Skip to main content
Erschienen in: Rheologica Acta 5/2010

01.05.2010 | Review

Stretching polymer chains

verfasst von: Malcolm Mackley

Erschienen in: Rheologica Acta | Ausgabe 5/2010

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config
loading …

Abstract

This paper is based on a presentation given at the de Gennes discussion meeting held at Chamonix in February 2009. The paper gives a personal review of the way developments relating to the stretching of polymer chains has taken place over the last 40 years. de Gennes was very influential in relation to chain dynamics concepts at the University of Bristol, where many pioneering concepts relating to chain stretching were developed by the late Sir Charles Frank and Andrew Keller. The paper reviews basic concepts on extensional rheology, droplet deformation, chain extension from extensional flow and the achievement of high chain extension for high-modulus polyethylene. The paper also reviews recent developments concerning the influence of chain stretching on polymer melt processing.

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Literatur
Zurück zum Zitat Andrews JM, Ward IM (1970) The cold drawing of high density polyethylene. J Mater Sci 5(5):411–417CrossRefADS Andrews JM, Ward IM (1970) The cold drawing of high density polyethylene. J Mater Sci 5(5):411–417CrossRefADS
Zurück zum Zitat Ball RC, Mcleish TCB (1986) A molecular approach to the spurt effect in polymer melt flow. J Polym Sci, Part B, Polym Phys 24(8):1735–1745CrossRefADS Ball RC, Mcleish TCB (1986) A molecular approach to the spurt effect in polymer melt flow. J Polym Sci, Part B, Polym Phys 24(8):1735–1745CrossRefADS
Zurück zum Zitat Berry MV, Mackley MR (1977) The six roll mill: unfolding an unstable persistently extensional flow. Phil Trans Roy Soc London 287(1337):1–16CrossRefADS Berry MV, Mackley MR (1977) The six roll mill: unfolding an unstable persistently extensional flow. Phil Trans Roy Soc London 287(1337):1–16CrossRefADS
Zurück zum Zitat Bird RB, Dorson PJ, Johnson NL (1980) Polymer solution rheology based on a finitely extensible bead spring model. J Non-Newton Fluid Mech 7:213–235MATHCrossRef Bird RB, Dorson PJ, Johnson NL (1980) Polymer solution rheology based on a finitely extensible bead spring model. J Non-Newton Fluid Mech 7:213–235MATHCrossRef
Zurück zum Zitat Bird RB, Armstrong RC, Hassager O (1987) Dynamics of polymer fluids. Wiley, Hoboken Bird RB, Armstrong RC, Hassager O (1987) Dynamics of polymer fluids. Wiley, Hoboken
Zurück zum Zitat Capaccio G, Ward IM (1975) Ultra-high-modulus linear polyethylene through controlled molecular weight and drawing. Polym Eng Sci 15:219–224CrossRef Capaccio G, Ward IM (1975) Ultra-high-modulus linear polyethylene through controlled molecular weight and drawing. Polym Eng Sci 15:219–224CrossRef
Zurück zum Zitat Coventry KD, Mackley MR (2008) Cross-slot extensional flow of polymer melts using a multi-pass rheometer. J Rheol 52:401–415CrossRefADS Coventry KD, Mackley MR (2008) Cross-slot extensional flow of polymer melts using a multi-pass rheometer. J Rheol 52:401–415CrossRefADS
Zurück zum Zitat Crowley DG, Frank FC, Mackley MR, Stephenson RG (1976) Localised flow birefringence of polyethylene oxide solutions in a four roll mill. J Polym Sci 14:1111–1119 Crowley DG, Frank FC, Mackley MR, Stephenson RG (1976) Localised flow birefringence of polyethylene oxide solutions in a four roll mill. J Polym Sci 14:1111–1119
