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Journal of Polymer Research
Erschienen in: Journal of Polymer Research 5/2019

01.05.2019 | ORIGINAL PAPER

Synthesis and characterization of novel ABA type poly(Ester-ether) triblock copolymers

verfasst von: Efkan Çatıker, Temel Öztürk, Mehmet Atakay, Bekir Salih

Erschienen in: Journal of Polymer Research | Ausgabe 5/2019

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Abstract

Oligomers of poly(3-hydroxypropionate) (P3HP) were synthesized via hydrogen transfer polymerization of acrylic acid. Olefinic end-group of the oligomers were modified through epoxidation and bromination to obtain activated oligomers with epoxy and bromide end-groups, respectively. Terminally hydroxyl oligomeric poly(ethylene glycol) (PEG-1450) was also converted to sodium alkoxide of PEG-1450 through reaction with sodium hydride. Novel ABA type P3HP-b-PEG-b-P3HP triblock copolymers were successfully obtained through simple nucleophilic addition reactions between alkoxy and epoxy/alkyl bromide. Water uptake measurements of the triblock copolymers were calculated. Characterization of the modified oligomers and the triblock copolymers was performed by using FT-IR, 1H-NMR and MALDI-MS analyses. Thermal transitions and degradation features of the copolymers were investigated by using DSC and TGA methods. Spectroscopic and thermal analyses revealed that both end-group modifications and coupling reactions were successfully achieved.
Vorheriger Artikel Development of segregated 3D graphene networks in rubber nanocomposites with enhanced electrical and mechanical properties
Nächster Artikel Enhancement of stiffness and dynamic mechanical properties of polymers using single-walled-carbon-nanotube – a multiscale finite element formulation study

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Metadaten
Titel
Synthesis and characterization of novel ABA type poly(Ester-ether) triblock copolymers
verfasst von
Efkan Çatıker
Temel Öztürk
Mehmet Atakay
Bekir Salih
Publikationsdatum
01.05.2019
Verlag
Springer Netherlands
Erschienen in
Journal of Polymer Research / Ausgabe 5/2019
Print ISSN: 1022-9760
Elektronische ISSN: 1572-8935
DOI
https://doi.org/10.1007/s10965-019-1778-5

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