Skip to main content
Erschienen in: Colloid and Polymer Science 4/2011

01.02.2011 | Original Contribution

Synthesis and characterization of a hybrid material from self-assembling colloidal particles and carbon nanotubes

verfasst von: Alexandra Mocanu, Edina Rusen, Bogdan Marculescu, Corneliu Cincu

Erschienen in: Colloid and Polymer Science | Ausgabe 4/2011

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config
loading …

Abstract

The work describes the synthesis of a hybrid material starting from surface-modified colloidal particles of styrene (ST)-acrylic acid (AA) copolymer and carbon nanotubes (CNTs). Vinyl double bonds have been chemically grafted on the surface of the ST-AA copolymer particles in order to be able to copolymerize with acrylamide (AM). The hybrid material was obtained by reaction between the free radicals resulted from both copolymerization and AM homopolymerization and the superficial groups of modified CNTs. Due to the difference between the diameter of the polymer particles and the one of the CNTs, a change in the CNTs shape is to be expected (disentanglement due to steric effects). The products thus obtained have been characterized using IR, SEM, XPS, Raman, and AFM techniques.

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Literatur
1.
Zurück zum Zitat Waterhouse GIN, Waterland MR (2007) Opal and inverse opal photonic crystals: fabrication and characterisation. Polyhedron 26:356–368CrossRef Waterhouse GIN, Waterland MR (2007) Opal and inverse opal photonic crystals: fabrication and characterisation. Polyhedron 26:356–368CrossRef
2.
Zurück zum Zitat Cardoso AH, Leite CAP, Zaniquelli MED, Galembeck F (1998) Easy polymr latex self-assembly and colloidal crystal formation: the case of poly[styrene-co-(2-hydroxyethyl methacrylate)]. Coll Surf A Phys Eng Aspects 144:207–217CrossRef Cardoso AH, Leite CAP, Zaniquelli MED, Galembeck F (1998) Easy polymr latex self-assembly and colloidal crystal formation: the case of poly[styrene-co-(2-hydroxyethyl methacrylate)]. Coll Surf A Phys Eng Aspects 144:207–217CrossRef
3.
Zurück zum Zitat Rusen E, Mocanu A, Marculescu Obtaining B (2010) of monodisperse particles through soap-free and seeded polymerization, respectively, through polymerization in the presence of C60. Colloid Polym Sci 288:769–776CrossRef Rusen E, Mocanu A, Marculescu Obtaining B (2010) of monodisperse particles through soap-free and seeded polymerization, respectively, through polymerization in the presence of C60. Colloid Polym Sci 288:769–776CrossRef
4.
Zurück zum Zitat Rusen E, Mocanu A, Corobea C, Marculescu B (2010) Obtaining of monodisperse particles through soap-free polymerization in the presence of C60. Coll Surf A Phys Eng Aspects 355:23–28CrossRef Rusen E, Mocanu A, Corobea C, Marculescu B (2010) Obtaining of monodisperse particles through soap-free polymerization in the presence of C60. Coll Surf A Phys Eng Aspects 355:23–28CrossRef
5.
Zurück zum Zitat Preda N, Matei E, Enculescu M, Rusen E, Mocanu A, Marculescu B, Enculescu I (2010) Effect of aqueous comonomer solubility on the surfactant-free emulsion copolymerization of methyl methacrylate. J Polym Res 18:25–30. doi:10.1007/s10965-009-9387-3 CrossRef Preda N, Matei E, Enculescu M, Rusen E, Mocanu A, Marculescu B, Enculescu I (2010) Effect of aqueous comonomer solubility on the surfactant-free emulsion copolymerization of methyl methacrylate. J Polym Res 18:25–30. doi:10.​1007/​s10965-009-9387-3 CrossRef
