Skip to main content
Erschienen in: Journal of Materials Science: Materials in Electronics 1/2018

30.10.2017

Surface characterization and gas sensing performance of yttrium doped TiO2 nanofilms prepared by automated nebulizer spray pyrolysis (ANSP)

verfasst von: V. Gopala Krishnan, P. Elango, V. Ganesan

Erschienen in: Journal of Materials Science: Materials in Electronics | Ausgabe 1/2018

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config
loading …

Abstract

YxTi1−xO2 nanofilms were deposited on glass substrate at 500 °C by automated nebulizer spray pyrolysis route. The influence of yttrium concentration on XRD shows the stabilized anatase tetragonal polycrystalline nature and *(222), *(400) plane orientation of Y2O3 were revealed by Y = 10%. An XPS spectrum reveals the primary elements such as O 1s, Ti 2p, Y 3d, Ti 3p and C 1s with a binding energy respectively. The morphological study of FESEM shows the modification from granular spherical to honeycomb structure based on yttrium concentration. Optical study shows the blue shift of sharp absorption edge with increased band gap values (E g  = 3.20 eV–3.78 eV) is depends upon Y concentration. Notably, gas sensing performance of YxTi1−xO2 shows the highest sensitivity response to Y = 10% (Y0.10Ti9.90O2) of NH3 at 150 °C with 300 ppm gas concentration and all the films exhibits better sensitivity response in order to NH3 > C2H6O > C3H6O> CH4O > C3H8O.

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Springer Professional "Wirtschaft"

Online-Abonnement

Mit Springer Professional "Wirtschaft" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 340 Zeitschriften

aus folgenden Fachgebieten:

  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Versicherung + Risiko




Jetzt Wissensvorsprung sichern!