Zurück zum Zitat de Gennes PG (1971) Reptation of a polymer chain in the presence of fixed obstacles. J Chem Phys 55:572–579CrossRefADS de Gennes PG (1971) Reptation of a polymer chain in the presence of fixed obstacles. J Chem Phys 55:572–579CrossRefADS
Zurück zum Zitat de Gennes PG (1974) Coil–stretch transition of dilute flexible polymers under ultrahigh velocity gradients. J Chem Phys 60:5030–5042CrossRefADS de Gennes PG (1974) Coil–stretch transition of dilute flexible polymers under ultrahigh velocity gradients. J Chem Phys 60:5030–5042CrossRefADS
Zurück zum Zitat Doi M, Edwards SF (1986) The theory of polymer dynamics. University Press, Oxford Doi M, Edwards SF (1986) The theory of polymer dynamics. University Press, Oxford
Zurück zum Zitat Frank FC (1970) The strength and stiffness of polymers. Proc R Soc Lond A319:127–136ADS Frank FC (1970) The strength and stiffness of polymers. Proc R Soc Lond A319:127–136ADS
Zurück zum Zitat Frank FC, Mackley MR (1976) Localized flow birefringence of polyethylene oxide solutions in a two roll mill. J Polym Sci A2(14):1121–1131 Frank FC, Mackley MR (1976) Localized flow birefringence of polyethylene oxide solutions in a two roll mill. J Polym Sci A2(14):1121–1131
Zurück zum Zitat Frank FC, Keller A, Mackley MR (1971) Polymer chain extension produced by impinging jets and its effect on polyethylene solution. Polymer 12:467–473CrossRef Frank FC, Keller A, Mackley MR (1971) Polymer chain extension produced by impinging jets and its effect on polyethylene solution. Polymer 12:467–473CrossRef
Zurück zum Zitat Grace HP (1982) Dispersion phenomena in high viscosity immiscible fluid systems and application of static mixers as dispersion devices in such systems. Chem Eng Commun 14:225–277CrossRef Grace HP (1982) Dispersion phenomena in high viscosity immiscible fluid systems and application of static mixers as dispersion devices in such systems. Chem Eng Commun 14:225–277CrossRef
Zurück zum Zitat Keller A, Machin MJ (1967) Oriented crystallization in polymers. J Macromol Sci B 1:41–91CrossRef Keller A, Machin MJ (1967) Oriented crystallization in polymers. J Macromol Sci B 1:41–91CrossRef
Zurück zum Zitat Kuhn W, Kuhn H (1943) Die Frage nach der Aufrollung von Fadenmolekeln in strömenden Lösungen. Helv Chim Acta 26:1394–1465CrossRef Kuhn W, Kuhn H (1943) Die Frage nach der Aufrollung von Fadenmolekeln in strömenden Lösungen. Helv Chim Acta 26:1394–1465CrossRef
Zurück zum Zitat Likhtman AE, Graham RS (2003) Simple constitutive equation for linear polymer melts derived from molecular theory: the ROLIEPOLY equation. J Non-Newton Fluid Mech 114(1):1–12MATHCrossRef Likhtman AE, Graham RS (2003) Simple constitutive equation for linear polymer melts derived from molecular theory: the ROLIEPOLY equation. J Non-Newton Fluid Mech 114(1):1–12MATHCrossRef
Zurück zum Zitat Mackley MR, Keller A (1975) Flow induced polymer chain extension and its relationship to fibrous crystallization. Phil Trans R Soc London A278(29):4–79 Mackley MR, Keller A (1975) Flow induced polymer chain extension and its relationship to fibrous crystallization. Phil Trans R Soc London A278(29):4–79