6.
Zurück zum Zitat E Rusen, A Mocanu, B Marculescu, C Andronescu, IC Stancu, A Ioncea, I Antoniac (2011) Influence of the solid-liquid adhesion on the self-assembling properties of colloidal particles. In: Photonic crystals: fabrication, band structure and applications, chapter 9. Nova Publishers, New York E Rusen, A Mocanu, B Marculescu, C Andronescu, IC Stancu, A Ioncea, I Antoniac (2011) Influence of the solid-liquid adhesion on the self-assembling properties of colloidal particles. In: Photonic crystals: fabrication, band structure and applications, chapter 9. Nova Publishers, New York
7.
Zurück zum Zitat Quin D, Qin GLS, Ford Microscopic WT (2010) Composition maps of poly(styrene-co-2-hydroxyethylmethacrylate) colloidal crystals and interconnected colloidal arrays. Langmuir 26:6256–6261CrossRef Quin D, Qin GLS, Ford Microscopic WT (2010) Composition maps of poly(styrene-co-2-hydroxyethylmethacrylate) colloidal crystals and interconnected colloidal arrays. Langmuir 26:6256–6261CrossRef
8.
Zurück zum Zitat Zhang J, Sun Z, Yang B (2009) Self-assembly of photonic crystals from polymer colloids. Curr Opin Colloid Interface Sci 14:103–114CrossRef Zhang J, Sun Z, Yang B (2009) Self-assembly of photonic crystals from polymer colloids. Curr Opin Colloid Interface Sci 14:103–114CrossRef
9.
Zurück zum Zitat Zhang L, Xiong Y (2007) Rapid self-assembly of microspheres at liquid surface by controlling evaporation and its mechanism. J Colloid Interface Sci 306:428–432CrossRef Zhang L, Xiong Y (2007) Rapid self-assembly of microspheres at liquid surface by controlling evaporation and its mechanism. J Colloid Interface Sci 306:428–432CrossRef
10.
Zurück zum Zitat Ge H, Song Y, Jiang L, Zhu D (2006) One-step preparation of polystyrene colloidal crystal films with structural colors and high hydrophobicity. Thin Solid Films 515:1539–1543CrossRef Ge H, Song Y, Jiang L, Zhu D (2006) One-step preparation of polystyrene colloidal crystal films with structural colors and high hydrophobicity. Thin Solid Films 515:1539–1543CrossRef
11.
Zurück zum Zitat Chiappini A, Armellini C, Chiasera A, Ferrari M, Fortes L, Clara Goncalves M, Guider R, Jestin Y, Nunzi Conti G, Pelli S, Almeida Rui M, Righini GC (2009) An alternative method to obtain direct opal photonic crystal structure. J Non-Cryst Solids 355:1167–1170CrossRef Chiappini A, Armellini C, Chiasera A, Ferrari M, Fortes L, Clara Goncalves M, Guider R, Jestin Y, Nunzi Conti G, Pelli S, Almeida Rui M, Righini GC (2009) An alternative method to obtain direct opal photonic crystal structure. J Non-Cryst Solids 355:1167–1170CrossRef
12.
Zurück zum Zitat He YQ, Wang XD, Wang JY, Feng Y, Zhao YQ, You XD (2007) PAM-PAA microgel inverse opal photonic crystal and pH response. Chin Chem Lett 18:1395–1398 He YQ, Wang XD, Wang JY, Feng Y, Zhao YQ, You XD (2007) PAM-PAA microgel inverse opal photonic crystal and pH response. Chin Chem Lett 18:1395–1398
13.
Zurück zum Zitat Dushin CD, Nagayama K, Miwa T, Kralcevsky PA (1993) Colored Multilayers from Transparent Submicrometer Spheres. Langmuir 9:3695–3701CrossRef Dushin CD, Nagayama K, Miwa T, Kralcevsky PA (1993) Colored Multilayers from Transparent Submicrometer Spheres. Langmuir 9:3695–3701CrossRef
14.
