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Journal of Coatings Technology and Research
Erschienen in: Journal of Coatings Technology and Research 1/2018

23.10.2017

Structure–property correlations of foul release coatings based on low hard segment content poly(dimethylsiloxane–urethane–urea)

verfasst von: Sangram K. Rath, Jayesh G. Chavan, Tanaji K. Ghorpade, T. Umasankar Patro, Manoranjan Patri

Erschienen in: Journal of Coatings Technology and Research | Ausgabe 1/2018

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Abstract

We report the foul release characteristics of model poly(dimethylsiloxane–urethane–urea) (PDMSPU)-based coatings with a relatively lower hard segment content of 9 to 13.7 wt%. The PDMSPUs were prepared by facile moisture curing of isophorone diisocyanate-capped hydroxyalkyl-terminated PDMS. The surface free energies of the coatings were tuned (20–25 mJ/m2) by varying the hard segment content to be in the minimum adhesive regime (20–30 mJ/m2) of Baier’s curve pertaining to the relative amount of biofouling vs the critical surface tension of various chemical substrates. A series of complimentary analytical tools, namely 1H NMR spectroscopy, small-angle x-ray scattering (SAXS), FTIR-attenuated total reflectance spectroscopy (FTIR-ATR), contact angle goniometry, marine field tests, and quantitative biofouling adhesion in shear, have been employed to deduce several physicochemical parameters of importance to establish the structure property correlations. Further, the time-dependant changes in surface wettability and surface concentration of polar functional groups of the coatings (immersed in 3.5 wt% aqueous solution of NaCl) were investigated by FTIR-ATR and contact angle goniometry. The extent of surface restructuring was found to increase with increasing hard segment content of the PDMSPUs and consequently increasing attachment strengths of macrofoulants with the coatings, which were in the range 0.12–0.5 MPa.
Vorheriger Artikel A novel adsorption method to simulate the dirt pickup performance of organic coatings
Nächster Artikel Flexible, hard, and tough biobased polyurethane thermosets from renewable materials: glycerol and 10-undecenoic acid

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Literatur
1.
Schultz, MP, “Effects of Coating Roughness and Biofouling on Ship Resistance and Powering.” Biofouling, 23 331–341 (2007)CrossRef
2.
Townsin, RL, “The Ship Hull Fouling Penalty.” Biofouling, 19 9–16 (2003)CrossRef
3.
Schultz, MP, Bendick, JA, Holm, ER, Hertel, WM, “Economic Impact of Biofouling on a Naval Surface Ship.” Biofouling, 27 87–98 (2011)CrossRef
4.
Callow, JA, Callow, ME, “Trends in the Development of Environmentally Friendly Fouling-Resistant Marine Coatings.” Nat. Commun., 2 (244) 1–10 (2011)
5.
Lejars, M, Margaillan, A, Bressy, C, “Fouling Release Coatings: A Nontoxic Alternative to Biocidal Antifouling Coatings.” Chem. Rev., 112 4347–4390 (2012)CrossRef
6.
Grozea, CM, Walker, GC, “Approaches in Designing Non-Toxic Polymer Surfaces to Deter Marine Biofouling.” Soft Matter, 5 4088–4100 (2009)CrossRef
7.
Rosenhahn, A, Schilp, S, Kreuzer, HJ, Grunze, M, “The Role of Inert Surface Chemistry in Marine Biofouling Prevention.” Phys. Chem. Chem. Phys., 12 4275–4286 (2010)CrossRef
8.
Krishnan, S, Weinman, CJ, Ober, CK, “Advances in Polymers for Anti-Biofouling Surfaces.” J. Mater. Chem., 18 3405–3413 (2008)CrossRef
9.
Nurioglu, AG, Esteves, ACC, de With, GJ, “Non-toxic, Non-Biocide-Release Antifouling Coatings Based on Molecular Structure Design for Marine Applications.” J. Mater. Chem. B, 3 6547–6570 (2015)CrossRef
10.
Yang, WJ, Neoh, KG, Kang, E, Teo, SLM, Rittschof, D, “Polymer Brush Coatings For Combating Marine Biofouling.” Prog. Polym. Sci., 39 1017–1042 (2014)CrossRef
11.