Literatur
1.
Zurück zum Zitat D. Mardare, N. Iftimie, D. Luca, TiO2 thin films as sensing gas materials. J. Non-Cryst. Solids 354, 4396 (2008)CrossRef D. Mardare, N. Iftimie, D. Luca, TiO2 thin films as sensing gas materials. J. Non-Cryst. Solids 354, 4396 (2008)CrossRef
2.
Zurück zum Zitat Z. Wen, L. Tian-Mo, Hydrogen sensing characteristics and mechanism of nanosize TiO2 dope with metallic ions. Physica B 405, 564 (2010)CrossRef Z. Wen, L. Tian-Mo, Hydrogen sensing characteristics and mechanism of nanosize TiO2 dope with metallic ions. Physica B 405, 564 (2010)CrossRef
3.
Zurück zum Zitat T. Honda, K. Yanashima, J. Yoshino, H. Kukimoto, F. Koyama, K. Iga, Fabrication of a ZnSe-based vertical Fabry-Perot cavity using SiO2/TiO2 multilayer reflectors and resonant emission characteristics. Jpn. J. Appl. Phys. 33, 3960 (1994)CrossRef T. Honda, K. Yanashima, J. Yoshino, H. Kukimoto, F. Koyama, K. Iga, Fabrication of a ZnSe-based vertical Fabry-Perot cavity using SiO2/TiO2 multilayer reflectors and resonant emission characteristics. Jpn. J. Appl. Phys. 33, 3960 (1994)CrossRef
4.
Zurück zum Zitat A. Sobhani-Nasab, Z. Zahraei, M. Akbari, M. Maddahfar, S.M. Hosseinpour-Mashkani, Synthesis-characterization and antibacterial activities of ZnLaFe2O4/NiTiO3 nanocomposite. J. Mol. Struct. 1139, 430 (2017)CrossRef A. Sobhani-Nasab, Z. Zahraei, M. Akbari, M. Maddahfar, S.M. Hosseinpour-Mashkani, Synthesis-characterization and antibacterial activities of ZnLaFe2O4/NiTiO3 nanocomposite. J. Mol. Struct. 1139, 430 (2017)CrossRef
5.
Zurück zum Zitat A. Ziarati, A. Sobhani-Nasab, M. Rahimi-Nasrabadi, M.R. Ganjali, A. Badiei, Sonication method synergism with rare earth based nanocatalyst: preparation of NiFe2–xEuxO4 nanostructures and its catalytic applications for the synthesis of benzimidazoles, benzoxazoles, and benzothiazoles under ultrasonic irradiation. J. Rare Earth 35(4), 374 (2017)CrossRef A. Ziarati, A. Sobhani-Nasab, M. Rahimi-Nasrabadi, M.R. Ganjali, A. Badiei, Sonication method synergism with rare earth based nanocatalyst: preparation of NiFe2–xEuxO4 nanostructures and its catalytic applications for the synthesis of benzimidazoles, benzoxazoles, and benzothiazoles under ultrasonic irradiation. J. Rare Earth 35(4), 374 (2017)CrossRef
6.
Zurück zum Zitat H.R. Naderi, A. Sobhani-Nasab, M. Rahimi-Nasrabadi, M.R. Ganjali, Decoration of nitrogen-doped reduced graphene oxide with cobalt tungstate nanoparticles for use in high-performance supercapacitors. Appl. Surf. Sci. 423, 1025 (2017)CrossRef H.R. Naderi, A. Sobhani-Nasab, M. Rahimi-Nasrabadi, M.R. Ganjali, Decoration of nitrogen-doped reduced graphene oxide with cobalt tungstate nanoparticles for use in high-performance supercapacitors. Appl. Surf. Sci. 423, 1025 (2017)CrossRef
7.
Zurück zum Zitat A. Sobhani-Nasab, H. Naderi, M. Rahimi-Nasrabadi, M.R. Ganjali, Evaluation of supercapacitive behavior of samarium tungstate nanoparticles synthesized via sonochemical method. J. Mater. Sci. 28, 8588 (2017) A. Sobhani-Nasab, H. Naderi, M. Rahimi-Nasrabadi, M.R. Ganjali, Evaluation of supercapacitive behavior of samarium tungstate nanoparticles synthesized via sonochemical method. J. Mater. Sci. 28, 8588 (2017)
8.
