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Rare Metals

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03.12.2018

Synthesis and hydrogen desorption kinetics of Mg₂FeH₆- and Mg₂CoH₅-based composites with in situ formed YH₃ and Mg₂NiH₄ nanoparticles

verfasst von: Can Li, Zhi-Wen Wu, Qing-An Zhang

Erschienen in: Rare Metals | Ausgabe 7/2023

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Abstract

Mg₂FeH₆- and Mg₂CoH₅-based composites with in situ formed YH₃ and Mg₂NiH₄ nanoparticles were synthesized by ball milling of Mg₁₀YNi + 4Fe (in mole ratio) and Mg₁₀YNi + 4Co powders, respectively, at 4 MPa H₂ followed by hydrogenation at 673 K for 60 h under a hydrogen pressure of 7 MPa. It is found that the nanocrystalline YH₃ and Mg₂NiH₄ particles are indeed embedded in Mg₂FeH₆ and Mg₂CoH₅ matrixes. The hydrogen desorption rates of Mg₂FeH₆- and Mg₂CoH₅-based composites are enhanced compared to those undoped Mg₂FeH₆ and Mg₂CoH₅ hydrides, respectively, due to the synergetic catalysis of nanosized YH₃ and Mg₂NiH₄ particles. This finding provides us with an efficient and simple approach for the improvement in hydrogen desorption kinetics of Mg-based hydrogen storage materials.

Vorheriger Artikel Ultrafine Ru nanoparticles anchored on core–shell structured zeolite-carbon for efficient catalysis of hydrogen generation

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Titel: Synthesis and hydrogen desorption kinetics of Mg2FeH6- and Mg2CoH5-based composites with in situ formed YH3 and Mg2NiH4 nanoparticles
verfasst von: Can Li
Zhi-Wen Wu
Qing-An Zhang
Publikationsdatum: 03.12.2018
Verlag: Nonferrous Metals Society of China
Erschienen in: Rare Metals / Ausgabe 7/2023
Print ISSN: 1001-0521
Elektronische ISSN: 1867-7185
DOI: https://doi.org/10.1007/s12598-018-1174-z

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