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Colloid and Polymer Science
Erschienen in: Colloid and Polymer Science 12/2016

12.10.2016 | Original Contribution

Synthesis and properties of novel branched polyether as demulsifiers for polymer flooding

Erschienen in: Colloid and Polymer Science | Ausgabe 12/2016

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Abstract

A novel branched polyether is prepared with 1,1,2,2-tetrakis (4-hydroxyphenyl) ethane as a core, amino groups as backbone, and polypropylene oxide (PPO)–polyethylene oxide (PEO) chains as branches based on phenol-amine resin, propylene oxide (PO), and ethylene oxide (EO). The surface activity is investigated by surface tension measurement at different temperature. The increase in PO/EO ratio or PPO chain lengths improve the surface activity and decrease the critical micelle concentration (cmc) as well as increase the temperature. The addition of inorganic salts causes a slight increase in cmc. The demulsification of water-in-crude-oil (W/O) emulsions, whether from polymer flooding or not, shows that the branched polyether is a good demulsifier to break the W/O emulsions. The stability of W/O emulsion in the presence of polyether shows that the highest water dehydration is not necessarily the highest stability index of W/O emulsion due to the turbidity of separated water. The demulsification process is also observed by microscope. Distribution of the polyether after demulsification is evaluated by partition coefficient at various concentrations.
Vorheriger Artikel Incorporation of Fe@Au nanoparticles into multiresponsive pNIPAM-AAc colloidal gels modulates drug uptake and release
Nächster Artikel Thermal-responsive poly(N-isopropyl acrylamide)/sodium alginate hydrogels: preparation, swelling behaviors, and mechanical properties

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Metadaten
Titel
Synthesis and properties of novel branched polyether as demulsifiers for polymer flooding
Publikationsdatum
12.10.2016
Erschienen in
Colloid and Polymer Science / Ausgabe 12/2016
Print ISSN: 0303-402X
Elektronische ISSN: 1435-1536
DOI
https://doi.org/10.1007/s00396-016-3956-x

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