Zurück zum Zitat I. Vaiciulis, M. Girtan, A. Stanculescu, L. Leontie, F. Habelhames, S. Antohe, On titanium oxide spray deposited thin films for solar cells applications. Proc. Rom. Acad. Ser. A 13(4), 335 (2012) I. Vaiciulis, M. Girtan, A. Stanculescu, L. Leontie, F. Habelhames, S. Antohe, On titanium oxide spray deposited thin films for solar cells applications. Proc. Rom. Acad. Ser. A 13(4), 335 (2012)
9.
Zurück zum Zitat N.E. Stankova, I.G. Dimitrov, T.R. Stoyanchov, P.A. Atanasov, Optical and gas sensing properties of thick TiO2 films grown by laser deposition. Appl. Surf. Sci. 254, 1268 (2007)CrossRef N.E. Stankova, I.G. Dimitrov, T.R. Stoyanchov, P.A. Atanasov, Optical and gas sensing properties of thick TiO2 films grown by laser deposition. Appl. Surf. Sci. 254, 1268 (2007)CrossRef
10.
Zurück zum Zitat Z. Seeley, Y.J. Choi, S. Bose, Citrate–nitrate synthesis of nano-structured titanium dioxide ceramics for gas sensors. Sens. Actuators B 140, 98 (2009)CrossRef Z. Seeley, Y.J. Choi, S. Bose, Citrate–nitrate synthesis of nano-structured titanium dioxide ceramics for gas sensors. Sens. Actuators B 140, 98 (2009)CrossRef
11.
Zurück zum Zitat L.A. Patil, D.N. Suryawanshi, I.G. Pathan, G. Dhanashri, Nanocrystalline Pt doped TiO2 thin films prepared by spray pyrolysis for hydrogen gas detection. Bull. Mater. Sci. 37(3), 425 (2014)CrossRef L.A. Patil, D.N. Suryawanshi, I.G. Pathan, G. Dhanashri, Nanocrystalline Pt doped TiO2 thin films prepared by spray pyrolysis for hydrogen gas detection. Bull. Mater. Sci. 37(3), 425 (2014)CrossRef
12.
Zurück zum Zitat V.G. Krishnan, P. Elango, V. Ganesan, P. Sathish, pH deeds on structural, optical, electrical and gas sensing performance of TiO2 nanofilms by automated nebulizer spray pyrolysis technique. Optik 127, 11102 (2016)CrossRef V.G. Krishnan, P. Elango, V. Ganesan, P. Sathish, pH deeds on structural, optical, electrical and gas sensing performance of TiO2 nanofilms by automated nebulizer spray pyrolysis technique. Optik 127, 11102 (2016)CrossRef
13.
Zurück zum Zitat B.D. Cullity, Elements of X-Ray Diffraction, 2nd edn. (Addison-Wesley Publishing Combany inc., Philippines, 1978) B.D. Cullity, Elements of X-Ray Diffraction, 2nd edn. (Addison-Wesley Publishing Combany inc., Philippines, 1978)
14.
Zurück zum Zitat R. Suresha, V. Ponnuswamy, R. Mariappan, Nanostructured cerium oxide thin films by nebulized spray pyrolysis (NSP) technique: Impact of surfactants on the structural, optical and compositional properties. Ceram. Int. 40, 13515 (2014)CrossRef R. Suresha, V. Ponnuswamy, R. Mariappan, Nanostructured cerium oxide thin films by nebulized spray pyrolysis (NSP) technique: Impact of surfactants on the structural, optical and compositional properties. Ceram. Int. 40, 13515 (2014)CrossRef
15.
Zurück zum Zitat R. Ayouchi, C. Casteleiro, R. Schwarz, J.R. Barrado, F. Martín, Optical properties of TiO2 thin films prepared by chemical spray pyrolysis from aqueous solutions. Phys. Status Solidi C 7(3–4), 933 (2010) R. Ayouchi, C. Casteleiro, R. Schwarz, J.R. Barrado, F. Martín, Optical properties of TiO2 thin films prepared by chemical spray pyrolysis from aqueous solutions. Phys. Status Solidi C 7(3–4), 933 (2010)
16.
Zurück zum Zitat J. Pouilleau, D. Devilliers, H. Groult, P. Marcus, Surface study of a titanium based ceramic electrode material by X-ray photoelectron spectroscopy. J. Mater. Sci. 32, 5645 (1997)CrossRef J. Pouilleau, D. Devilliers, H. Groult, P. Marcus, Surface study of a titanium based ceramic electrode material by X-ray photoelectron spectroscopy. J. Mater. Sci. 32, 5645 (1997)CrossRef
