Skip to main content
Fachgebiete
Automobil + Motoren Bauwesen + Immobilien Business IT + Informatik Elektrotechnik + Elektronik Energie + Nachhaltigkeit Finance + Banking Management + Führung Marketing + Vertrieb Maschinenbau + Werkstoffe Versicherung + Risiko
DE
EN
Bücher
Zeitschriften
Themenseiten
Organisationspsychologie Projektmanagement Marketing Smart Manufacturing
Weitere Formate
Podcasts Webinare Technik Webinare Wirtschaft Kongresse Veranstaltungskalender Awards
Jetzt Einzelzugang starten
Zugang für Unternehmen
Referenzkunden
SLX-Digitalkonferenz: Zukunftswerkstatt 2024

Mehr Umsatz mit Top-Kontakten

Am 7. Mai erfahren Sie, wie Vertriebsteams Leadgenerierung, Leadnurturing und Leadstrategien effizient steuern können.
Erweiterte Suche
Anmelden
nach oben
Polymer Bulletin
Erschienen in: Polymer Bulletin 7/2017

10.11.2016 | Original Paper

Synthesis, characterization, electrochemical and surface morphology properties of poly(azomethine-ester)s

verfasst von: Kevser Temizkan, İsmet Kaya

Erschienen in: Polymer Bulletin | Ausgabe 7/2017

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config
loading …

Abstract

In this study, poly(azomethine-ester)s (PAEs) were synthesized via elimination reactions of aromatic dihydroxy compounds containing imine bonding with terephthaloyl chloride. The structures of PAEs containing different aliphatic chains and ether bridges were confirmed by FT-IR, 1H, 13C-NMR and UV-Vis measurements. Electrochemical parameters of the synthesized SBs and PAEs were determined by cyclic voltammetry measurements. Thermal properties of the synthesized monomers and polymers were investigated by TG–DTA, DMA and DSC techniques. Molecular mass distributions of PAEs are determined with gel permeation chromatography measurements. Morphological and topographic properties of the SBs and PAEs containing azomethine linkage in the main chain were investigated by SEM and AFM techniques, respectively. Maximum particle sizes on surfaces of polymers were calculated with AFM analyses. Surface modifications of poly(azomethine-ester)s and maximum particle size on their surface were studied with topographic and 3D AFM images and particular size curves.
Vorheriger Artikel Enthalpy relaxation of the glass of poly (l-lactic acid) of different d-isomer content and its effect on mechanical properties
Nächster Artikel Unsymmetrical pyrazole-based new semiconductor oligomer: synthesis and optical properties

