Skip to main content
Erschienen in: Cellulose 3/2016

11.04.2016 | Original Paper

Synthesis and characterization of cellulose-g-polyoxyethylene (2) hexadecyl ether solid–solid phase change materials

verfasst von: Na Han, Zhinan Li, Xingxiang Zhang, Wanyong Yu, Xiaoying Chen, Dong Wang, Junbao Li

Erschienen in: Cellulose | Ausgabe 3/2016

Einloggen

Aktivieren Sie unsere intelligente Suche um passende Fachinhalte oder Patente zu finden.

search-config
loading …

Abstract

A series of novel solid–solid phase change materials, namely, cellulose-g-polyoxyethylene (2) hexadecyl ether (Cellulose-g-E2C16) copolymers, were synthesized using toluene 2,4-diisocyanate (TDI) as a coupling reagent in the ionic liquid 1-allyl-3-methylimidazolium chloride (AmimCl). The optimum prepolymerization conditions were determined to be 25 °C and 75 min without catalyst, and the optimum reaction conditions of the grafting step were 90 °C, 6 h and 0.1 wt% dibutyltin dilaurate (DBTDL, weight percent of TDI). The successful grafting was confirmed by FTIR and 1H-NMR. The properties of the Cellulose-g-E2C16 copolymers were investigated by DSC, TG and XRD. It is shown that the heat storage ability and phase change temperature of Cellulose-g-E2C16 copolymers depended on the degree of substitution. The crystalline type of the grafted E2C16 was not affected by the cellulosic backbone. Compared with E2C16, Cellulose-g-E2C16 copolymers showed better thermal stability. They are expected to be widely applied in the area of thermal energy storage.

