nach oben

Cellulose

Erschienen in:

26.01.2021 | Original Research

Sustainable development of mosquito-repellent, flame-retardant, antibacterial, fragrant and antioxidant linen using microcapsules containing Thymus vulgaris oil in in-situ generated chitosan-phosphate

verfasst von: Nagender Singh, Javed Sheikh

Erschienen in: Cellulose | Ausgabe 4/2021

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config

KI-gestützte Suche

Aus

Abstract

In the present work, thyme oil embedded functional microcapsules were prepared using in-situ synthesized chitosan phosphate as a shell material through spray drying technique. The encapsulation efficiency (EE %) of microcapsules was determined to investigate the amount of oil entrapped inside the core-shell structure. The prepared microcapsules and finished fabric were characterized using FTIR, EDX, TGA and SEM analysis. The multifunctional properties of finished fabric were investigated using standard test methods. The finished fabric showed excellent antibacterial property (> 98%), antioxidant activity (96%), flame retardancy (LOI > 28), mosquito repellency (100%) and an excellent fragrance. The functional properties were found durable until at least 20 washes. The structure-property relationship was also confirmed through various characterization techniques.

Graphic abstract

Vorheriger Artikel Thermal insulating and fire-retarding behavior of treated cotton fabrics with a novel high water-retaining hydrogel used in thermal protective clothing

Nächster Artikel Carboxymethyl cellulose and cellulose nanocrystals from cassava stem as thickeners in reactive printing of cotton

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

über 67.000 Bücher
über 390 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Maschinenbau + Werkstoffe

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

über 102.000 Bücher
über 537 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Finance + Banking
Management + Führung
Marketing + Vertrieb
Maschinenbau + Werkstoffe
Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Jetzt informieren

AATCC TM 61-2007 Test Method for Colorfastness to Laundering: Accelerated. American Association of Textile Chemists Colorists, USA

AATCC TM100-2004 Test Method for Antibacterial Finishes on Textile Materials. American Association of Textile Chemists Colorists, USA

Ali Raza Z, Anwar F, Hussain I et al (2019) Fabrication of PLA incorporated chitosan nanoparticles to create enhanced functional properties of cotton fabric. Pigment Resin Technol 48:169–177. https://doi.org/10.1108/PRT-11-2017-0088CrossRef

Altiok D, Altiok E, Tihminlioglu F (2010) Physical, antibacterial and antioxidant properties of chitosan films incorporated with thyme oil for potential wound healing applications. J Mater Sci Mater Med 21:2227–2236. https://doi.org/10.1007/s10856-010-4065-xCrossRefPubMed

Aranaz I, Mengibar M, Harris R et al (2009) Functional characterization of chitin and chitosan. Curr Chem Biol 3:203–230. https://doi.org/10.2174/187231309788166415CrossRef

Aslam M, Raza ZA, Siddique A (2020) Fabrication and chemo-physical characterization of CuO/chitosan nanocomposite-mediated tricomponent PVA films. Polym Bull 77:1–11. https://doi.org/10.1007/s00289-020-03194-4CrossRef

Ayub A, Raza ZA, Majeed MI et al (2020) Development of sustainable magnetic chitosan biosorbent beads for kinetic remediation of arsenic contaminated water. Int J Biol Macromol 163:603–617. https://doi.org/10.1016/j.ijbiomac.2020.06.287CrossRefPubMed

Bakry AM, Abbas S, Ali B et al (2016) Microencapsulation of oils: a comprehensive review of benefits, techniques, and applications. Compr Rev Food Sci Food Saf 15:143–182. https://doi.org/10.1111/1541-4337.12179CrossRefPubMed

Barnard D, Bernier U, Xue R, Debboun M (2006) Standard methods for testing mosquito repellents. In: Insect tepellents. CRC Press, Boca Raton, pp 103–110