Zurück zum Zitat Wang X, Husson SM, Qian X, Wickramasinghe Vertical SR (2009) cell assembly of colloidal crystal films with controllable thickness. Mater Lett 63:1981–1983CrossRef Wang X, Husson SM, Qian X, Wickramasinghe Vertical SR (2009) cell assembly of colloidal crystal films with controllable thickness. Mater Lett 63:1981–1983CrossRef
15.
Zurück zum Zitat Fudouzi Novel H (2007) Coating method for artificial opal films and its process analysis. Coll Surf 311:11–15CrossRef Fudouzi Novel H (2007) Coating method for artificial opal films and its process analysis. Coll Surf 311:11–15CrossRef
16.
Zurück zum Zitat He X, Thomann Y, Leyrer RJ, Rieger Iridescent J (2006) Colors from films made of polymeric core-shell particles. Polym Bull 57:785–796CrossRef He X, Thomann Y, Leyrer RJ, Rieger Iridescent J (2006) Colors from films made of polymeric core-shell particles. Polym Bull 57:785–796CrossRef
17.
Zurück zum Zitat Tang F, Fudouzi H, Zhang J, Sakka Y (2003) Preparation of macroporous titania from nanoparticle building blocks and polymer templates. Scr Mater 49:735–740CrossRef Tang F, Fudouzi H, Zhang J, Sakka Y (2003) Preparation of macroporous titania from nanoparticle building blocks and polymer templates. Scr Mater 49:735–740CrossRef
18.
Zurück zum Zitat Coleman JN, Khan U, Blau WJ, Gun'ko YK (2006) Small but strong: a review of the mechanical properties of carbon nanotube-polymer composites. Carbon 44(9):1624–1652CrossRef Coleman JN, Khan U, Blau WJ, Gun'ko YK (2006) Small but strong: a review of the mechanical properties of carbon nanotube-polymer composites. Carbon 44(9):1624–1652CrossRef
19.
Zurück zum Zitat Kaneto K, Tsuruta M, Sakai G, Cho WY, Ando Y (1999) Electrical conductivities of multi-wall carbon nano tubes. Synth Met 103(1–3):2543–2546CrossRef Kaneto K, Tsuruta M, Sakai G, Cho WY, Ando Y (1999) Electrical conductivities of multi-wall carbon nano tubes. Synth Met 103(1–3):2543–2546CrossRef
20.
Zurück zum Zitat Bokobza L (2007) Multiwall carbon nanotube elastomeric composites: a review. Polymer 48(17):4907–4920CrossRef Bokobza L (2007) Multiwall carbon nanotube elastomeric composites: a review. Polymer 48(17):4907–4920CrossRef
21.
Zurück zum Zitat Xie X-L, Mai Y-W, Zhou X-P (2005) Dispersion and alignment of carbon nanotubes in polymer matrix: a review. Mater Sci Eng R: Reports 49(4):89–112CrossRef Xie X-L, Mai Y-W, Zhou X-P (2005) Dispersion and alignment of carbon nanotubes in polymer matrix: a review. Mater Sci Eng R: Reports 49(4):89–112CrossRef
22.
Zurück zum Zitat Steinert BW, Dean DR (2009) Magnetic field alignment and electrical properties of solution cast PET–carbon nanotube composite films. Polymer 50(3):898–904CrossRef Steinert BW, Dean DR (2009) Magnetic field alignment and electrical properties of solution cast PET–carbon nanotube composite films. Polymer 50(3):898–904CrossRef
23.
Zurück zum Zitat Bliznyuk VN, Singamaneni S, Sanford RL, Chiappetta D, Crooker B, Shibaev PV (2006) Matrix mediated alignment of single wall carbon nanotubes in polymer composite films. Polymer 11(17):3915–3921CrossRef Bliznyuk VN, Singamaneni S, Sanford RL, Chiappetta D, Crooker B, Shibaev PV (2006) Matrix mediated alignment of single wall carbon nanotubes in polymer composite films. Polymer 11(17):3915–3921CrossRef
24.
Zurück zum Zitat Samaneh A, Pierre JC, Abdessalem D (2010) Flow induced orientation of multiwalled carbon nanotubes in polycarbonate nanocomposites: rheology, conductivity and mechanical properties. Polymer 51(4):922–935CrossRef Samaneh A, Pierre JC, Abdessalem D (2010) Flow induced orientation of multiwalled carbon nanotubes in polycarbonate nanocomposites: rheology, conductivity and mechanical properties. Polymer 51(4):922–935CrossRef
