.: Mechanical energy storage performance of an aluminum fumarate metal–organic framework. Chem. Sci. 7, 446–450 (2016)CrossRef

Titel: Stepped water isotherm and breakthrough curves on aluminium fumarate metal–organic framework: experimental and modelling study
verfasst von: Belgin Bozbiyik
Tom Van Assche
Jeroen Lannoeye
Dirk E. De Vos
Gino V. Baron
Joeri F. M. Denayer
Publikationsdatum: 09.12.2016
Verlag: Springer US
Erschienen in: Adsorption / Ausgabe 1/2017
Print ISSN: 0929-5607
Elektronische ISSN: 1572-8757
DOI: https://doi.org/10.1007/s10450-016-9847-0

Premium Partner

Marktübersichten

Die im Laufe eines Jahres in der „adhäsion“ veröffentlichten Marktübersichten helfen Anwendern verschiedenster Branchen, sich einen gezielten Überblick über Lieferantenangebote zu verschaffen.

Zur Marktübersicht

Springer Professional

Abstract

Bitte loggen Sie sich ein, um Zugang zu Ihrer Lizenz zu erhalten.

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Springer Professional "Technik"

Weitere Artikel der Ausgabe 1/2017

Elaborate control over the morphology and pore structure of porous silicas for VOCs removal with high efficiency and stability

Zeolite adsorbent-MOF layered nanovalves for CH4 storage

High-pressure sour gas adsorption on zeolite 4A

Water adsorption characteristics of MCM-41 post-modified by Al grafting and cations doping: equilibrium and kinetics study

Effect of MnCl2 deposition content on the textural properties of activated alumina and its elution performance for hydrogen isotopes

Dioxin and 1,2-dichlorobenzene adsorption in aluminosilicate zeolite Beta

Premium Partner

Marktübersichten