Beirão-da-Costa S, Duarte C, Bourbon AI et al (2013) Inulin potential for encapsulation and controlled delivery of Oregano essential oil. Food Hydrocoll 33:199–206. https://doi.org/10.1016/J.FOODHYD.2013.03.009CrossRef

Bhushan S, Kumar A, Singh N, Sheikh J (2020) Functionalization of wool fabric using lignin biomolecules extracted from groundnut shells. Int J Biol Macromol 142:559–563. https://doi.org/10.1016/j.ijbiomac.2019.09.130CrossRefPubMed

Braga PC, Dal Sasso M, Culici M et al (2006) Anti-inflammatory activity of thymol: inhibitory effect on the release of human neutrophil elastase. Pharmacology 77:130–136. https://doi.org/10.1159/000093790CrossRefPubMed

Burt S (2004) Essential oils: their antibacterial properties and potential applications in foods—A review. Int J Food Microbiol 94:223–253. https://doi.org/10.1016/J.IJFOODMICRO.2004.03.022CrossRefPubMed

Burt SA, Vlielander R, Haagsman HP, Veldhuizen EJA (2005) Increase in activity of essential oil components carvacrol and thymol against Escherichia coli O157:H7 by addition of food stabilizers. J Food Prot 68:919–926. https://doi.org/10.4315/0362-028X-68.5.919CrossRefPubMed

Cheng XW, Guan JP, Yang XH et al (2019) A bio-resourced phytic acid/chitosan polyelectrolyte complex for the flame retardant treatment of wool fabric. J Clean Prod 223:342–349. https://doi.org/10.1016/j.jclepro.2019.03.157CrossRef

Da Costa JMG, Borges SV, Hijo AACT et al (2013) Matrix structure selection in the microparticles of essential oil oregano produced by spray dryer. J Microencapsul 30:717–727. https://doi.org/10.3109/02652048.2013.778909CrossRefPubMed

de Oliveira Neto GC, Ferreira Correia JM, Silva PC et al (2019) Cleaner Production in the textile industry and its relationship to sustainable development goals. J Clean Prod 228:1514–1525. https://doi.org/10.1016/j.jclepro.2019.04.334CrossRef

El-Tahlawy K (2008) Chitosan phosphate: a new way for production of eco-friendly flame-retardant cotton textiles. J Text Inst 99:185–191. https://doi.org/10.1080/00405000701584311CrossRef

Gao F, Tong L, Fang Z (2006) Effect of a novel phosphorous-nitrogen containing intumescent flame retardant on the fire retardancy and the thermal behaviour of poly(butylene terephthalate). Polym Degrad Stab 91:1295–1299. https://doi.org/10.1016/j.polymdegradstab.2005.08.013CrossRef

Ghosh SK (2006) Functional coatings: by polymer microencapsulation. Wiley-VCH

Hadidi M, Pouramin S, Adinepour F et al (2020) Chitosan nanoparticles loaded with clove essential oil: characterization, antioxidant and antibacterial activities. Carbohydr Polym 236:116075. https://doi.org/10.1016/j.carbpol.2020.116075CrossRefPubMed

Hassan MM, Sunderland M (2015) Antimicrobial and insect-resist wool fabrics by coating with microencapsulated antimicrobial and insect-resist agents. Prog Org Coatings 85:221–229. https://doi.org/10.1016/J.PORGCOAT.2015.04.016CrossRef

Janarthanan M, Senthil Kumar M (2017) Novel improvement of bioactive microencapsulated textile products using brown seaweed for healthcare applications. Int J Cloth Sci Technol 29:200–214. https://doi.org/10.1108/IJCST-03-2016-0023CrossRef

Joshi M, Bhattacharyya A (2011) Nanotechnology—A new route to high-performance functional textiles. Text Prog 43:155–233. https://doi.org/10.1080/00405167.2011.570027CrossRef

Kong M, Chen XG, Xing K, Park HJ (2010) Antimicrobial properties of chitosan and mode of action: a state of the art review. Int J Food Microbiol 144:51–63. https://doi.org/10.1016/J.IJFOODMICRO.2010.09.012CrossRefPubMed