17.
Zurück zum Zitat W. Zhang, K. Wang, S. Zhu, Yttrium-doped TiO2 films prepared by means of DC reactive magnetron sputtering. Chem. Eng. J. 155, 83 (2009)CrossRef W. Zhang, K. Wang, S. Zhu, Yttrium-doped TiO2 films prepared by means of DC reactive magnetron sputtering. Chem. Eng. J. 155, 83 (2009)CrossRef
18.
Zurück zum Zitat M.P. Bole, D.S. Patil, Effect of annealing temperature on the optical constants of zinc oxide films. J. Phys. Chem. Solids 70, 466 (2009)CrossRef M.P. Bole, D.S. Patil, Effect of annealing temperature on the optical constants of zinc oxide films. J. Phys. Chem. Solids 70, 466 (2009)CrossRef
19.
Zurück zum Zitat K.Y. Rajpure, C.D. Lokhande, C.H. Bhosale, A comparative study of the properties of spray-deposited Sb2Se3 thin films prepared from aqueous and nonaqueous media. Mater. Res. Bull. 34, 1079 (1999)CrossRef K.Y. Rajpure, C.D. Lokhande, C.H. Bhosale, A comparative study of the properties of spray-deposited Sb2Se3 thin films prepared from aqueous and nonaqueous media. Mater. Res. Bull. 34, 1079 (1999)CrossRef
20.
Zurück zum Zitat S. Pawar, M. Chougule, S. Patil, B. Raut, D. Dalvi, P. Patil, S. Sen, P. Joshi, V. Patil, Fabrication of nanocrystalline TiO2 thin film ammonia vapor sensor. J. Sens. Technol. 1, 9 (2011)CrossRef S. Pawar, M. Chougule, S. Patil, B. Raut, D. Dalvi, P. Patil, S. Sen, P. Joshi, V. Patil, Fabrication of nanocrystalline TiO2 thin film ammonia vapor sensor. J. Sens. Technol. 1, 9 (2011)CrossRef
21.
Zurück zum Zitat A.A. Haidrya, J. Puskelova, T. Plecenik, P. Durina, J. Gregus, M. Truchly, T. Roch, M. Zahoran, M. Vargova, P. Kus, A. Plecenik, G. Plesch, Characterization and hydrogen gas sensing properties of TiO2 thin films prepared by sol–gel method. Appl. Surf. Sci. 259, 270 (2012)CrossRef A.A. Haidrya, J. Puskelova, T. Plecenik, P. Durina, J. Gregus, M. Truchly, T. Roch, M. Zahoran, M. Vargova, P. Kus, A. Plecenik, G. Plesch, Characterization and hydrogen gas sensing properties of TiO2 thin films prepared by sol–gel method. Appl. Surf. Sci. 259, 270 (2012)CrossRef
22.
Zurück zum Zitat C. Garzella, E. Comini, E. Tempesti, C. Frigeri, G. Sberveglieri, TiO2 thin films by a novel sol–gel processing for gas sensor applications. Sens Actuators B 68, 189 (2000)CrossRef C. Garzella, E. Comini, E. Tempesti, C. Frigeri, G. Sberveglieri, TiO2 thin films by a novel sol–gel processing for gas sensor applications. Sens Actuators B 68, 189 (2000)CrossRef
23.
Zurück zum Zitat X. Zhang, X. Dong, Y. Gui, Theoretical and experimental study on competitive adsorption of SF6 decomposed components on Au-modified anatase (101) surface. Appl. Surf. Sci. 387, 437 (2016)CrossRef X. Zhang, X. Dong, Y. Gui, Theoretical and experimental study on competitive adsorption of SF6 decomposed components on Au-modified anatase (101) surface. Appl. Surf. Sci. 387, 437 (2016)CrossRef
24.
Zurück zum Zitat X. Zhang, Q. Chen, J. Tang, W. Hu, J. Zhang, Adsorption of SF6 decomposed gas on anatase (101) and (001) surfaces with oxygen defect: a density functional theory study. Sci. Rep. 4(4), 4762 (2014) X. Zhang, Q. Chen, J. Tang, W. Hu, J. Zhang, Adsorption of SF6 decomposed gas on anatase (101) and (001) surfaces with oxygen defect: a density functional theory study. Sci. Rep. 4(4), 4762 (2014)
