Skip to main content
Erschienen in: Polymer Bulletin 7/2020

30.08.2019 | Original Paper

Study of mechanical, enzymatic degradation and antimicrobial properties of poly(butylene succinate)/pine-resin blends

verfasst von: Robert Chang, Roselyn Lata, David Rohindra

Erschienen in: Polymer Bulletin | Ausgabe 7/2020

Einloggen

Aktivieren Sie unsere intelligente Suche um passende Fachinhalte oder Patente zu finden.

search-config
loading …

Abstract

Pine resin obtained from the plant (Pinus CaribaeaHondurensis) was melt blended with poly(butylene succinate) (PBS) in mass ratios of the pine resin up to 50 wt%. The blends were tested for mechanical strength, melting and decomposition temperature and internal and spherulitic morphology using tensile test, differential scanning calorimetry, thermogravimetric analysis, scanning electron microscopy (SEM) and polarized microscopy, respectively. Enzymatic degradation of PBS and the pine-resin blends were investigated by porcine pancreatic and candida rugosa lipases while the antimicrobial property was studied against Pseudomonas aeruginosa, Escherichia coli, Bacillus subtilis and Staphylococcus aureas using the zone inhibition method. The two components were reported to be miscible and in blends with low pine resin, the thermal stability was similar to PBS. SEM micrographs showed homogeneity in the morphology of the blends. The mechanical properties of the blends showed a decrease in Young’s modulus, but an improvement in flexibility was seen when compared to PBS. Enzymatic degradation was prominent in pine resin and blends containing pine-resin content but not with PBS. The pine resin was active against all the bacteria tested except E. coli while the blends were active against P. aeruginosa and B. subtilis.