Kröber T, Kessler S, Frei J et al (2010) An in vitro assay for testing mosquito repellents employing a warm body and carbon dioxide as a behavioral activator. J Am Mosq Control Assoc 26:381–386. https://doi.org/10.2987/10-6044.1CrossRefPubMed

Lacroix M, Smoragiewicz W, Pazdernik L et al (1997) Prevention of lipid radiolysis by natural antioxidants from rosemary (Rosmarinus officinalis L.) and thyme (Thymus vulgaris L.). Food Res Int 30:457–462. https://doi.org/10.1016/S0963-9969(98)00002-7CrossRef

Le Tien C, Lacroix M, Ispas-Szabo P, Mateescu M-A (2003) N-acylated chitosan: hydrophobic matrices for controlled drug release. J Control Release 93:1–13. https://doi.org/10.1016/S0168-3659(03)00327-4CrossRefPubMed

Lehn DN, Esquerdo VM, Dahlem Júnior MA et al (2018) Microencapsulation of different oils rich in unsaturated fatty acids using dairy industry waste. J Clean Prod 196:665–673. https://doi.org/10.1016/j.jclepro.2018.06.127CrossRef

Levchik SV, Weil ED (2008) Developments in phosphorus flame retardants. In: Advances in Fire retardant materials. Elsevier Ltd, Amsterdam, pp 41–66

Li P, Wang B, Liu YY et al (2020) Fully bio-based coating from chitosan and phytate for fire-safety and antibacterial cotton fabrics. Carbohydr Polym 237:116173. https://doi.org/10.1016/j.carbpol.2020.116173CrossRefPubMed

Li S, Boyter H, Qian L (2005) UV curing for encapsulated aroma finish on cotton. J Text Inst 96:407–411. https://doi.org/10.1533/joti.2005.0116CrossRef

Li S, Huang J, Chen Z et al (2017) A review on special wettability textiles: theoretical models, fabrication technologies and multifunctional applications. J Mater Chem A 5:31–55. https://doi.org/10.1039/C6TA07984ACrossRef

Li Y, Ai L, Yokoyama W et al (2013) Properties of chitosan-microencapsulated orange oil prepared by spray-drying and its stability to detergents. J Agric Food Chem 61:3311–3319. https://doi.org/10.1021/jf305074qCrossRefPubMed

Liu W, Wang M, Xu L et al (2019) Radiation technology application in high-performance fibers and functional textiles. In: Radiation technology for advanced materials: from basic to modern applications. Academic Press, London, pp 13–73

Miró Specos MM, Escobar G, Marino P et al (2010) Aroma finishing of cotton fabrics by means of microencapsulation techniques. J Ind Text 40:13–32. https://doi.org/10.1177/1528083709350184CrossRef

Miro Specos MM, Garcia JJ, Gutierrez AC, Hermida LG (2017) Application of microencapsulated biopesticides to improve repellent finishing of cotton fabrics. J Text Inst 108:1454–1460. https://doi.org/10.1080/00405000.2016.1257345CrossRef

Munim SA, Saddique MT, Raza ZA, Majeed MI (2020) Fabrication of cellulose-mediated chitosan adsorbent beads and their surface chemical characterization. Polym Bull 77:183–196. https://doi.org/10.1007/s00289-019-02711-4CrossRef

Muthaiyan A, Limayem A, Ricke SC (2011) Antimicrobial strategies for limiting bacterial contaminants in fuel bioethanol fermentations. Prog Energy Combust Sci 37:351–370. https://doi.org/10.1016/J.PECS.2010.06.005CrossRef

Nagoor Meeran MF, Javed H, Taee H, Al et al (2017) Pharmacological properties and molecular mechanisms of thymol: prospects for its therapeutic potential and pharmaceutical development. Front Pharmacol 8:1–34. https://doi.org/10.3389/fphar.2017.00380CrossRef

