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06.11.2022

Study on the Reversible and Irreversible Heat Generation of the Lithium-Ion Battery with LiFePO₄ Cathode

verfasst von: Weiwei Shao, Beibei Zhao, Wenjuan Zhang, Yan Feng, Wenfeng Mao, Guo Ai, Kehua Dai

Erschienen in: Fire Technology | Ausgabe 2/2023

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Abstract

The study of reversible and irreversible heat generation of lithium-ion batteries at different C rates is important for designing thermal management system. Galvanostatic intermittent titration technique is used to determine the overpotential of different SOC (state of charge) or SOD (state of discharge) of commercial lithium iron phosphate pouch cells. The reversible and irreversible heat generation of the battery is calculated based on the entropy change and overpotential. It is found that when the lithium iron phosphate battery is charged, reversible heat first manifests itself as heat absorption, and then soon as exotherm after around 30% SOC, while the reverse for discharge. The total heat generation of lithium iron phosphate batteries during charging is higher than that during discharging. The relative contribution of irreversible and reversible heat generation at low and high rates are different. At 0.1 C rate, the maximum proportion of q_rev is about 70%, while at 1 C rate, the maximum proportion of q_rev is about 25%.

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Titel: Study on the Reversible and Irreversible Heat Generation of the Lithium-Ion Battery with LiFePO4 Cathode
verfasst von: Weiwei Shao
Beibei Zhao
Wenjuan Zhang
Yan Feng
Wenfeng Mao
Guo Ai
Kehua Dai
Publikationsdatum: 06.11.2022
Verlag: Springer US
Erschienen in: Fire Technology / Ausgabe 2/2023
Print ISSN: 0015-2684
Elektronische ISSN: 1572-8099
DOI: https://doi.org/10.1007/s10694-022-01325-z

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Study on the Reversible and Irreversible Heat Generation of the Lithium-Ion Battery with LiFePO₄ Cathode

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