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Jetzt informieren
Literatur
1.
Cerrada P, Oriol L, Pinol M, Serrano JL, Iribarren I, Guerro SM (1996) Mechanical properties and characterization of the crystalline structure in annealed thermotropic poly(azomethines). Macromolecules 29:2515–2523CrossRef
2.
Cerrada P, Oriol L, Pinol M, Serrano JL, Alonso PJ, Puértolas JA, Iribarren I, Guerra SM (1999) Influence of hydroxy functionalization and metal cross-linking on fiber properties of liquid-crystalline polyazomethines. Macromolecules 32:3565–3573CrossRef
3.
Marin L, Cozan V, Bruma M, Grigoras VC (2006) Synthesis and thermal behaviour of new poly(azomethine-ether). Eur Polym J 42:1173–1182CrossRef
4.
Marin L, Cozan V, Bruma M (2006) Comparative study of new thermotropic polyazomethines. Polym Adv Technol 17:664–672CrossRef
5.
Flory PJ (1956) Statistical thermodynamics of semi flexible chain molecules. Proc Roy Coc Lond A Ser A 234:60–73CrossRef
6.
Gennes PG, Seances CR (1975) Académie des sciences—series 281B:101–103
7.
Sek D (1984) Liquid crystalline polymers VII. Thermotropic liquid crystalline poly (azomethine-ether)s containing dibenzylidene derivatives in the main chain. Eur Polym J 20:923–926CrossRef
8.
Li CH, Chang TC (1991) Thermotropic liquid crystalline polymer. III. Synthesis and properties of poly(amide-azomethine-ester). J Polym Sci Part A Polym Chem 29:361–367CrossRef
9.
Percec V, Yourd R (1989) Thermotropic polyethers and copolyethers based on 1-(4-hydroxyphenyl)-2-(2-methyl-4-hydroxyphenyl) ethane and flexible spacers containing an odd number of methylene units. Macromolecules 22:524–537CrossRef
10.
Gul A, Akhter Z, Siddiq M, Sarfraz S, Mirza B (2013) Ferrocene-based aliphatic and aromatic poly(azomethine)esters: synthesis, physicochemical studies, and biological evaluation. Macromolecules 46:2800–2807CrossRef
11.
Hafeez N, Siddiqi HM, Zaman S, Akhter Z (2015) Multi-segment poly(azomethine)esters: synthesis, characterization and thermal studies. J Chem Soc Pak 37:484–491
12.
Morgan PW, Kwolek SL, Plecher TC (1987) Aromatic azomethine polymers and fibers. Macromolecules 20:729–739CrossRef
13.
Wojkowski PW (1987) Aromatic-aliphatic azomethine ether polymers and fibers. Macromolecules 20:740–748CrossRef
14.
Yeakel KG, Mani RS, Allen RD, Mohanty DK (1993) Synthesis and characterization of processable aromatic poly(azomethine)s with ether linkages. Macromol Chem Phys 194:2779–2787CrossRef
15.
Yang CJ, Jenekhe SA (1995) Conjugated aromatic polyimines. 2. Synthesis, structure, and properties of new aromatic polyazomethines. Macromolecules 28:1180–1196CrossRef
16.
Fukuda K, Shimoda M, Sukegawa M, Nobori T, Lehn JM (2012) Doubly degradable dynamers: dynamic covalent polymers based on reversible imine connections and biodegradable polyester units. Green Chem 14:2907–2911CrossRef
17.
Bounekhel M, McNeill IC (1996) Thermal degradation studies of terephthalate polyesters: 3. Diphenylene and phenylene terephthalate polymers. Polym Degrad Stab 51:35–43CrossRef
18.
Iwan A, Sek D (2008) Processable polyazomethines and polyketanils: from aerospace to light emitting diodes and other advanced applications. Prog Polym Sci 33:289–345CrossRef
19.
Balagi K, Murugavel SC (2011) Synthesis and characterization of photosensitive liquid crystalline poly(benzylidene-ether)s with alkanones and methylene spacers in the main chain. J Polym Sci Part A Polym Chem 49:4809–4819CrossRef
20.
Gul A, Akhter Z, Bhatti A, Mirza B (2012) Synthesis, physicochemical studies and potential applications of high-molecular-weight ferrocene-based poly(azomethine)ester and its soluble terpolymers. J Organomet Chem 719:41–53CrossRef
21.
Pavia DL, Lampman GM, Kriz GS (2001) Introduction to spectroscopic, 3rd edn. Thomson Learning Inc., New York
22.