Navarrete P, Toledo I, Mardones P et al (2010) Effect of Thymus vulgaris essential oil on intestinal bacterial microbiota of rainbow trout, Oncorhynchus mykiss (Walbaum) and bacterial isolates. Aquac Res 41:e667–e678. https://doi.org/10.1111/j.1365-2109.2010.02590.xCrossRef

Nejman A, Cieślak M, Gajdzicki B et al (2014) Methods of PCM microcapsules application and the thermal properties of modified knitted fabric. Thermochim Acta 589:158–163. https://doi.org/10.1016/J.TCA.2014.05.037CrossRef

Nelson G (2008) Microencapsulation in textile finishing. Rev Prog Color Relat Top 31:57–64. https://doi.org/10.1111/j.1478-4408.2001.tb00138.xCrossRef

Nunthanid J, Puttipipatkhachorn S, Yamamoto K, Peck GE (2001) Physical properties and molecular behavior of chitosan films. Drug Dev Ind Pharm 27:143–157. https://doi.org/10.1081/DDC-100000481CrossRefPubMed

Park B-S, Choi W-S, Kim J-H et al (2005) Monoterpenes from thyme (Thymus vulgaris) as potential mosquito repellents. J Am Mosq Control Assoc 21:80–83. https://doi.org/10.2987/8756-971x(2005)21[80:mfttva]2.0.co;2CrossRefPubMed

Pisitsak P, Tungsombatvisit N, Singhanu K (2018) Utilization of waste protein from Antarctic krill oil production and natural dye to impart durable UV-properties to cotton textiles. J Clean Prod 174:1215–1223. https://doi.org/10.1016/j.jclepro.2017.11.010CrossRef

Pranoto Y, Rakshit SK, Salokhe VM (2005) Enhancing antimicrobial activity of chitosan films by incorporating garlic oil, potassium sorbate and nisin. LWT - Food Sci Technol 38:859–865. https://doi.org/10.1016/J.LWT.2004.09.014CrossRef

Rattan RS (2010) Mechanism of action of insecticidal secondary metabolites of plant origin. Crop Prot 29:913–920. https://doi.org/10.1016/J.CROPRO.2010.05.008CrossRef

Raza ZA, Anwar F, Abid S (2019a) Multi-response optimization in impregnation of chitosan nanoparticles on polyester fabric. Polym Bull 76:3039–3058. https://doi.org/10.1007/s00289-018-2523-7CrossRef

Raza ZA, Bilal U, Noreen U et al (2019b) Chitosan mediated formation and impregnation of silver nanoparticles on viscose fabric in single bath for antibacterial performance. Fibers Polym 20:1360–1367. https://doi.org/10.1007/s12221-019-1018-yCrossRef

Raza ZA, Khalil S, Ayub A, Banat IM (2020) Recent developments in chitosan encapsulation of various active ingredients for multifunctional applications. Carbohydr Res 492:1–15. https://doi.org/10.1016/j.carres.2020.108004CrossRef

Rosenberg Talmon IJ, Kopelman MY (1988) The microstructure of spray-dried microcapsules. Food Struct 7:15–23

Scacchetti FAP, Pinto E, Soares GMB (2017) Functionalization and characterization of cotton with phase change materials and thyme oil encapsulated in beta-cyclodextrins. Prog Org Coatings 107:64–74. https://doi.org/10.1016/J.PORGCOAT.2017.03.015CrossRef

Schwarz K, Ernst H, Ternes W (1996) Evaluation of antioxidative constituents from thyme. J Sci Food Agric 70:217–223. https://doi.org/10.1002/(SICI)1097-0010(199602)70:2<217::AID-JSFA488>3.0.CO;2-YCrossRef

Šipailieneė A, Venskutonis PR, Baranauskienė R, Šarkinas A (2006) Antimicrobial activity of commercial samples of thyme and marjoram oils. J Essent Oil Res 18:698–703. https://doi.org/10.1080/10412905.2006.9699210CrossRef

