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Erschienen in: Journal of Materials Science: Materials in Electronics 7/2016

14.03.2016

Structure and dielectric properties of zinc borate glass–ceramics modified by magnesium

verfasst von: Hongtao Yu, Jingsong Liu, Mengshi Zeng, Lei He

Erschienen in: Journal of Materials Science: Materials in Electronics | Ausgabe 7/2016

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Abstract

The effects of magnesium substitution for zinc in zinc borate glass–ceramics [xMgO–(3 − x)ZnO–2B2O3 where x = 0, 0.1, 0.2, 0.3] prepared by conventional solid state on structure, crystallized temperature and dielectric properties were investigated. Fourier transform infrared spectrometer was used to investigate the variations of the glass structure. With increasing magnesium amount, the non-bridge oxygen amount increased, lowering the crystallized temperature. Surplus substitution leaded to the formation of boroxol rings and [MgO4] groups in the glass structure, strengthening the glass structure. Thus, the crystallized temperature increased. Two main crystalline phases of α-Zn(BO2)2 and Zn3B2O6 were found at the x level of 0 and 0.1 for the sintered samples, while Mg3B2O6 appeared when the magnesium substitution achieved to 0.2 and 0.3. Further, the magnesium-substitution lowered the dielectric constant slightly due to its relatively low ionic polarizability and low magnesium content. When the 0.2 mol magnesium amounts was substituted for zinc, the specimens showed the optimal dielectric properties, with a dielectric constant of 6.7 and a dielectric loss of 1 × 10−3 after sintering at 640 °C for 30 min, which demonstrated a good potential for use in low temperature co-fired ceramic technology.
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Metadaten
Titel
Structure and dielectric properties of zinc borate glass–ceramics modified by magnesium
verfasst von
Hongtao Yu
Jingsong Liu
Mengshi Zeng
Lei He
Publikationsdatum
14.03.2016
Verlag
Springer US
Erschienen in
Journal of Materials Science: Materials in Electronics / Ausgabe 7/2016
Print ISSN: 0957-4522
Elektronische ISSN: 1573-482X
DOI
https://doi.org/10.1007/s10854-016-4673-4