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Literatur
Zurück zum Zitat Abdel-Halim ES (2014) Chemical modification of cellulose extracted from sugarcane bagasse: preparation of hydroxyethyl cellulose. Arab J Chem 7:362–371CrossRef Abdel-Halim ES (2014) Chemical modification of cellulose extracted from sugarcane bagasse: preparation of hydroxyethyl cellulose. Arab J Chem 7:362–371CrossRef
Zurück zum Zitat Arzu K, Sennur AA (2014) Cellulose-PEG grafts from cotton waste in thermo-regulating textiles. Text Res J 84(4):337–346CrossRef Arzu K, Sennur AA (2014) Cellulose-PEG grafts from cotton waste in thermo-regulating textiles. Text Res J 84(4):337–346CrossRef
Zurück zum Zitat Barthel S, Heinze T (2006) Acylation and carbanilation of cellulose in ionic liquids. Green Chem 8:301–306CrossRef Barthel S, Heinze T (2006) Acylation and carbanilation of cellulose in ionic liquids. Green Chem 8:301–306CrossRef
Zurück zum Zitat Bianchi E, Marsano E, Ricco L (1998) Free radical grafting onto cellulose in homogeneous conditions 1. Modified cellulose-acrylonitrile system. Carbohydr Polym 36:313–318CrossRef Bianchi E, Marsano E, Ricco L (1998) Free radical grafting onto cellulose in homogeneous conditions 1. Modified cellulose-acrylonitrile system. Carbohydr Polym 36:313–318CrossRef
Zurück zum Zitat Bianchi E, Bonazza A, Marsano E (2000) Free radical grafting onto cellulose in homogeneous conditions 2. Modified cellulose-methyl methacrylate system. Carbohydr Polym 41:47–53CrossRef Bianchi E, Bonazza A, Marsano E (2000) Free radical grafting onto cellulose in homogeneous conditions 2. Modified cellulose-methyl methacrylate system. Carbohydr Polym 41:47–53CrossRef
Zurück zum Zitat Cheng Y, Zhang JM, Lv YX (2009) Thermoplastic cellulose-graft-poly(L-lactide) copolymers homogeneously synthesized in an lonic liquid with 4-dimethylamininopyridine catalyst. Biomacromolecules 10(8):2013–2018CrossRef Cheng Y, Zhang JM, Lv YX (2009) Thermoplastic cellulose-graft-poly(L-lactide) copolymers homogeneously synthesized in an lonic liquid with 4-dimethylamininopyridine catalyst. Biomacromolecules 10(8):2013–2018CrossRef
Zurück zum Zitat Chen X, Zheng N, Wang Q (2014) Effect of synthetic pathways on the phase transition and side-chain crystallization behavior of alkyl-substituted cellulose ethers. Polym Chem 5:4105–4114CrossRef Chen X, Zheng N, Wang Q (2014) Effect of synthetic pathways on the phase transition and side-chain crystallization behavior of alkyl-substituted cellulose ethers. Polym Chem 5:4105–4114CrossRef
Zurück zum Zitat Cheng SL, Chen YM, Yu H (2008) Synthesis and properties of a spinnable phase change material CDA-IPDI-MPEG. e-Polymers 8(1):1569–1579CrossRef Cheng SL, Chen YM, Yu H (2008) Synthesis and properties of a spinnable phase change material CDA-IPDI-MPEG. e-Polymers 8(1):1569–1579CrossRef
Zurück zum Zitat Gyorgy S, Attila D, Szilvia K (2008) Molecular structure and properties of cellulose acetate chemically modified with caprolactone. Eur Polym J 44:357–365CrossRef Gyorgy S, Attila D, Szilvia K (2008) Molecular structure and properties of cellulose acetate chemically modified with caprolactone. Eur Polym J 44:357–365CrossRef
Zurück zum Zitat Isik M, Sardon H, Mecerreyes D (2014) Ionic liquids and cellulose: dissolution, chemical modification and preparation of new cellulosic materials. Int J Mol Sci 15:11922–11940CrossRef Isik M, Sardon H, Mecerreyes D (2014) Ionic liquids and cellulose: dissolution, chemical modification and preparation of new cellulosic materials. Int J Mol Sci 15:11922–11940CrossRef
Zurück zum Zitat Kumar A, Kulkarni PS, Samui AB (2014) Polyethylene glycol grafted cotton as phase change polymer. Cellulose 21:685–696CrossRef Kumar A, Kulkarni PS, Samui AB (2014) Polyethylene glycol grafted cotton as phase change polymer. Cellulose 21:685–696CrossRef
Zurück zum Zitat Labafzadeh SR, Vyavaharkar K, Kavakka JS (2015) Amination thiolation of chloroacetyl cellulose through reactive dissolution in N, N-dimethylformamide. Carbohydr Polym 116:60–66CrossRef Labafzadeh SR, Vyavaharkar K, Kavakka JS (2015) Amination thiolation of chloroacetyl cellulose through reactive dissolution in N, N-dimethylformamide. Carbohydr Polym 116:60–66CrossRef
Zurück zum Zitat Li YX, Wu M, Liu RG (2009) Cellulose-based solid-solid phase change materials synthesized in ionic liquid. Solar Energy Mater Solar Cells 93:1321–1328CrossRef Li YX, Wu M, Liu RG (2009) Cellulose-based solid-solid phase change materials synthesized in ionic liquid. Solar Energy Mater Solar Cells 93:1321–1328CrossRef
Zurück zum Zitat Luan YH, Zhang JM, Zhang MS (2013) Highly efficient propionylation and butyralation of cellulose in an ionic liquid catalyzed by 4-dimethylminopyridine. Carbohydr Polym 92:307–311CrossRef Luan YH, Zhang JM, Zhang MS (2013) Highly efficient propionylation and butyralation of cellulose in an ionic liquid catalyzed by 4-dimethylminopyridine. Carbohydr Polym 92:307–311CrossRef
Zurück zum Zitat Lucie C, Valerie M, Nicolas J (2011) Effect of side chain length on structure and thermomechanical properties of fully substituted cellulose fatty esters. Carbohydr Polym 83:1812–1820CrossRef Lucie C, Valerie M, Nicolas J (2011) Effect of side chain length on structure and thermomechanical properties of fully substituted cellulose fatty esters. Carbohydr Polym 83:1812–1820CrossRef