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Literatur
1.
Zurück zum Zitat Kumar A, Karthick K, Arumugam KP (2011) Biodegradable polymers and its applications. Int J Biosci Biochem Bioinf 1:173–176 Kumar A, Karthick K, Arumugam KP (2011) Biodegradable polymers and its applications. Int J Biosci Biochem Bioinf 1:173–176
2.
Zurück zum Zitat Al-Rawajfeh AE, Al-Salah HA, Al-Rhael I (2006) Miscibility, crystallinity and morphology of polymer blends of polyamide-6/poly (β-hydroxybutyrate). Jordan J Chem 1:155–170 Al-Rawajfeh AE, Al-Salah HA, Al-Rhael I (2006) Miscibility, crystallinity and morphology of polymer blends of polyamide-6/poly (β-hydroxybutyrate). Jordan J Chem 1:155–170
3.
Zurück zum Zitat Ciardelli G, Chiono V, Vozzi G, Pracella M, Ahluwalia A, Barbani N, Cristallini C, Giusti P (2005) Blends of poly-(epsilon-caprolactone) and polysaccharides in tissue engineering applications. Biomacromolecules 6:1961–1976CrossRef Ciardelli G, Chiono V, Vozzi G, Pracella M, Ahluwalia A, Barbani N, Cristallini C, Giusti P (2005) Blends of poly-(epsilon-caprolactone) and polysaccharides in tissue engineering applications. Biomacromolecules 6:1961–1976CrossRef
4.
Zurück zum Zitat Sarasam A, Madihally SV (2005) Characterization of chitosan–polycaprolactone blends for tissue engineering applications. Biomaterials 26:5500–5508CrossRef Sarasam A, Madihally SV (2005) Characterization of chitosan–polycaprolactone blends for tissue engineering applications. Biomaterials 26:5500–5508CrossRef
6.
Zurück zum Zitat Xu J, Guo BH (2010) Poly(butylene succinate) and its copolymers: research, development and industrialization. Biotechnol J 5:1149–1163CrossRef Xu J, Guo BH (2010) Poly(butylene succinate) and its copolymers: research, development and industrialization. Biotechnol J 5:1149–1163CrossRef
7.
Zurück zum Zitat Chavalitpanya K, Phattanarudee S (2013) Poly(lactic acid)/polycaprolactone blends compatibilized with block copolymer. Energy Proc 34:542–548CrossRef Chavalitpanya K, Phattanarudee S (2013) Poly(lactic acid)/polycaprolactone blends compatibilized with block copolymer. Energy Proc 34:542–548CrossRef
9.
Zurück zum Zitat Álvarez-Paino M, Muñoz-Bonilla A, Fernández-Garcìa M (2017) Antimicrobial polymers in the nano-world. Nanomaterials 48:1–44 Álvarez-Paino M, Muñoz-Bonilla A, Fernández-Garcìa M (2017) Antimicrobial polymers in the nano-world. Nanomaterials 48:1–44
10.
Zurück zum Zitat Muñoz-Bonilla A, Echeverria C, Sonseca Á, Arrieta MP, Fernández-Garcìa M (2019) Bio-based polymers with antimicrobial properties towards sustainable development. Materials 12:641CrossRef Muñoz-Bonilla A, Echeverria C, Sonseca Á, Arrieta MP, Fernández-Garcìa M (2019) Bio-based polymers with antimicrobial properties towards sustainable development. Materials 12:641CrossRef
11.
Zurück zum Zitat Have R, Teunissen PJ (2001) Oxidative mechanisms involved in lignin degradation by white-rot fungi. Chem Rev 101:3397–3413CrossRef Have R, Teunissen PJ (2001) Oxidative mechanisms involved in lignin degradation by white-rot fungi. Chem Rev 101:3397–3413CrossRef
12.
Zurück zum Zitat Adler E (1957) Structural elements of lignin. Ind Eng Chem 49:1377–1383CrossRef Adler E (1957) Structural elements of lignin. Ind Eng Chem 49:1377–1383CrossRef
13.
Zurück zum Zitat Di Maggio J (2014) In Callison Pacific pine chemicals LLC. In: PCA international conference, Seattle Washington Di Maggio J (2014) In Callison Pacific pine chemicals LLC. In: PCA international conference, Seattle Washington
14.
Zurück zum Zitat Wang J, Yao K, Korich AL, Li S, Ma S, Ploehn HJ, Iovine PM, Wang C, Chu F, Tang C (2011) Combining renewable gum rosin and lignin: towards hydrophobic polymer composites by controlled polymerization. J Polym Sci A Polym Chem 49:3728–3738CrossRef Wang J, Yao K, Korich AL, Li S, Ma S, Ploehn HJ, Iovine PM, Wang C, Chu F, Tang C (2011) Combining renewable gum rosin and lignin: towards hydrophobic polymer composites by controlled polymerization. J Polym Sci A Polym Chem 49:3728–3738CrossRef
15.
Zurück zum Zitat Chang R, Lata R, Rohindra D (2017) Miscibility study of poly(butylene succinate) and pine-gum blends. Key Eng Mater 735:148–152CrossRef Chang R, Lata R, Rohindra D (2017) Miscibility study of poly(butylene succinate) and pine-gum blends. Key Eng Mater 735:148–152CrossRef
16.
Zurück zum Zitat Chang R, Rohindra D, Lata R, Kuboyama K, Ougizawa T (2019) Development of poly(ε-caprolactone)/pine resin blends: study of thermal, mechanical and antimicrobial properties. Polym Eng Sci 59:E32–E41CrossRef Chang R, Rohindra D, Lata R, Kuboyama K, Ougizawa T (2019) Development of poly(ε-caprolactone)/pine resin blends: study of thermal, mechanical and antimicrobial properties. Polym Eng Sci 59:E32–E41CrossRef
17.
Zurück zum Zitat Rohindra D (2009) Miscibility determination in poly(ε-caprolactone)/poly(vinyl formal) blend by equilibrium melting temperature and spherulite morphology. J Macromol Sci Phys B 48:1103–1113CrossRef Rohindra D (2009) Miscibility determination in poly(ε-caprolactone)/poly(vinyl formal) blend by equilibrium melting temperature and spherulite morphology. J Macromol Sci Phys B 48:1103–1113CrossRef
18.
Zurück zum Zitat Xiao Q, Yan S, Rogausch KD, Petermann J, Huang Y (2001) Ring-banded spherulites poly(ε-caprolactone) blended with hydroxyethyl cellulose acetate as an indication for partial miscibility. J Appl Polym Sci 80:1681–1686CrossRef Xiao Q, Yan S, Rogausch KD, Petermann J, Huang Y (2001) Ring-banded spherulites poly(ε-caprolactone) blended with hydroxyethyl cellulose acetate as an indication for partial miscibility. J Appl Polym Sci 80:1681–1686CrossRef
