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Erschienen in: Polymer Bulletin 7/2017

09.12.2016 | Original Paper

Study on the self-assembly properties of surface active hydrophobically associating polyacrylamide with nonionic surfmer units

verfasst von: Fan Li, Yue Luo, Pan Hu, Gaoshen Su

Erschienen in: Polymer Bulletin | Ausgabe 7/2017

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Abstract

A novel class of hydrophobic associated copolymers (PASC) with nonionic surfmer was synthesized. These copolymers are the copolymerization product of acrylamide (AM), 2-(acrylamido)-2- methyl propane sulfonic acid (AMPS) and different contents of nonionic surfmer (CP). Macroscopic and microscopic self-assembly associative properties in solutions of PASC, as well as the effects of salt and temperature on the associative behavior were studied via viscosimetry, scanning electron microscope (SEM), atomic force microscope (AFM), rheology and fluorescence spectroscopy (FS). The results show that the introduced nonionic surfmer along polymer chain can lead to a strong intermolecular hydrophobic association in water. The viscosity and surface activity increased with the increase of polymer concentration and nonionic surfmer concentration. Additionally, the polymer showed a good thermal stability and good salt tolerance. Contact angle studies shows that PASC solution has good potential on change of wettability from oil-wet to water-wet. All of these properties indicate that the polymer is an excellent chemical for chemical enhanced oil recovery.

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Metadaten
Titel
Study on the self-assembly properties of surface active hydrophobically associating polyacrylamide with nonionic surfmer units
verfasst von
Fan Li
Yue Luo
Pan Hu
Gaoshen Su
Publikationsdatum
09.12.2016
Verlag
Springer Berlin Heidelberg
Erschienen in
Polymer Bulletin / Ausgabe 7/2017
Print ISSN: 0170-0839
Elektronische ISSN: 1436-2449
DOI
https://doi.org/10.1007/s00289-016-1871-4

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