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Erschienen in: Polymer Bulletin 9/2017

03.02.2017 | Original Paper

Synthesis and application of fluorinated α-diimine nickel catalyst for ethylene polymerization: deactivation mechanism

verfasst von: S. Ahmadjo, S. Damavandi, G. H. Zohuri, A. Farhadipour, N. Samadieh, Z. Etemadinia

Erschienen in: Polymer Bulletin | Ausgabe 9/2017

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Abstract

A fluorinated LTM catalyst of [bis(N,N′-2-fluorophenylimino)acenaphthene] nickel(ΙΙ) dibromide was prepared and applied for ethylene polymerization. We established a reasonable hypothesis, highlighting the role of fluorine in ligand structure. In addition, density functional theory (DFT) studies have been applied to strengthen our propositions. DFT calculations of the β-agostic cationic species at room temperature and 75 °C suggest that the β-agostic structure for the latter was destabilized by 19 eV which rendered it less prone to β-H transfer reactions than the species at room temperature. In addition, a mechanism for the catalyst deactivation for fluorinated α-diimine nickel based catalysts has been proposed.

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Metadaten
Titel
Synthesis and application of fluorinated α-diimine nickel catalyst for ethylene polymerization: deactivation mechanism
verfasst von
S. Ahmadjo
S. Damavandi
G. H. Zohuri
A. Farhadipour
N. Samadieh
Z. Etemadinia
Publikationsdatum
03.02.2017
Verlag
Springer Berlin Heidelberg
Erschienen in
Polymer Bulletin / Ausgabe 9/2017
Print ISSN: 0170-0839
Elektronische ISSN: 1436-2449
DOI
https://doi.org/10.1007/s00289-017-1924-3

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