19.
Zurück zum Zitat Keith HD, Padden FJ (1984) Twisting orientation and the role of transient states in polymer crystallization. Polymer 25:28–42CrossRef Keith HD, Padden FJ (1984) Twisting orientation and the role of transient states in polymer crystallization. Polymer 25:28–42CrossRef
20.
Zurück zum Zitat Chrissafis K, Paraskevopoulos KM, Bikiaris DN (2005) Thermal degradation mechanism of poly(ethylene succinate) and poly(butylene succinate): comparative study. Thermochim Acta 435:142–150CrossRef Chrissafis K, Paraskevopoulos KM, Bikiaris DN (2005) Thermal degradation mechanism of poly(ethylene succinate) and poly(butylene succinate): comparative study. Thermochim Acta 435:142–150CrossRef
21.
Zurück zum Zitat Rohindra D, Kuboyama K, Ougizawa T (2010) High pressure analysis of the multiple melting endotherms of poly(ethylene succinate) and poly(butylene succinate). J Macromol Sci B 49:470–478CrossRef Rohindra D, Kuboyama K, Ougizawa T (2010) High pressure analysis of the multiple melting endotherms of poly(ethylene succinate) and poly(butylene succinate). J Macromol Sci B 49:470–478CrossRef
22.
Zurück zum Zitat Hoffman JD, Miller RL (1997) Kinetic of crystallization from the melt and chain folding in polyethylene fractions revisited: theory and experiment. Polymer 38:3151–3212CrossRef Hoffman JD, Miller RL (1997) Kinetic of crystallization from the melt and chain folding in polyethylene fractions revisited: theory and experiment. Polymer 38:3151–3212CrossRef
23.
Zurück zum Zitat Yoo ES, Im SS (1999) Melting behavior of poly(butylene succinate) during heating scan by DSC. J Polym Sci B 37:1357–1366CrossRef Yoo ES, Im SS (1999) Melting behavior of poly(butylene succinate) during heating scan by DSC. J Polym Sci B 37:1357–1366CrossRef
24.
Zurück zum Zitat Nishi T, Wang TT (1975) Melting point depression and kinetic effects of cooling on crystallization in poly(vinylidene fluoride)-poly(methyl methacrylate) mixtures. Macromolecules 8:909–915CrossRef Nishi T, Wang TT (1975) Melting point depression and kinetic effects of cooling on crystallization in poly(vinylidene fluoride)-poly(methyl methacrylate) mixtures. Macromolecules 8:909–915CrossRef
25.
Zurück zum Zitat Lee CW, Kimura Y, Chung J (2008) Mechanism of Enzymatic degradation of poly(butylene succinate). Macromol Res 16:358–651 Lee CW, Kimura Y, Chung J (2008) Mechanism of Enzymatic degradation of poly(butylene succinate). Macromol Res 16:358–651
26.
Zurück zum Zitat Nikolic MS, Djonlagic J (2001) Synthesis and characterization of biodegradable poly(butylene succinate-co-butylene adipates). Polym Degrad Stab 74:263–270CrossRef Nikolic MS, Djonlagic J (2001) Synthesis and characterization of biodegradable poly(butylene succinate-co-butylene adipates). Polym Degrad Stab 74:263–270CrossRef
27.
Zurück zum Zitat Thirunavukarasu K, Purushothaman S, Sridevi J, Aarthy M, Gowthaman MK, Nakajima-Kambe T, Kamini NR (2016) Degradation of poly(butylene succinate) and poly(butylene) succinate-co-adipate) by a lipase from Yeast Cryptococcus sp. grown on agro-industrial residues. Int Biodeterior Biodegrad 110:99–107CrossRef Thirunavukarasu K, Purushothaman S, Sridevi J, Aarthy M, Gowthaman MK, Nakajima-Kambe T, Kamini NR (2016) Degradation of poly(butylene succinate) and poly(butylene) succinate-co-adipate) by a lipase from Yeast Cryptococcus sp. grown on agro-industrial residues. Int Biodeterior Biodegrad 110:99–107CrossRef
28.
Zurück zum Zitat Singh G, Kumar P (2013) Phytochemical study and screening for antimicrobial activity of flavonoids of Euphorbia hirta. Int J Appl Basic Med Res 3:111–116CrossRef Singh G, Kumar P (2013) Phytochemical study and screening for antimicrobial activity of flavonoids of Euphorbia hirta. Int J Appl Basic Med Res 3:111–116CrossRef
29.
Zurück zum Zitat Comuzzi B, Arcelloni C, Vaiani R, Paroni J (2001) Gentamicin diffusion in Mueller–Hinton agar plates from different manufacturers. J Antimicrob Chemother 47:496–498CrossRef Comuzzi B, Arcelloni C, Vaiani R, Paroni J (2001) Gentamicin diffusion in Mueller–Hinton agar plates from different manufacturers. J Antimicrob Chemother 47:496–498CrossRef
30.
Zurück zum Zitat Nerantzaki M, Kchagias N, Francone A, Fernandez A, Torres CMS, Papi R, Papadopoulou TC, Bikiaris DN (2018) Design of a multifunctional nanoengineered PLLA surface by maximizing the synergies between biochemical and surface design bactericidal effects. ACS Omega 3:1509–1521CrossRef Nerantzaki M, Kchagias N, Francone A, Fernandez A, Torres CMS, Papi R, Papadopoulou TC, Bikiaris DN (2018) Design of a multifunctional nanoengineered PLLA surface by maximizing the synergies between biochemical and surface design bactericidal effects. ACS Omega 3:1509–1521CrossRef
Metadaten
Titel
Study of mechanical, enzymatic degradation and antimicrobial properties of poly(butylene succinate)/pine-resin blends
verfasst von
Robert Chang
Roselyn Lata
David Rohindra
Publikationsdatum
30.08.2019
Verlag
Springer Berlin Heidelberg
Erschienen in
Polymer Bulletin / Ausgabe 7/2020
Print ISSN: 0170-0839
Elektronische ISSN: 1436-2449
DOI
https://doi.org/10.1007/s00289-019-02938-1

Weitere Artikel der Ausgabe 7/2020

Polymer Bulletin 7/2020 Zur Ausgabe

    Marktübersichten

    Die im Laufe eines Jahres in der „adhäsion“ veröffentlichten Marktübersichten helfen Anwendern verschiedenster Branchen, sich einen gezielten Überblick über Lieferantenangebote zu verschaffen.