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Polymer Bulletin
Erschienen in: Polymer Bulletin 3/2009

01.03.2009 | Original Paper

Synthesis and characterization of poly(methyl methacrylate) using monofunctional polyhedral oligomeric silsesquioxane as an initiator

verfasst von: Lei Liu, Wenping Wang

Erschienen in: Polymer Bulletin | Ausgabe 3/2009

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Abstract

POSS/PMMA composite was synthesized by atom transfer radical polymerization (ATRP) at 110 °C using commercial POSSCl as an initiator and CuCl/2,2′-bipyridine as catalyst system. The structures of POSS/PMMA and POSSCl were characterized by Fourier transfer infrared spectroscopy, Nuclear magnetic resonance spectroscopy, Ger permeation chromatography, X-ray diffraction and X-ray photoelectron spectroscopy, which confirmed that Si–Cl bond on POSS cage could successfully initiate the ATRP of methyl methacrylate, so there is only one POSS unit in a PMMA chain. The thermal properties of POSS/PMMA were investigated by Differential scanning calorimetry and Thermogravimetric analysis, the results show that the incorporation of POSS cage results in the enhancement of the glass transition temperature and the decomposition temperature of PMMA, which is mainly attributed to the mono-dispersion of POSS in PMMA matrix at molecular lever.
Vorheriger Artikel Synthesis of through-space conjugated polymers containing the pseudo-ortho-linked [2.2]paracyclophane moiety
Nächster Artikel Synthesis of novel polymeric HALS stabilizers and chain transfer effect of hindered amine norbornene derivatives on ring-opening metathesis polymerization

