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2017 | OriginalPaper | Buchkapitel

2. Synthesis and Reactivity of Cage Metal Complexes

verfasst von : Yan Voloshin, Irina Belaya, Roland Krämer

Erschienen in: Cage Metal Complexes

Verlag: Springer International Publishing

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Abstract

Synthesis of cage metal complexes of different symmetry and functionality is one of the most important tasks in the chemistry of these compounds with unique or uncommon chemical, physicochemical, and physical properties. Until publication of our first book on clathrochelate chemistry in 2002 [1], main synthetic approaches for preparation of various types of clathrochelates have included:

Template self-assembly on a suitable metal ion as a matrix (for all the classes of such cage complexes)

Coordination of an initially prepared encapsulating ligand toward an appropriate metal ion (for the conformationally labile polyamine and polyimine ligands)

Nucleophilic substitution with highly active nucleophiles (for the reactive halogenoclathrochelates)

Transmetallation (a capping group exchange) reaction [for the cage complexes with labile cross-linking group(s)]

Chemical transformation of apical substituent(s) at a cage framework [for the clathrochelates with reactive terminal group(s)]

Condensation of an appropriate macrocyclic precursor with a suitable ligand synthon

Macrobicyclization (cross-linking) of a reactive semiclathrochelate precursor (first of all, for the hydrazonate, oximehydrazonate, and azineoximate cage complexes)

Imine condensation (for the Schiff-base clathrochelates)

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Vorheriges Kapitel General Considerations

Nächstes Kapitel Spacial and Electronic Structure of Cage Metal Complexes

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Titel: Synthesis and Reactivity of Cage Metal Complexes
verfasst von: Yan Voloshin
Irina Belaya
Roland Krämer
Verlag: Springer International Publishing
Buch: Cage Metal Complexes
Print ISBN: 978-3-319-56419-7

Electronic ISBN: 978-3-319-56420-3

Copyright-Jahr: 2017
DOI: https://doi.org/10.1007/978-3-319-56420-3_2

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