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Polymer Bulletin
Erschienen in: Polymer Bulletin 11/2019

10.01.2019 | Original Paper

Synthesis, characterization and properties of poly(N-allyl-tetrasubstituted imidazole)

verfasst von: Haikun Chang, Xiaodong Chen, Qingyang Hu, Yanpeng Shi, Ran Zheng, Jie Fan, Qiang Gu, Yumin Zhang

Erschienen in: Polymer Bulletin | Ausgabe 11/2019

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Abstract

A new poly(N-allyl-tetrasubstituted imidazole) containing furan rings and benzene ring was synthesized starting from 1-allyl-4,5-di(furan-2-yl)-2-phenyl-1H-imidazole (N-allyl-tetrasubstituted imidazole, monomer) using benzoyl peroxide as an initiator coupled with the mixture of benzene and water as solvents. The influence factors on the conversion of N-allyl-tetrasubstituted imidazole (monomer) were optimized by the orthogonal experiment. The structure and property of the obtained monomer and polymers were characterized by Fourier infrared spectroscopy, high-resolution mass spectroscopy, nuclear magnetic resonance spectroscopy, X-ray diffraction, gel permeation chromatography, differential scanning calorimetry and thermogravimetric analysis. Moreover, the luminescence property of monomer and polymers from the different polymerization conditions was investigated. The results showed that the luminescence property and thermal stability of polymer were related to molecular weight and the crystallization degree of polymer, and their thermal stability was markedly better than monomer. It suggested that poly(N-allyl-tetrasubstituted imidazole) had potential application in the fields of heat-resistant material and luminescence material.
Vorheriger Artikel Fabrication of PVA/ZnO fibrous composite polymer as a novel sorbent for arsenic removal: design and a systematic study
Nächster Artikel The comparative investigation on synthesis, characterizations of silver ion-imprinting and non-imprinting cryogels, their impedance spectroscopies and relaxation mechanisms

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Metadaten
Titel
Synthesis, characterization and properties of poly(N-allyl-tetrasubstituted imidazole)
verfasst von
Haikun Chang
Xiaodong Chen
Qingyang Hu
Yanpeng Shi
Ran Zheng
Jie Fan
Qiang Gu
Yumin Zhang
Publikationsdatum
10.01.2019
Verlag
Springer Berlin Heidelberg
Erschienen in
Polymer Bulletin / Ausgabe 11/2019
Print ISSN: 0170-0839
Elektronische ISSN: 1436-2449
DOI
https://doi.org/10.1007/s00289-019-02680-8

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