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18.10.2021 | Original Research

Synthesis and catalytic evaluation of silver@nickel oxide and alginate biopolymer nanocomposite hydrogel beads

verfasst von: Ashi Khalil, Nauman Ali, Abdullah M. Asiri, Tahseen Kamal, Sher Bahadar Khan, Jawad Ali

Erschienen in: Cellulose | Ausgabe 18/2021

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Abstract

In this study, silver–nickel oxide/calcium alginate (Ag@NiO/Alg) hydrogel beads were synthesized by incorporating the nanomaterial into the polymer solution followed by their extrusion from a syringe to coagulating solution for crosslinking. The Ag@NiO/Alg beads formed through this procedure were characterized by different instrumental techniques. The catalytic efficiency of Ag@NiO/Alg was evaluated for the reduction of rhodamine B (RhB) and methyl orange (MO), in the presence of sodium borohydride. After applying various kinetic order equations to the experimental data, the reactions were found to follow pseudo-first order kinetics using the Ag@NiO/Alg catalyst. The apparent rate constant (k_app) was determined as 0.33358 min⁻¹ and 0.20882 min⁻¹ for the catalytic reduction of RhB and MO, respectively. Furthermore, reduction reactions were studied at varying dye concentration and catalyst dosages. The recovered catalyst was reused up to five cycles without significant drop in the activity.

Vorheriger Artikel Single fiber swelling behavior for natural and man-made cellulose fibers under alkaline treatment

Nächster Artikel Recoverable, water-soluble polyethylene glycol-immobilized N-hydroxyphthalimide, as mediator for cellulose oxidation in the presence of NaBr and NaClO

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Titel: Synthesis and catalytic evaluation of silver@nickel oxide and alginate biopolymer nanocomposite hydrogel beads
verfasst von: Ashi Khalil
Nauman Ali
Abdullah M. Asiri
Tahseen Kamal
Sher Bahadar Khan
Jawad Ali
Publikationsdatum: 18.10.2021
Verlag: Springer Netherlands
Erschienen in: Cellulose / Ausgabe 18/2021
Print ISSN: 0969-0239
Elektronische ISSN: 1572-882X
DOI: https://doi.org/10.1007/s10570-021-04248-0

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