Sonam Chouhan KS and SG (2017) Antimicrobial activity of some essential oils—Present status and future perspectives. Medicines 4:1–21. https://doi.org/10.3390/medicines4030058CrossRef

Talón E, Trifkovic KT, Vargas M et al (2017) Release of polyphenols from starch-chitosan based films containing thyme extract. Carbohydr Polym 175:122–130. https://doi.org/10.1016/j.carbpol.2017.07.067CrossRefPubMed

Tiwari BK, Valdramidis VP, O’ Donnell CP et al (2009) Application of natural antimicrobials for food preservation. J Agric Food Chem 57:5987–6000. https://doi.org/10.1021/jf900668nCrossRefPubMed

Tong W (2016) Formulation of nano and micro-encapsulated phase change materials with a solar-absorbing metamaterial shell. J Nanoelectron Optoelectron 11:756–761. https://doi.org/10.1166/jno.2016.1962CrossRef

Trifković KT, Milašinović NZ, Djordjević VB et al (2014) Chitosan microbeads for encapsulation of thyme (Thymus serpyllum L.) polyphenols. Carbohydr Polym 111:901–907. https://doi.org/10.1016/j.carbpol.2014.05.053CrossRefPubMed

Van Tran V, Loi Nguyen T, Moon J-Y, Lee Y-C (2019) Core-shell materials, lipid particles and nanoemulsions, for delivery of active anti-oxidants in cosmetics applications: challenges and development strategies. Chem Eng J 368:88–114. https://doi.org/10.1016/J.CEJ.2019.02.168CrossRef

Verlee A, Mincke S, Stevens CV (2017) Recent developments in antibacterial and antifungal chitosan and its derivatives. Carbohydr Polym 164:268–283CrossRef

Vílchez-Maldonado S, Calderó G, Esquena J, Molina R (2014) UV protective textiles by the deposition of functional ethylcellulose nanoparticles. Cellulose 21:2133–2145. https://doi.org/10.1007/s10570-014-0217-3CrossRef

Wang B, Sheng H, Shi Y et al (2015) Recent advances for microencapsulation of flame retardant. Polym Degrad Stab 113:96–109. https://doi.org/10.1016/j.polymdegradstab.2015.01.008CrossRef

Yip J, Luk MYA (2016) Microencapsulation technologies for antimicrobial textiles. Antimicrob Text 19–46. https://doi.org/10.1016/B978-0-08-100576-7.00003-1

Titel: Sustainable development of mosquito-repellent, flame-retardant, antibacterial, fragrant and antioxidant linen using microcapsules containing Thymus vulgaris oil in in-situ generated chitosan-phosphate
verfasst von: Nagender Singh
Javed Sheikh
Publikationsdatum: 26.01.2021
Verlag: Springer Netherlands
Erschienen in: Cellulose / Ausgabe 4/2021
Print ISSN: 0969-0239
Elektronische ISSN: 1572-882X
DOI: https://doi.org/10.1007/s10570-020-03629-1

Springer Professional

Abstract

Graphic abstract

Bitte loggen Sie sich ein, um Zugang zu Ihrer Lizenz zu erhalten.

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Technik"

Springer Professional "Wirtschaft+Technik"

Weitere Artikel der Ausgabe 4/2021

Solvothermal sol–gel synthesis of TiO2-cellulose nanocrystalline composites

Cellulose and its derivatives: towards biomedical applications

Aging state assessment of transformer cellulosic paper insulation using multivariate chemical indicators

Comparison between cellulose nanocrystal and microfibrillated cellulose as reinforcement of poly(vinyl acetate) composites obtained by either in situ emulsion polymerization or a simple mixing technique

Pickering emulsions stabilized by partially acetylated cellulose nanocrystals for oral administration: oils effect and in vivo toxicity

Dissolution studies of α-chitin fibers in freezing NaOH(aq)