Strength and Deformation Properties of Low-Alloy Steel Bolts with Electroless Ni-P Coating: An Investigation of Two Thermal Routes

Low-alloy steel bolts are used in applications where high strength is needed, although they presented low corrosion resistance, limiting their application in harsh environments. Ni-P coatings could be an alternative to protect low-alloy steel bolts against corrosion. However, Ni-P coatings must be submitted to an interdiffusion post-heat treatment, which provokes severe microstructural changes in the steel substrate, lowering its strength. This research aims to investigate two new thermal routes to obtain Ni-P coatings on low-alloy steel bolts, aiming to preserve the steel substrate's resistance and deformation properties, addressing the ASTM A320/L7 requirements. The first route proposed consists of obtaining the Ni-P coating on an austempered steel substrate, instead of a quenched/tempered one. This approach resulted in less microstructural changes during the post-heat treatment, although poor impact properties were achieved. The second thermal route consists of Ni-P coating on a quenched substrate, followed by a single-step post-heat treatment aiming to temper the substrate and promote the coatings' interdiffusion at the same time. The single-step post-heat treatment performed at 600 °C for 4 h resulted in appropriated mechanical properties while assuring the creation of a proper coating/steel interdiffusion layer, showing the feasibility to use Ni-P coatings in low-alloy steel to be used in harsh environments.