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2022 | Buch

Sustainable Production of Biofuels Using Intensified Processes

verfasst von: Juan Gabriel Segovia-Hernández, Eduardo Sanchez-Ramirez, Heriberto Alcocer-Garcia, Ana Gabriela Romero-Garcia, Juan José Quiroz-Ramirez

Verlag: Springer International Publishing

Buchreihe : Green Energy and Technology

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Über dieses Buch

This book describes for first time the synthesis and intensified process design in the production of top biofuels. The production of biofuels is not new. In 2019, global biofuel production levels reached 1,841 thousand barrels of oil equivalent per day, in stark comparison to the 187 thousand barrels of oil equivalent per day that was produced in 2000. Growth has largely been driven by policies that encourage the use and production of biofuels due to the perception that it could provide energy security and reduce greenhouse gas emissions in relevant sectors. From a technical point of view, almost all fuels from fossil resources could be substituted by their bio-based counterparts. However, the cost of bio-based production in many cases exceeds the cost of petrochemical production. Also, biofuels must be proven to perform at least as good as the petrochemical equivalent they are substituting and to have a lower environmental impact. The low price of crude oil acted as a barrier to biofuels production and producers focussed on the specific attributes of biofuels such as their complex structure to justify production costs.

Also, the consumer demand for environmentally friendly products, population growth and limited supplies of non-renewable resources has now opened new windows of opportunity for biofuels. The industry is increasingly viewing chemical production from renewable resources as an attractive area for investment. This book uniquely introduces the application of new process intensification techniques that will allow the generation of clean, efficient and economical processes for biofuels in a competitive way in the market.