Zurück zum Zitat Mackley MR, Solbai S (1987) Swell drawing; a new process for manufacturing high performance polyethylene. Polymer 28:1115–1120CrossRef Mackley MR, Solbai S (1987) Swell drawing; a new process for manufacturing high performance polyethylene. Polymer 28:1115–1120CrossRef
Zurück zum Zitat Mackley MR, Marshall RTJ, Smeulders JBAF (1995) The multipass rheometer. J Rheol 39(6):1293–1309CrossRefADS Mackley MR, Marshall RTJ, Smeulders JBAF (1995) The multipass rheometer. J Rheol 39(6):1293–1309CrossRefADS
Zurück zum Zitat McLeish TCB, Larson RC (1998) Molecular constitutive equations for a class of branched polymers: the pom-pom polymer. J Rheol 42(1):81–110CrossRefADS McLeish TCB, Larson RC (1998) Molecular constitutive equations for a class of branched polymers: the pom-pom polymer. J Rheol 42(1):81–110CrossRefADS
Zurück zum Zitat Odell JA, Carrington SP (2006) Extensional flow oscillatory rheometry. J Non-Newton Fluid Mech 137:110–120CrossRef Odell JA, Carrington SP (2006) Extensional flow oscillatory rheometry. J Non-Newton Fluid Mech 137:110–120CrossRef
Zurück zum Zitat Pearson D, Herbolzheimer E, Grizzuti N, Marrucci G (1991) Transient behaviour of entangled polymers at high shear rates. J Polym Sci B 29(13):1589–1597CrossRef Pearson D, Herbolzheimer E, Grizzuti N, Marrucci G (1991) Transient behaviour of entangled polymers at high shear rates. J Polym Sci B 29(13):1589–1597CrossRef
Zurück zum Zitat Pennings AJ, van der Mark JMMA, Booj HC (1970) Hydrodynamically induced crystallization of polymers from solution. Kolloid-Z Z Polym 236:99–111CrossRef Pennings AJ, van der Mark JMMA, Booj HC (1970) Hydrodynamically induced crystallization of polymers from solution. Kolloid-Z Z Polym 236:99–111CrossRef
Zurück zum Zitat Peterlin A (1966) Hydrodynamics of linear macromolecules. Pure Appl Chem 12:563–585CrossRef Peterlin A (1966) Hydrodynamics of linear macromolecules. Pure Appl Chem 12:563–585CrossRef
Zurück zum Zitat Scrivener O, Berner C, Cressely R, Hocquart R, Sellin R, Vlaches NS (1979) Dynamical behaviour of drag-reducing polymer solutions. J Non-Newton Fluid Mech 5:475–495CrossRef Scrivener O, Berner C, Cressely R, Hocquart R, Sellin R, Vlaches NS (1979) Dynamical behaviour of drag-reducing polymer solutions. J Non-Newton Fluid Mech 5:475–495CrossRef
Zurück zum Zitat Sentmanat M, Wang BN, McKinley GH (2005) Measuring the transient extensional rheology of polyethylene melts using the SER universal testing platform. J Rheol 49(2):585–606CrossRefADS Sentmanat M, Wang BN, McKinley GH (2005) Measuring the transient extensional rheology of polyethylene melts using the SER universal testing platform. J Rheol 49(2):585–606CrossRefADS
Zurück zum Zitat Smith P, Lemstra PJ (1980) Ultra-high-strength polyethylene filaments by solution spinning/drawing. J Mater Sci 15:505–514CrossRefADS Smith P, Lemstra PJ (1980) Ultra-high-strength polyethylene filaments by solution spinning/drawing. J Mater Sci 15:505–514CrossRefADS
Zurück zum Zitat Taylor GI (1923) Stability of a viscous liquid contained between two rotating cylinders. Phil Trans 223A:289–343ADS Taylor GI (1923) Stability of a viscous liquid contained between two rotating cylinders. Phil Trans 223A:289–343ADS
Zurück zum Zitat Taylor GI (1934) The formation of emulsions in definable fields of flow. Proc R Soc Lond Al46:501–523ADS Taylor GI (1934) The formation of emulsions in definable fields of flow. Proc R Soc Lond Al46:501–523ADS