Zurück zum Zitat Meng JY, Tang XF, Li W, Shi HF, Zhang XX (2013a) Crystal structure and thermal property of polyethylene glycol octadecyl ether. Thermochim Acta 558:83–86CrossRef Meng JY, Tang XF, Li W, Shi HF, Zhang XX (2013a) Crystal structure and thermal property of polyethylene glycol octadecyl ether. Thermochim Acta 558:83–86CrossRef
Zurück zum Zitat Meng JY, Tang XF, Zhang ZL, Zhang XX, Shi HF (2013b) Fabrication and properties of poly(polyethylene glycol octadecyl ether methacrylate). Thermochim Acta 574:116–120CrossRef Meng JY, Tang XF, Zhang ZL, Zhang XX, Shi HF (2013b) Fabrication and properties of poly(polyethylene glycol octadecyl ether methacrylate). Thermochim Acta 574:116–120CrossRef
Zurück zum Zitat Saleh H, Yvonne A, Mikael S (2014) All-cellulose nanocomposite fibers produced by melt spinning cellulose acetate butyrate and cellulose nanocrystals. Cellulose 21:2665–2678CrossRef Saleh H, Yvonne A, Mikael S (2014) All-cellulose nanocomposite fibers produced by melt spinning cellulose acetate butyrate and cellulose nanocrystals. Cellulose 21:2665–2678CrossRef
Zurück zum Zitat Simon EB, Giuseppe G, Contreras JM (2013) Characterization of esterified cassava starch with long alkyl side chains and different substitution degrees. Int J Biol Macromol 59:384–390CrossRef Simon EB, Giuseppe G, Contreras JM (2013) Characterization of esterified cassava starch with long alkyl side chains and different substitution degrees. Int J Biol Macromol 59:384–390CrossRef
Zurück zum Zitat Tang EJ, Du KD, Feng XY (2015) Controlled synthesis of cellulose-graft-poly[2-(diethylamino)-ethyl methacrylate] by ATRP in ionic liquid [AMIM]Cl and its pH-responsive property. Eur Polym J 66:228–235CrossRef Tang EJ, Du KD, Feng XY (2015) Controlled synthesis of cellulose-graft-poly[2-(diethylamino)-ethyl methacrylate] by ATRP in ionic liquid [AMIM]Cl and its pH-responsive property. Eur Polym J 66:228–235CrossRef
Zurück zum Zitat Teramoto Y, Nishio Y (2003) Cellulose diacetate-graft-poly(lactic acid)s: synthesis of wide-ranging compositions and their thermal and mechanical properties. Polymer 44:2071–2079CrossRef Teramoto Y, Nishio Y (2003) Cellulose diacetate-graft-poly(lactic acid)s: synthesis of wide-ranging compositions and their thermal and mechanical properties. Polymer 44:2071–2079CrossRef
Zurück zum Zitat Thakur VK, Singha AS, Thakur MK (2012) Graft copolymerization of methyl acrylate onto cellulosic biofiber: synthesis, characterization and applications. J Polym Environ 20:164–174CrossRef Thakur VK, Singha AS, Thakur MK (2012) Graft copolymerization of methyl acrylate onto cellulosic biofiber: synthesis, characterization and applications. J Polym Environ 20:164–174CrossRef
Zurück zum Zitat Youssef H, Anne-Lise G, Nancy S (2008) Bionanocomposites based on poly(ε-caprolactone)-grafted cellulose nanocrystals by ring-opening polymerization. J Mater Chem 18:5002–5010CrossRef Youssef H, Anne-Lise G, Nancy S (2008) Bionanocomposites based on poly(ε-caprolactone)-grafted cellulose nanocrystals by ring-opening polymerization. J Mater Chem 18:5002–5010CrossRef
Zurück zum Zitat Zhang H, Wu J, Zhang J, He JS (2005) 1-Allyl-3-methylimidazolium chloride room temperature ionic liquid: a new and powerful nonderivatizing solvent for cellulose. Macromolecules 38:8272–8277CrossRef Zhang H, Wu J, Zhang J, He JS (2005) 1-Allyl-3-methylimidazolium chloride room temperature ionic liquid: a new and powerful nonderivatizing solvent for cellulose. Macromolecules 38:8272–8277CrossRef
Zurück zum Zitat Zhang LJ, Shi HF, Li WW, Han X, Zhang XX (2013a) Structure and thermal performance of poly(ethylene glycol) alkyl ether (Brij)/porous silica (MCM-41) composites as shape-stabilized phase change materials. Thermochim Acta 570:1–7CrossRef Zhang LJ, Shi HF, Li WW, Han X, Zhang XX (2013a) Structure and thermal performance of poly(ethylene glycol) alkyl ether (Brij)/porous silica (MCM-41) composites as shape-stabilized phase change materials. Thermochim Acta 570:1–7CrossRef
Zurück zum Zitat Zhang Y, Li HF, Li XD, Gibril M, Han KQ, Yu MH (2013b) Green chemical preparation of cellulose/high performance elastomer blend fibers by melt-spinning method. J Polym Res 20(6):1–9CrossRef Zhang Y, Li HF, Li XD, Gibril M, Han KQ, Yu MH (2013b) Green chemical preparation of cellulose/high performance elastomer blend fibers by melt-spinning method. J Polym Res 20(6):1–9CrossRef
Zurück zum Zitat Zhang LJ, Shi HF, Li WW, Han X, Zhang XX (2014a) Thermal performance and crystallization behavior of poly(ethylene glycol) hexadecyl ether in confined environment. Polym Int 63(6):982–988CrossRef Zhang LJ, Shi HF, Li WW, Han X, Zhang XX (2014a) Thermal performance and crystallization behavior of poly(ethylene glycol) hexadecyl ether in confined environment. Polym Int 63(6):982–988CrossRef
Zurück zum Zitat Zhang Y, Li HF, Li XD, Gibril M, Yu MH (2014b) Chemical modification of cellulose by in situ reactive extrusion in ionic liquid. Carbohydr Polym 99:126–131CrossRef Zhang Y, Li HF, Li XD, Gibril M, Yu MH (2014b) Chemical modification of cellulose by in situ reactive extrusion in ionic liquid. Carbohydr Polym 99:126–131CrossRef
Metadaten
Titel
Synthesis and characterization of cellulose-g-polyoxyethylene (2) hexadecyl ether solid–solid phase change materials
verfasst von
Na Han
Zhinan Li
Xingxiang Zhang
Wanyong Yu
Xiaoying Chen
Dong Wang
Junbao Li
Publikationsdatum
11.04.2016
Verlag
Springer Netherlands
Erschienen in
Cellulose / Ausgabe 3/2016
Print ISSN: 0969-0239
Elektronische ISSN: 1572-882X
DOI
https://doi.org/10.1007/s10570-016-0901-6

Weitere Artikel der Ausgabe 3/2016

Cellulose 3/2016 Zur Ausgabe