Martinelli, E, Guazzelli, E, Bartoli, C, Gazzari, M, Chiellini, F, Galli, G, Callow, ME, Callow, JA, Finlay, JA, Hill, S, “Amphiphilic Pentablock Copolymers and Their Blends with PDMS for Antibiofouling Coatings.” J. Polym. Sci. Part A, Polym. Chem., 53 1213–1225 (2015)CrossRef
12.
Hawkins, ML, Faÿ, F, Rèhel, K, Linossier, I, Grunlan, MA, “Bacteria and Diatom Resistance of Silicones Modified With PEO-Silane Amphiphiles.” Biofouling, 30 247–258 (2014)CrossRef
13.
Martinelli, E, Sarvothaman, MK, Galli, G, Pettitt, MI, Callow, ME, Callow, JA, Conlan, SL, Clare, S, Sugiharto, AB, Davies, C, Williams, D, “Polydimethyl Siloxane (PDMS) Network Blends of Amphiphilic Acrylic Copolymer with Poly(ethylene glycol)-Fluoroalkyl Side Chains for Foul Release Coatings. II. Laboratory Assays & Field Immersion Trials.” Biofouling, 28 571–582 (2012)CrossRef
14.
Pereira, M, Ankjaergaard, C, Advances in Marine Antifouling Coatings and Technologies, p. 240. Woodshead Publishing, Cambridge, UK (2009)CrossRef
15.
Schultz, MP, Kavanagh, CJ, Swain, GW, “Hydrodynamic Forces on Barnacles: Implications on Detachment From Fouling Release Surfaces.” Biofouling, 13 323–335 (1999)CrossRef
16.
Stein, J, Truby, K, Wood, MD, Takemori, M, Vallance, M, Swain, G, Kavanagh, CJ, Kovach, B, Schultz, M, Weibe, D, Holm, E, Montemarano, J, Wendt, D, Smith, C, Meyer, A, “Structure-Property Relationships of Silicone Biofouling-Release Coatings: Effect of Silicone Network Architecture on Pseudobarnacle Attachment Strengths.” Biofouling, 19 87–94 (2003)CrossRef
17.
Brady, RF, “Properties Which Influence Marine Fouling Resistance in Polymers Containing Silicon and Fluorine.” Prog. Org. Coat., 35 31–35 (1999)CrossRef
18.
Chaudhury, MK, Finlay, JA, Chung, JY, Callow, ME, Callow, JA, “The Influence of Elastic Modulus and Thickness on the Release of the Soft-Fouling Green Alga Ulva Linza (Syn. Enteromorpha Linza) From Poly(dimethylsiloxane) (PDMS) Model Networks.” Biofouling, 21 41–48 (2005)CrossRef
19.
Dyong, TH, Briand, JF, Margaillan, A, Bressy, C, “Polysiloxane-Based Block Copolymers with Marine Bacterial Anti-Adhesion Properties.” ACS Appl. Mater. Interfaces, 7 15578–15586 (2015)CrossRef
20.
Beigbeder, A, Degee, P, Conlan, SL, Mutton, RJ, Clare, AS, Pettitt, ME, Callow, ME, Callow, JA, Dubois, P, “Preparation and Characterisation of Silicone-Based Coatings Filled With Carbon Nanotubes and Natural Sepiolite and Their Application as Marine Fouling-Release Coatings.” Biofouling, 24 291–302 (2008)CrossRef
21.
Kavanagh, CJ, Swain, GW, Kovach, BS, Stein, J, Wood, CD, Truby, K, Holm, E, Montemarano, J, Meyer, A, Wiebe, D, “The Effects of Silicone Fluid Additives and Silicone Elastomer Matrices on Barnacle Adhesion Strength.” Biofouling, 19 381–390 (2003)CrossRef
22.
Webster, DC, Pieper, RJ, Ekin, A, “Thermoset Siloxane-Urethane Fouling Release Coatings.” US20080213599 (2008)
23.
Joshi, RG, Goel, A, Mannari, VM, Finlay, JA, Callow, ME, Callow, JA, “Evaluating Fouling-Resistance and Fouling-Release Performance of Smart Polyurethane Surfaces: An Outlook for Efficient and Environmentally Benign Marine Coatings.” J. Appl. Polym. Sci., 114 3693–3703 (2009)CrossRef
24.