Zurück zum Zitat Thom R (1972) Stabilite structurelle et morphogenes. Benjamin, Reading (English trans. (1975) Structural stability and morphogenesis) Thom R (1972) Stabilite structurelle et morphogenes. Benjamin, Reading (English trans. (1975) Structural stability and morphogenesis)
Zurück zum Zitat Treloar LR (1975) The physics of rubber elasticity, 3rd edn. Clarendon, Oxford Treloar LR (1975) The physics of rubber elasticity, 3rd edn. Clarendon, Oxford
Zurück zum Zitat Trouton FT (1906) On the coefficient of viscous traction and its relation to that of viscosity. Proc R Soc Lond A77:426–440ADS Trouton FT (1906) On the coefficient of viscous traction and its relation to that of viscosity. Proc R Soc Lond A77:426–440ADS
Zurück zum Zitat Verbeeten WMH, Peters GWM, Baaijens FPT (2002) Viscoelastic analysis of complex polymer melt flows using the eXtended Pom-Pom model. J Non-Newton Fluid Mech 108:301–326MATHCrossRef Verbeeten WMH, Peters GWM, Baaijens FPT (2002) Viscoelastic analysis of complex polymer melt flows using the eXtended Pom-Pom model. J Non-Newton Fluid Mech 108:301–326MATHCrossRef
Zurück zum Zitat Wagner MH, Hepperle J, Münstedt H (2004) Relating rheology and molecular structure of model branched polystyrene melts by molecular stress function theory. J Rheol 48(2):489–503CrossRefADS Wagner MH, Hepperle J, Münstedt H (2004) Relating rheology and molecular structure of model branched polystyrene melts by molecular stress function theory. J Rheol 48(2):489–503CrossRefADS
Zurück zum Zitat Willmouth FM, Keller A, Ward IM, Williams T (1968) Gel permeation chromatographic studies of the degradation of polyethylene with fuming nitric acid. III. Fibrous stirring-induced crystals. J Polym Sci 6(9):1627–1637 Willmouth FM, Keller A, Ward IM, Williams T (1968) Gel permeation chromatographic studies of the degradation of polyethylene with fuming nitric acid. III. Fibrous stirring-induced crystals. J Polym Sci 6(9):1627–1637
Zurück zum Zitat Zeeman EC (1997) Catastrophe theory: selected papers 1972–77. Addison Wesley, Boston Zeeman EC (1997) Catastrophe theory: selected papers 1972–77. Addison Wesley, Boston
Zurück zum Zitat Ziabicki A (1959) Studies on orientation phenomena by fiber formation from polymer melts. Part II. Theoretical considerations. J Appl Polym Sci 2:24–31CrossRef Ziabicki A (1959) Studies on orientation phenomena by fiber formation from polymer melts. Part II. Theoretical considerations. J Appl Polym Sci 2:24–31CrossRef
Zurück zum Zitat Zwijnenburg A, Pennings AJ (1975) Longitudinal growth of polymer crystals from flowing solutions III. Polyethylene crystals in Couette flow. Colloid Polym Sci 254(10):868–881 Zwijnenburg A, Pennings AJ (1975) Longitudinal growth of polymer crystals from flowing solutions III. Polyethylene crystals in Couette flow. Colloid Polym Sci 254(10):868–881
Metadaten
Titel
Stretching polymer chains
verfasst von
Malcolm Mackley
Publikationsdatum
01.05.2010
Verlag
Springer-Verlag
Erschienen in
Rheologica Acta / Ausgabe 5/2010
Print ISSN: 0035-4511
Elektronische ISSN: 1435-1528
DOI
https://doi.org/10.1007/s00397-010-0435-z

Weitere Artikel der Ausgabe 5/2010

Rheologica Acta 5/2010 Zur Ausgabe

    Marktübersichten

    Die im Laufe eines Jahres in der „adhäsion“ veröffentlichten Marktübersichten helfen Anwendern verschiedenster Branchen, sich einen gezielten Überblick über Lieferantenangebote zu verschaffen.