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Colloid and Polymer Science
Erschienen in: Colloid and Polymer Science 3/2015

01.03.2015 | Original Contribution

Synthesis and solution property of acrylamide-sulfobetaine copolymers

verfasst von: Tao Ye, Yihu Song, Qiang Zheng

Erschienen in: Colloid and Polymer Science | Ausgabe 3/2015

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Abstract

Sulfobetaine 3-[N,N-dimethyl-N-(2-methacryloxylethyl)ammonio]-propane sulfonate (DMAPS) was used to copolymerize with acrylamide (AM) to prepare salt-sensitive copolymers. The optimal reaction conditions, such as initiator concentration, temperature, and reaction time, to achieve the largest weight averaged molecular weight (M w) and the lowest polydispersity index (PDI) were studied. The reactivity ratios of AM and DMAPS (r 1, r 2) were calculated to be (0.45, 0.84) by the Fineman-Ross method, and (0.47, 0.91) by the Kelen-Tüdös method. The Q-e values of DMAPS were calculated to be (0.30, −0.38). DMAPS was found to be more easily to add into the copolymer than AM to form random copolymers with a slight alternating tendency. Solution rheology and molecular size of the copolymers as a function of M w were studied in 1 M NaCl solution, a near θ-solution, by rotational rheometer and light scattering methods, respectively. Undisturbed dimension of the copolymers was evaluated according to Stockmayer-Fixman relation.
Vorheriger Artikel Determination of the critical micellar temperature of F127 aqueous solutions at the presence of sodium bromide by cyclic voltammetry
Nächster Artikel Synthesis of multifunctional microspheres having polymer brush with magnetism, fluorescence, and pH-responsiveness

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Metadaten
Titel
Synthesis and solution property of acrylamide-sulfobetaine copolymers
verfasst von
Tao Ye
Yihu Song
Qiang Zheng
Publikationsdatum
01.03.2015
Verlag
Springer Berlin Heidelberg
Erschienen in
Colloid and Polymer Science / Ausgabe 3/2015
Print ISSN: 0303-402X
Elektronische ISSN: 1435-1536
DOI
https://doi.org/10.1007/s00396-014-3467-6

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