Inhaltsverzeichnis

Frontmatter
Chapter 1. Biofuels: Historical Development and Their Role in Today’s Society
Abstract
Have you ever imagined what life would be like without energy sources? What would the growth of civilizations have been like without fuel? How would we live today if we did not have technological developments in energy? This and other questions may arise when thinking about the development of fuels to generate energy. Currently talking about fuels is a very daily topic, about which we do not ask ourselves its origin and the evolution that these have had in history. Thought history, the human being has searched for ways of putting energy to work for them. Due to growing population, human has been looking for faster, easier, and more efficient ways to produce energy. However, for years the human being has made excessive use of existing resources, causing them to be depleted at present. Likewise, the pollution generated using these resources is also causing considerable damage to the environment at a global level. For these reasons, there is a growth in the use of alternative energy sources to reduce pollution and meet their energy needs. In this chapter will describe the origin and historical evolution of biofuels. The social, political and environmental context that originated the need for their scientific and technological development. The biofuels with the greatest demand and potential to replace fossil fuels in the medium term will be briefly described.
Juan Gabriel Segovia-Hernández, Eduardo Sanchez-Ramirez, Heriberto Alcocer-Garcia, Ana Gabriela Romero-Garcia, Juan José Quiroz-Ramirez
Chapter 2. Process Intensification and Circular Economy
Abstract
Process intensification is a valuable strategy to enhance the performance of production processes. It may allow reductions in costs and environmental impact, and enhancements in terms of operability and safety. Although the PI philosophy and methodology have a relatively long history in the scientific field, the ideas of this philosophy fit well with the current trends of sustainability and circular economy; since both ideas, in short, seek the reduction of resource use, the reduction of waste, and the continuous and circular use of raw materials. To ensure the sustainability of biofuel purification, it is important to develop processes with low environmental impact, which can also be allowed through the development of intensified technologies. This chapter presents how the intensification of processes is directly related to sustainability, circular economy, and the principles of green chemistry. Finally, a summary of the intensified technologies for obtaining liquid biofuels is shown.
Juan Gabriel Segovia-Hernández, Eduardo Sanchez-Ramirez, Heriberto Alcocer-Garcia, Ana Gabriela Romero-Garcia, Juan José Quiroz-Ramirez
Chapter 3. Bioethanol
Abstract
Climate change is one of the worst environmental problems worldwide related with CO2 emissions. As is known the burning of fossil fuels has led to ever-increasing levels of greenhouse pollution associated with global warming (Venkata Mohan et al., Bioresour Technol 99:59–67 (2008)). Due to environmental problems, the seek for sustainable alternatives of fuels has become mandatory, having as the most promising alternative the use of biomass as an energy source as well to decrease CO2 emissions. There are several biofuels that can be obtained from biomass, highlighting the bioethanol as a promising renewable and sustainable fuel for tackling today’s global energy crisis and the worsening environment quality. Bioethanol has been recognized as a potential replacement to fossil fuel-based energy, and it can overcome the issue of exhaustion of energy sources and reduce the environmental pollution. Compared to fossil fuels, using bioethanol could reduce more than 80% of carbon emissions (Qiao and Lü, in Advances in 2nd generation of bioethanol production. Woodhead Publishing, Sawston, pp 213–227 (2021) [1]). This chapter aims to show an overview of bioethanol production focusing on the production of bioethanol through lignocellulosic biomass. The traditional feedstock for bioethanol production, its conventional production process highlighting two steps, the biomass pretreatment and separation process. As well due to the necessity of enhance the process it is shown some proposals for intensified processes to produce bioethanol.
Juan Gabriel Segovia-Hernández, Eduardo Sanchez-Ramirez, Heriberto Alcocer-Garcia, Ana Gabriela Romero-Garcia, Juan José Quiroz-Ramirez
Chapter 4. Biobutanol
Abstract
Butanol is an organic chemical that is mostly employed as a solvent in a variety of industries. The growing need to mitigate the climatic effects of fossil-based compounds has fueled study into this compound's potential as a biofuel. This chapter will go through the history of butanol as a biofuel, as well as the present demand for it and the whole biofuel production process. The traditional feedstocks for butanol production, the feedstock to butanol transformation process, and certain butanol purification techniques will all be reviewed. The implementation of process intensification measures that have resulted in enhanced yields in the two primary regions of the process, the reactive stage, and the separation section, will be emphasized. Finally, existing potential niches in the overall process will be addressed, allowing the renewable feedstock process to directly compete with the conventional process.
Juan Gabriel Segovia-Hernández, Eduardo Sanchez-Ramirez, Heriberto Alcocer-Garcia, Ana Gabriela Romero-Garcia, Juan José Quiroz-Ramirez
Chapter 5. 2,3-Butanediol
Abstract
2,3-Butanediol (2,3-BD) is a fascinating chemical with a wide range of uses. The industrial development of this chemical has not been adequately researched due to the presence of many stereoisomers. It may, however, be thought of as a platform chemical that can serve as the starting point for a number of high-value compounds. We will look at the overall properties of 2,3-BD as well as the global demand for it in this chapter. The production process will be addressed in terms of renewable and non-renewable raw resources. Finally, a few existing research involving the use of process intensification ideas in the manufacturing of 2,3-BD will be examined.