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Literatur
1.
Matyjaszewski K, Miller PJ, Pyun J, Kickelbick G, Diamanti S (1999) Synthesis and characterization of star polymers with varying arm number, length, and composition from organic and hybrid inorganic/organic multifunctional initiators. Macromolecules 32:6526CrossRef
2.
Zhang CX, Babonneau F, Bonhomme C, Laine RM, Soles CL, Hristov HA, Yee AF (1998) Highly porous polyhedral silsesquioxane polymers. Synthesis and characterization. J Am Chem Soc 120:8380CrossRef
3.
Xu HY, Kuo SW, Chang FC (2002) Significant glass transition temperature increase based on polyhedral oligomeric silsequioxane (POSS) copolymer through hydrogen bonding. Polym Bull 48:469CrossRef
4.
Lee A, Xiao J, Feher FJ (2005) New approach in the synthesis of hybrid polymers grafted with polyhedral oligomeric silsesquioxane and their physical and viscoelastic properties. Macromolecules 38:438CrossRef
5.
Mather PT, Jeon HG, Uribe AR (1999) Mechanical relaxation and microstructure of poly(norbornyl-POSS) copolymers. Macromolecules 32:1194CrossRef
6.
Zhao CB, Yang XJ, Wu XD, Liu XH, Wang X, Lu LD (2008) Preparation and characterization of poly(methyl methacrylate) nanocomposites containing octavinyl polyhedral oligomeric silsesquioxane. Polym Bull 60:495CrossRef
7.
Haddad TS, Lichtenhan JD (1996) Hybrid organic-inorganic thermoplastics: styryl-based polyhedral oligomeric silsesquioxane polymers. Macromolecules 29:7302CrossRef
8.
Chen RX, Feng W, Zhu SP, Botton G, Org B, Wu YL (2006) Surface-initiated atom transfer radical polymerization of polyhedral oligomeric silsesquioxane (POSS) methacrylate from flat silicon wafer. Polymer 47:1119CrossRef
9.
Pyun J, Matyjaszewski K (2002) The synthesis of hybrid polymers using atom transfer radical polymerization: homopolymers and block copolymers from polyhedral oligomeric silsesquioxane monomer. Macromolecules 33:217CrossRef
10.
Xu HY, Kuo SW, Huang CF, Chang FC (2002) Poly(acetoxystyrene-co-isobutylstyryl POSS) nanocomposites: characterization and molecular interaction. J Polym Res 9:239CrossRef
11.
Zhao QY, Schiraldi DA (2005) Thermal and mechanical properties of polyhedral oligomeric silsesquioxane (POSS)/polycarbonate composites. Polymer 46:11640
12.
Liang KW, Li GZ, Toghiani H, Koo JH, Pittman CU (2006) Cyanate ester/polyhedral oligomeric silsesquioxane (POSS) nanocomposites: synthesis and characterization. Chem Mater 18:301CrossRef
13.
Liu L, Tian M, Zhang W, Zhang LQ, Mark JE (2007) Crystallization and morphology study of polyhedral oligomeric silsesquioxane (POSS)/polysiloxane elastomer composites prepared by melt blending. Polymer 48:3201CrossRef
14.
Zhang YD, Lee SH, Yoonessi M, Liang KW, Pittman CU (2006) Phenolic resin–trisilanolphenyl polyhedral oligomeric silsesquioxane (POSS) hybrid nanocomposites: structure and properties. Polymer 47:2984CrossRef
15.
Zhang YD, Lee SH, Yoonessi M, Toghiani Pittman CU (2007) Phenolic resin/octa(aminophenyl)-T8-polyhedral oligomeric silsesquioxane (POSS) hybrid nanocomposites: synthesis, morphology, thermal and mechanical properties. J Inorg Organomet 17:159CrossRef
16.
Amir N, Levina A, Silverstein MS (2007) Nanocomposites through copolymerization of a polyhedral oligomeric silsesquioxane and methyl methacrylate. J Polym Sci Part A Polym Chem 45:4264CrossRef
17.
Ueda J, Matsuyama M, Kamigaito M, Sawamoto M (1998) Multifunctional initiators for the ruthenium-mediated living radical polymerization of methyl methacrylate: di- and trifunctional dichloroacetates for synthesis of multiarmed polymers. Macromolecules 31:557CrossRef
18.
Hong CY, You YZ, Wu DS, Liu Y, Pan CY (2007) Thermal control over the topology of cleavable polymers: from linear to hyperbranched structures. J Am Chem Soc 129:5434
19.
Terashima T, Ouchi M, Ando T, Kamigaito M, Sawamoto M (2006) Metal-complex-bearing star polymers by metal-catalyzed living radical polymerization: synthesis and characterization of poly(methyl methacrylate) star polymers with Ru(II)-embedded microgel cores. J Polym Sci Part A Polym Chem 44:4966CrossRef
20.
Feng XS, Pan CY (2002) Synthesis of amphiphilic miktoarm ABC star copolymers by RAFT mechanism using maleic anhydride as linking agent. Macromolecules 35:4888CrossRef
21.
You YZ, Hong CY, Wang WP, Wang PH, Lu WQ, Pan CY (2004) A novel strategy to synthesize graft copolymers with controlled branch spacing length and defined grafting sites. Macromolecules 37:7140CrossRef
22.
Ray B, Isobe Y, Morioka K, Habaue S, Okamoto Y, Kamigaito M, Sawamoto M (2003) Synthesis of isotactic poly(N-isopropylacrylamide) by RAFT polymerization in the presence of Lewis acid. Macromolecules 36:543CrossRef
23.
Yamamura Y, Matyjaszewski K (2008) Tripodal imidazole containing ligands for copper catalyzed ATRP. J Polym Sci Part A Polym Chem 46:2015CrossRef
24.
Yuan WZ, Yuan JY, Zhou M, Pan CY (2008) Synthesis, characterization, and fluorescence of pyrene-containing eight-arm star-shaped dendrimer-like copolymer with pentaerythritol core. J Polym Sci Part A Polym Chem 46:2788CrossRef
25.
Pyun J, Matyjaszewski K, Wu J, Kim JM, Chun SB, Mather PT (2003) ABA triblock copolymers containing polyhedral oligomeric silsesquioxane pendant groups: synthesis and unique properties. Polymer 44:2739CrossRef
26.
Li HY, Chen ST, Zhang XF, Lu YY, Hu YL (2005) Study on the polymerizations of methyl methacrylate and styrene initiated with chlorotrimethylsilane and CuCl/N, N, N′, N″, N″-pentamethyldiethyltriamine. Eur Polym J 41:2874CrossRef
27.
Matyjaszewski K, Patten TE, Xia J (1997) Controlled/“living” radical polymerization. Kinetics of the homogeneous atom transfer radical polymerization of styrene. J Am Chem Soc 119:674CrossRef
28.
Xu HY, Yang BH, Wang JF, Guang SY, Li C (2007) Preparation, Tg improvement, and thermal stability enhancement mechanism of soluble poly(methyl methacrylate) nanocomposites by incorporating octavinyl polyhedral oligomeric silsesquioxanes. J Polym Sci Part A Polym Chem 45:5308CrossRef
29.
Deng XB, Liu BL, Cao SS, Luo R, Chen HL (2007) A novel approach for the preparation of PMMA–PDMS core–shell particles with PDMS in the shell. Appl Surf Sci 253:4823CrossRef
30.
Gu GT, Zhang ZJ, Dang HX (2004) Preparation and characterization of hydrophobic organic–inorganic composite thin films of PMMA/SiO2/TiO2 with low friction coefficient. Appl Surf Sci 221:129CrossRef
31.
Leu CM, Chang YT, Wei KH (2003) Polyimide-side-chain tethered polyhedral oligomeric silsesquioxane nanocomposites for low-dielectric film applications. Chem Mater 15:3721CrossRef
32.
Markvic E, Matisons J, Hussain M, Simon GP (2007) Poly(ethylene glycol) octafunctionalized polyhedral oligomeric silsesquioxane: WAXD and rheological studies. Macromolecules 40:4530CrossRef
33.
Miura Y, Okada M (2006) Synthesis of graft copolymer by ATRP of MMA from poly(phenylacetylene). J Polym Sci Part A Polym Chem 44:6697CrossRef
34.
Xu HY, Kuo SW, Lee JS, Chang FC (2002) Glass transition temperatures of poly(hydroxystyrene-covinylpyrrolidone-co-isobutylstyryl polyhedral oligosilsesquioxanes). Polymer 43:5117CrossRef
Metadaten
Titel
Synthesis and characterization of poly(methyl methacrylate) using monofunctional polyhedral oligomeric silsesquioxane as an initiator
verfasst von
Lei Liu
Wenping Wang
Publikationsdatum
01.03.2009
Verlag
Springer-Verlag
Erschienen in
Polymer Bulletin / Ausgabe 3/2009
Print ISSN: 0170-0839
Elektronische ISSN: 1436-2449
DOI
https://doi.org/10.1007/s00289-008-0020-0

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