25.
Zurück zum Zitat H. Tang, K. Prasad, R. Sanjinés, F. Lévy, TiO2 anatase thin films as gas sensors. Sens Actuators B 26, 71 (1995)CrossRef H. Tang, K. Prasad, R. Sanjinés, F. Lévy, TiO2 anatase thin films as gas sensors. Sens Actuators B 26, 71 (1995)CrossRef
26.
Zurück zum Zitat L.A. Patil, D.N. Suryawanshi, I.G. Pathan, D.M. Patil, Nickel doped spray pyrolyzed nanostructured TiO2 thin films for LPG gas sensing. Sens Actuators B 176 514 (2013)CrossRef L.A. Patil, D.N. Suryawanshi, I.G. Pathan, D.M. Patil, Nickel doped spray pyrolyzed nanostructured TiO2 thin films for LPG gas sensing. Sens Actuators B 176 514 (2013)CrossRef
27.
Zurück zum Zitat B. Karunagaran, P. Uthirakumar, S.J. Chung, S. Velumani, E.-K. Suh, TiO2 thin film gas sensor for monitoring ammonia. Mater. Charact. 58, 680 (2007)CrossRef B. Karunagaran, P. Uthirakumar, S.J. Chung, S. Velumani, E.-K. Suh, TiO2 thin film gas sensor for monitoring ammonia. Mater. Charact. 58, 680 (2007)CrossRef
28.
Zurück zum Zitat A.K. Yewale, F.C. Raghuwanshi, N.G. Belsare, R.V. Waghmare, R.V. Joat, T.S. Wasnik, K.B. Raulkar, A.S. Wadatkar, G. Lamdhade, Gas sensitivity of TiO2 based thick film sensor to NH3 gas at room temperature. IJAET 2(4), 226 (2011) A.K. Yewale, F.C. Raghuwanshi, N.G. Belsare, R.V. Waghmare, R.V. Joat, T.S. Wasnik, K.B. Raulkar, A.S. Wadatkar, G. Lamdhade, Gas sensitivity of TiO2 based thick film sensor to NH3 gas at room temperature. IJAET 2(4), 226 (2011)
29.
Zurück zum Zitat R. Prajesha, N. Jain, V.K. Khanna, V. Gupta, A. Agarwal, MEMS based integrated gas sensor for NO2 and NH3. J. ISSS. 3(3), 1 (2014) R. Prajesha, N. Jain, V.K. Khanna, V. Gupta, A. Agarwal, MEMS based integrated gas sensor for NO2 and NH3. J. ISSS. 3(3), 1 (2014)
30.
Zurück zum Zitat C. Dighavkar, Characterization of nanosized zinc oxide based ammonia gas sensor. Arch. Appl. Sci. Res. 5(6), 96 (2013) C. Dighavkar, Characterization of nanosized zinc oxide based ammonia gas sensor. Arch. Appl. Sci. Res. 5(6), 96 (2013)
31.
Zurück zum Zitat S. Shukla, S. Seal, Encyclopedia of Nanoscience and Nanotechnology. (American Scientific Publishers, Stevenson Ranc, 2003) S. Shukla, S. Seal, Encyclopedia of Nanoscience and Nanotechnology. (American Scientific Publishers, Stevenson Ranc, 2003)
32.
Zurück zum Zitat V.Y. Young, F.C. Chang, K. Cheng, Characterization of oxidized nickel (II) dimethylglyoxime using X-ray photoelectron spectroscopy. Appl. Spectrosc. 41(6), 994 (1987)CrossRef V.Y. Young, F.C. Chang, K. Cheng, Characterization of oxidized nickel (II) dimethylglyoxime using X-ray photoelectron spectroscopy. Appl. Spectrosc. 41(6), 994 (1987)CrossRef
Metadaten
Titel
Surface characterization and gas sensing performance of yttrium doped TiO2 nanofilms prepared by automated nebulizer spray pyrolysis (ANSP)
verfasst von
V. Gopala Krishnan
P. Elango
V. Ganesan
Publikationsdatum
30.10.2017
Verlag
Springer US
Erschienen in
Journal of Materials Science: Materials in Electronics / Ausgabe 1/2018
Print ISSN: 0957-4522
Elektronische ISSN: 1573-482X
DOI
https://doi.org/10.1007/s10854-017-7928-9

Weitere Artikel der Ausgabe 1/2018

Journal of Materials Science: Materials in Electronics 1/2018 Zur Ausgabe

Neuer Inhalt