Pieper, RJ, Ekin, A, Webster, DC, Casse, F, Callow, JA, Callow, ME, “The Effect of Formulation Variables on Fouling-Release Performance of Stratified Siloxane-Polyurethane Coatings.” J. Coat. Technol. Res., 9 235–249 (2012)CrossRef
25.
Galhenage, TP, Webster, DC, Moreira, AMS, Burgett, J, Staslien, SH, Vanderwal, L, Finlay, JA, Clare, AS, “Poly(ethylene) Glycol-Modified, Amphiphilic, Siloxane-Polyurethane Coatings and Their Performance as Fouling-Release Surfaces.” J. Coat. Technol. Res., 14 307–322 (2017)CrossRef
26.
Fang, J, Kelarakis, A, Wang, DY, Giannelis, EP, Finlay, JA, Callow, ME, Callow, JA, “Fouling Release Nanostructured Coatings based on PDMS-Polyurea Segmented Copolymer.” Polymer, 51 2636–2642 (2010)CrossRef
27.
Adkins, JD, Mera, AE, Roe-Short, MA, Pawlikowski, GT, Brady, RF, “Novel Non-Toxic Coatings Designed to Resist Marine Fouling.” Prog. Org. Coat., 29 1–5 (1996)CrossRef
28.
Sommer, S, Webster, DC, Stafslien, SJ, Daniels, J, VanderWal, LJ, Thompson, SE, Callow, ME, Callow, JE, “A Preliminary Study on the Properties and Fouling-Release Performance of Siloxane-Polyurethane Coatings Prepared from Poly(dimethylsiloxane) (PDMS) Macromers.” Biofouling, 26 961–972 (2010)CrossRef
29.
Chen, Z, Chisholm, B, Kim, J, Stafslien, S, Wagner, R, Patel, S, Daniels, J, Vandewal, L, Li, J, Ward, K, Callow, M, Thompson, S, “UV-Curable, Oxetane Toughened Epoxy-Siloxane Coatings for Marine Fouling Release Coating Applications.” Polym. Int., 57 879–886 (2008)CrossRef
30.
Rath, SK, Chavan, JG, Sasane, S, Srivastava, A, Patri, M, Samui, AB, Chakraborty, BC, Sawant, SN, “Coatings of PDMS-Modified Epoxy via Urethane Linkage: Segmental Correlation Length, Phase Morphology, Thermomechanical and Surface Behaviour.” Prog. Org. Coat., 65 366–374 (2009)CrossRef
31.
Rath, SK, Chavan, JG, Sasane, S, Patri, M, Samui, AB, Chakraborty, BC, “Two Component Silicone Modified Epoxy Foul Release Coatings: Effect of Modulus, Surface Energy and Surface Restructuring on Pseudobarnacle and Macrofouling Behaviour.” Appl. Surf. Sci., 256 2440–2446 (2010)CrossRef
32.
Majumdar, P, Webster, DC, “Preparation of Siloxane − Urethane Coatings Having Spontaneously Formed Stable Biphasic Microtopographical Surfaces.” Macromolecules, 38 5857–5859 (2005)CrossRef
33.
Pieper, RJ, Ekin, A, Webster, DC, Casse, F, Callow, JA, Callow, ME, “Combinatorial Approach to Study the Effect of Acrylic Polyol Composition on the Properties of Crosslinked Siloxane-Polyurethane Fouling-Release Coatings.” J. Coat. Technol. Res. 4 453–461(2007)
34.
Ekin, A, Webster, DC, Daniels, JW, Stafslien, SJ, Casse, F, Callow, JA, Callow, ME, “Synthesis, Formulation, and Characterization of Siloxane-Polyurethane Coatings for Underwater Marine Applications Using Combinatorial High-Throughput Experimentation.” J. Coat. Technol. Res., 4 435–451 (2007)CrossRef
35.
Majumdar, P, Stafslien, S, Daniels, J, Webster, DC, “High Throughput Combinatorial Characterization of Thermosetting Siloxane-Urethane Coatings Having Spontaneously Formed Microtopographical Surfaces.” J. Coat. Technol. Res., 4 131–138 (2007)CrossRef
36.