25.
Zurück zum Zitat Qinghao Meng, Jinlian Hu (2008) Self-organizing alignment of carbon nanotubes in shape memory segmented fiber prepared by in situ polymerization and melt spinning. Composites Part A: Applied Science and Manufacturing 39(2):314–321 Qinghao Meng, Jinlian Hu (2008) Self-organizing alignment of carbon nanotubes in shape memory segmented fiber prepared by in situ polymerization and melt spinning. Composites Part A: Applied Science and Manufacturing 39(2):314–321
26.
Zurück zum Zitat Tasis D, Tagmatarchis N, Bianco A, Prato M (2006) Chemistry of carbon nanotubes. Chem Rev 106(3):1105–1136CrossRef Tasis D, Tagmatarchis N, Bianco A, Prato M (2006) Chemistry of carbon nanotubes. Chem Rev 106(3):1105–1136CrossRef
27.
Zurück zum Zitat Spitalsky Z, Tasis D, Papagelis K, Galiotis C (2010) Carbon nanotube-polymer composites: chemistry, processing, mechanical and electrical properties. Prog Polym Sci 35:357–401CrossRef Spitalsky Z, Tasis D, Papagelis K, Galiotis C (2010) Carbon nanotube-polymer composites: chemistry, processing, mechanical and electrical properties. Prog Polym Sci 35:357–401CrossRef
28.
Zurück zum Zitat Jiang S, Deng J, Yang W (2008) Functionalization of multi-walled carbon nanotubes by thermo-grafting with alpha-methylstyrene-containing copolymers. Macromol Rapid Commun 29(18):1521–1526CrossRef Jiang S, Deng J, Yang W (2008) Functionalization of multi-walled carbon nanotubes by thermo-grafting with alpha-methylstyrene-containing copolymers. Macromol Rapid Commun 29(18):1521–1526CrossRef
29.
Zurück zum Zitat Akbar S, Beyou E, Cassagnau P, Chaumont P, Farzi G (2009) Radical grafting of polyethylene onto MWCNTs: a model compound approach. Polymer 50(12):2535–2543CrossRef Akbar S, Beyou E, Cassagnau P, Chaumont P, Farzi G (2009) Radical grafting of polyethylene onto MWCNTs: a model compound approach. Polymer 50(12):2535–2543CrossRef
30.
Zurück zum Zitat Blake RC, Coleman JN, Byrne MT, McCarthy JE, Perova TS, Blau WJ (2006) J Mater Chem 16:4206–4213CrossRef Blake RC, Coleman JN, Byrne MT, McCarthy JE, Perova TS, Blau WJ (2006) J Mater Chem 16:4206–4213CrossRef
31.
Zurück zum Zitat Baskaran D, Dunlap JR, Mays JW, Bratcher MS (2005) Grafting efficiency of hydroxy-terminated poly(methyl methacrylate) with multiwalled carbon nanotubes. Macromol Rapid Commun 26(6):481–486CrossRef Baskaran D, Dunlap JR, Mays JW, Bratcher MS (2005) Grafting efficiency of hydroxy-terminated poly(methyl methacrylate) with multiwalled carbon nanotubes. Macromol Rapid Commun 26(6):481–486CrossRef
Metadaten
Titel
Synthesis and characterization of a hybrid material from self-assembling colloidal particles and carbon nanotubes
verfasst von
Alexandra Mocanu
Edina Rusen
Bogdan Marculescu
Corneliu Cincu
Publikationsdatum
01.02.2011
Verlag
Springer-Verlag
Erschienen in
Colloid and Polymer Science / Ausgabe 4/2011
Print ISSN: 0303-402X
Elektronische ISSN: 1435-1536
DOI
https://doi.org/10.1007/s00396-011-2378-z

Weitere Artikel der Ausgabe 4/2011

Colloid and Polymer Science 4/2011 Zur Ausgabe

    Marktübersichten

    Die im Laufe eines Jahres in der „adhäsion“ veröffentlichten Marktübersichten helfen Anwendern verschiedenster Branchen, sich einen gezielten Überblick über Lieferantenangebote zu verschaffen.