Juan Gabriel Segovia-Hernández, Eduardo Sanchez-Ramirez, Heriberto Alcocer-Garcia, Ana Gabriela Romero-Garcia, Juan José Quiroz-Ramirez
Chapter 6. Methyl-Ethyl Ketone
Abstract
MEK (methyl ethyl ketone) is a very versatile chemical with a wide range of industrial uses. The demand for this compound is currently expanding due to its use in a variety of applications. Its potential use as a fuel has recently been highlighted. The role of process intensification in the manufacture of MEK will be explored in this chapter in two process zones: the chemical reaction zone and the separation zone. MEK production using renewable and non-renewable feedstocks will be demonstrated. Despite the fact that the conventional MEK production technique is now the most extensively utilized, the strategies provided in this chapter are an encouragement to eventually replace MEK with renewable feedstock sources.
Juan Gabriel Segovia-Hernández, Eduardo Sanchez-Ramirez, Heriberto Alcocer-Garcia, Ana Gabriela Romero-Garcia, Juan José Quiroz-Ramirez
Chapter 7. Biojet
Abstract
In recent years, the production and consumption of fossil jet fuel have increased as a consequence of a rise in the number of passengers and goods transported by air. In an economic context still dependent on scarce oil, this represents a problem as well as the inherent environmental impact throughout the life cycle of this fuel. Given this, a promising solution is the use of biojet fuel as renewable aviation fuel. In a framework of circular economy, the use of lignocellulosic biomass in the form of sugar-rich crop residues allows the production of alcohols necessary to obtain biojet fuel. Besides, the tools provided by process intensification make it possible to design a sustainable process with low environmental impact and capable to achieve energy savings. The goal of this work was to design an intensified process to produce biojet fuel from Mexican lignocellulosic biomass having alcohols as intermediates.
Juan Gabriel Segovia-Hernández, Eduardo Sanchez-Ramirez, Heriberto Alcocer-Garcia, Ana Gabriela Romero-Garcia, Juan José Quiroz-Ramirez
Chapter 8. Ethyl Levulinate
Abstract
Ethyl levulinate is a versatile chemical feedstock with numerous potential industrial applications. EL can be used up to 5 wt% as the diesel miscible biofuel directly in regular diesel car engines. This chapter describes the production of ethyl levulinate, one of the most important levulinic acid derivatives due to its potential use as a fuel additive and precursor to various chemicals. In this sense, general characteristics and data on this compound, its current production, market, growth prospects and applications are addressed. In addition, recent advances in the production of ethyl levulinate through process intensification were discussed.
Juan Gabriel Segovia-Hernández, Eduardo Sanchez-Ramirez, Heriberto Alcocer-Garcia, Ana Gabriela Romero-Garcia, Juan José Quiroz-Ramirez
Chapter 9. 2,5-Dimethylfuran
Abstract
2,5-Dimethylfuran became an attractive biofuel candidate after a new production method using biomass as feedstock was published in the early 2000s. It has an energy density 40% greater than that of ethanol, making it comparable to gasoline. It is also chemically stable and, being insoluble in water, does not absorb moisture from the atmosphere. Recent tests in a single-cylinder gasoline engine found that the thermal efficiency of burning dimethylfuran is similar to that of gasoline. Also, it has a similar heat of vaporization to gasoline; therefore, it may have less cold start problems compared to bioethanol. Overall, from the point of view of physicochemical properties, 2,5-Dimethylfuran is a promising gasoline alternative, with some aspects better than those of gasoline. Challenges and opportunities arise in process intensification to be able to design sustainable biorefineries that can produce it from lignocellulosic biomass in an economically profitable way.
Juan Gabriel Segovia-Hernández, Eduardo Sanchez-Ramirez, Heriberto Alcocer-Garcia, Ana Gabriela Romero-Garcia, Juan José Quiroz-Ramirez
Chapter 10. The Challenge of Biofuel: Energy Generation for a Sustainable Future
Abstract
It is increasing clear that biofuels can be a viable source of renewable energy in contrast to the finite nature, geopolitical instability, and deleterious global effects of fossil fuel energy. Collectively, biofuels include any energy-enriched chemicals generated directly through the biological processes or derived from the chemical conversion from biomass of prior living organisms. Currently it is still problematic and challenging for biofuel to be commercially competitive over fossil fuel. To address the energy crisis, the global collaborative efforts are essential for transforming biofuels into our current energy system. These collaborative activities will facilitate the cultivation methodology development and technology innovation of biofuel production, including fundamental mechanistic research, cell growth facility construction, genetic engineering of algae strains, and biofuel production condition optimization. Future research endeavors in biofuel production should be placed on the search of novel biofuel production species, optimization and improvement of culture conditions, genetic engineering of biofuel-producing species, complete understanding of the biofuel production mechanisms, and effective techniques for mass cultivation of microorganisms.
Juan Gabriel Segovia-Hernández, Eduardo Sanchez-Ramirez, Heriberto Alcocer-Garcia, Ana Gabriela Romero-Garcia, Juan José Quiroz-Ramirez
Metadaten
Titel
Sustainable Production of Biofuels Using Intensified Processes
verfasst von
Juan Gabriel Segovia-Hernández
Eduardo Sanchez-Ramirez
Heriberto Alcocer-Garcia
Ana Gabriela Romero-Garcia
Juan José Quiroz-Ramirez
Copyright-Jahr
2022
Electronic ISBN
978-3-031-13216-2
Print ISBN
978-3-031-13215-5
DOI
https://doi.org/10.1007/978-3-031-13216-2