Luzinova, I, Minkob, S, Tsukrukc, VV, “Adaptive and Responsive Surfaces Through Controlled Reorganization of Interfacial Polymer Layers.” Prog. Polym. Sci., 29 635–698 (2004)CrossRef
37.
Esteves, ACC, Günbas, ID, vanRiel, JM, Noordover, BAJ, de With, G, van Benthem, RATM, “Time-resolved Surface Rearrangements of Polymer Films Monitored by Dynamic Recovery Contact Angle (DRCA).” RSC Adv, 4 20094–20101 (2014)CrossRef
38.
Koberstein, JT, “Molecular Design of Functional Polymer Surfaces.” J. Polym. Sci., Part B:Polym. Phys. 42 2942–2956 (2004)
39.
Pike, JK, Ho, T, Wynne, KJ, “Water-Induced Surface Rearrangements of Poly(dimethylsiloxane − urea − urethane) Segmented Block Copolymers.” Chem. Mater., 8 856–860 (1996)CrossRef
40.
Chatelier, RC, Xie, X, Gengenbach, TR, Griesser, HJ, “Quantitative Analysis of Polymer Surface Restructuring.” Langmuir, 11 2576–2584 (1995)CrossRef
41.
Martinelli, E, Sarvothaman, MK, Alderighi, M, Galli, G, Mielczarski, E, Mieczarski, JA, “PDMS Network Blends of Amphiphilic Acrylic Copolymers with Poly(ethylene glycol)-Fluoroalkyl Side Chains for Fouling-Release Coatings I. Chemistry and Stability of the Film Surface.” J. Polym. Sci. Part A. Polym. Chem., 50 2677–2686 (2012)CrossRef
42.
Martinelli, E, Gunes, D, Wenning, BM, Ober, CK, Finlay, JA, Callow, ME, Callow, JA, Fino, AD, Clare, AS, Galli, G, “Effects of Surface Active Block Copolymers with Oxyethylene and Fluoroalkyl Side Chains on the Antifouling Performance of Silicone-based Films.” Biofouling, 32 81–93 (2016)CrossRef
43.
Vaidya, A, Chaudhury, MK, “Synthesis and Surface Properties of Environmentally Responsive Segmented Polyurethanes.” J. Colloid Interface Sci., 249 235–245 (2002)CrossRef
44.
Baszkin, A, Ter-Minassian-Saraga, L, “Effect of Temperature on the Wettability of Oxidized Polyethylene Films.” Polymer, 15 759–760 (1974)CrossRef
45.
Holly, FJ, Refojo, M, “Wettability of Hydrogels I. Poly(2-hydroxyethyl methacrylate).” J. Biomed. Mater. Res., 9 315–326 (1976)CrossRef
46.
Tezuka, Y, Kazama, H, Imai, K, “Environmentally Induced Macromolecular Rearrangement on the Surface of Polyurethane-Polysiloxane Block Copolymers.” J. Chem. Soc. Faraday Trans, 87 147–152 (1991)CrossRef
47.
Tezuka, Y, Ono, T, Imai, K, “Environmentally Induced Macromolecular Rearrangement on the Surface of Polyurethane-Polysiloxane Graft Copolymers.” J. Colloid Interface Sci., 136 408–414 (1990)CrossRef
48.
Chavan, JG, Rath, SK, Kalletla, S, Praveen, S, Patri, M, “Hydrogen Bonding and Thermomechanical Properties of Model Polydimethylsiloxane based Poly(urethane-urea) Copolymers: Effect of Hard Segment Content.” Prog. Org. Coat., 90 350–358 (2016)CrossRef
49.
Rath, SK, Patri, M, Khakhar, DV, “Structure–Thermomechanical Property Correlation of Moisture Cured Poly(urethane-urea)/Clay Nanocomposite Coatings.” Prog. Org. Coat., 75 264–273 (2012)CrossRef
50.
Rath, SK, Ishack, AM, Suryawansi, UG, Patri, M, “Phase Morphology and Surface Properties of Moisture Cured Polyurethane-Urea (MCPU) Coatings: Effect of Catalysts.” Prog. Org. Coat., 62 393–399 (2008)CrossRef
51.
Pandey, S, Rath, SK, Samui, AB, “Structure–Thermomechanical Property Correlations of Highly Branched Siloxane-Urethane Networks.” Ind. Eng. Chem. Res., 51 3531–3540 (2012)CrossRef
52.
Harrick, NJ, Internal Reflection Spectroscopy. John Wiley & Sons, Int, New York (1967)
53.
Owens, DK, Wendt, RC, “Estimation of the Surface Free Energy of Polymers.” J. Appl. Polym. Sci., 13 1741–1747 (1969)CrossRef
54.
Swain, GW, Schultz, MP, “The Testing and Evaluation of Non-Toxic Antifouling Coatings.” Biofouling, 18 187–197 (1996)CrossRef
55.
Li, S, Feng, S, Li, S, “Preparation of Uniform Poly(urea–siloxane) Microspheres Through Precipitation Polymerization.” RSC Adv., 5 90313–90320 (2015)CrossRef
56.
Garrett, JT, Runt, J, Lin, JS, “Microphase Separation of Segmented Poly(urethane urea) Block Copolymers.” Macromolecules, 33 6353–6359 (2000)CrossRef
57.
Chuang, FS, Tsi, HY, Chow, JD, Tsen, WC, Shu, YC, Jang, SC, “Thermal Degradation of Poly(siloxane-urethane) Copolymers.” Polym. Degrad. Stab., 93 1753–1761 (2008)CrossRef
58.
Chen, X, Gardella, JA, Jr, Ho, T, Wynne, KJ, “Surface Composition of a Series of Dimethylsiloxane Urea Urethane Segmented Copolymers Studied by Electron Spectroscopy for Chemical Analysis.” Macromolecules, 28 1635–1642 (1995)CrossRef
59.
Yilgor, I, Eynur, T, Yilgor, E, Wilkes, GL, “Contribution of Soft Segment Entanglement on the Tensile Properties of Silicone-Urea Copolymers with Low Hard Segment Contents.” Polymer, 50 4432–4437 (2009)CrossRef
60.
Stefslien, SJ, Summer, S, Webster, DC, Bodhke, R, Pieper, R, Danniels, J, Wal, LV, Callow, MC, Callow, JA, Raalston, E, Brewer, L, Wendt, D, Dickinson, GH, Lim, CS, Teo, SLM, “Comparison of Laboratory and Field Testing Performance Evaluations of Siloxane-Polyurethane Fouling-Release Marine Coatings.” Biofouling, 32 949–968 (2016)CrossRef
61.
Baier, RE, “Surface Behaviour of Biomaterials: The Theta Surface for Biocompatibility.” J. Mater. Sci.: Mater. Med. 17 1057–1062 (2006)
62.
Lim, LT, Britt, IJ, Tung, MA, “Sorption and Transport of Water Vapor in Nylon 6,6 Film.” J. Appl. Polym. Sci., 71 197–206 (1999)CrossRef
63.
Wang, W, Jin, Y, Su, Z, “Spectroscopic Study on Water Diffusion in Poly(ester urethane) Block Copolymer Matrix.” J. Phys. Chem. B, 113 15742–15746 (2009)CrossRef
64.
Yang, B, Huang, WM, Li, C, Li, L, “Effects of Moisture on the Thermomechanical Properties of a Polyurethane Shape Memory Polymer.” Polymer, 47 1348–1356 (2006)CrossRef
65.
Sharp, KA, Madan, B, Manas, E, Vanderkooi, JM, “Water Structure Changes Induced by Hydrophobic and Polar Solutes Revealed by Simulations and Infrared Spectroscopy.” J. Chem. Phys., 114 1791–1795 (2001)CrossRef
Metadaten
Titel
Structure–property correlations of foul release coatings based on low hard segment content poly(dimethylsiloxane–urethane–urea)
verfasst von
Sangram K. Rath
Jayesh G. Chavan
Tanaji K. Ghorpade
T. Umasankar Patro
Manoranjan Patri
Publikationsdatum
23.10.2017
Verlag
Springer US
Erschienen in
Journal of Coatings Technology and Research / Ausgabe 1/2018
Print ISSN: 1547-0091
Elektronische ISSN: 1935-3804
DOI
https://doi.org/10.1007/s11998-017-9982-x

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