Kannan P, Raja S, Sakthivel P (2004) Synthesis and characterization of thermotropic liquid crystalline poly (azomethine ether). Polymer 45:7895–7902CrossRef
23.
Shukla U, Rao KV, Rakshit AK (2003) Thermotropic liquid-crystalline polymers: synthesis, characterization, and properties of poly(azomethine esters). J Appl Polym Sci 88:153–160CrossRef
24.
Akhter Z, Khan MS, Bashir MA (2004) Novel organometallic aromatic azopolyesters based on ferrocene. J Inorg Organomet Polym 14:253–267CrossRef
25.
Avcı A, Temizkan K, Kaya İ (2015) Sulfone group containing poly(azomethine-urethane)s: thermal stability, optical and electrochemical properties. Polym Bull 72:2871–2889CrossRef
26.
Kaya İ, Temizkan K, Aydın A (2013) Synthesis and characterization of aromatic and aliphatic ether bridged polymers containing carbazole moieties. Mater Sci Eng B 178:863–874CrossRef
27.
Kaya İ, Temizkan K, Aydın A (2013) Synthesis and characterization of ether bridged polymers and their fluorescent, thermal, conductivity, optical and electrochemical properties. J Electroanal Chem 708:54–61CrossRef
28.
Aly KI, Hammam AS, Radwan SM, Abdel-Rahman MA (2011) New unsaturated copolyesters based on diarylidenecyclopentanone. Optimum conditions of synthesis, characterization and morphology. J Basic Appl Sci 11:15–35
29.
Malathy N, Singh DR (2012) Synthesis and characterization of certain photocrosslinkable random copolyesters from 4,4′-oxybis(benzoic acid). Int J Chem Res 2:1–13
30.
Kaya İ, Yıldırım M, Avcı A, Kamacı M (2011) Synthesis and thermal characterization of novel poly(azomethine-urethane)s derived from azomethine containing phenol and polyphenol species. Macromol Res 19:286–293CrossRef
31.
Kaya İ, Kılavuz E (2015) Novel multicolor Schiff base polymers prepared via oxidative polycondensation. J Flouresc 25(3):663–673CrossRef
32.
Avcı A, Kaya İ (2015) A new selective fluorescent sensor for Zn(II) ions based on poly(azomethine-urethane). Tetrahedron Lett 56(14):1820–1824CrossRef
33.
Vasanthi BJ, Ravikumar L (2013) Synthesis and Characterization of Poly(azomethine ester)s with a Pendent Dimethoxy Benzylidene Group. Open J Polym Chem 3:70–77CrossRef
34.
Vasanthi BJ, Ravikumar L (2007) Synthesis and characterization of new poly(azomethine ester)s having phenylthiourea units. Eur Polym J 43:4325–4331CrossRef
35.
Lim WL, Oo CW, Choo YSL, Looi ST (2015) New generation of photosensitive poly(azomethine)esters: thermal behaviours, photocrosslinking and photoluminescence studies. Polymer 71:15–22CrossRef
36.
Kamacı M, Kaya İ (2016) New low-band gap polyurethanes containing azomethine bonding: photophysical, electrochemical, thermal and morphological properties. J Taiwan Inst Chem Eng 59:536–546CrossRef
37.
Doğan F, Kaya İ, Temizkan K (2016) Regioselectively functionalized synthesis of poly(amino naphthalene disulfonic acid. Synth Met 215:77–85CrossRef
38.
Iwan A, Palewicz M, Chuchmała A, Pasciak G (2012) Optoelectrical properties of new aromatic polyazomethines with fluorene moieties in the main chain for polymeric photovoltaic devices. Synth Met 162(1–2):143–153CrossRef
Metadaten
Titel
Synthesis, characterization, electrochemical and surface morphology properties of poly(azomethine-ester)s
verfasst von
Kevser Temizkan
İsmet Kaya
Publikationsdatum
10.11.2016
Verlag
Springer Berlin Heidelberg
Erschienen in
Polymer Bulletin / Ausgabe 7/2017
Print ISSN: 0170-0839
Elektronische ISSN: 1436-2449
DOI
https://doi.org/10.1007/s00289-016-1851-8

Weitere Artikel der Ausgabe 7/2017

Polymer Bulletin 7/2017 Zur Ausgabe

Original Paper

A novel polyurethanes from epoxidized soybean oil synthesized by ring opening with bifunctional compounds

Original Paper

Production, characterization, and surface morphology of novel aromatic poly(amide-ester-imide)/functionalized TiO2 nanocomposites via ultrasonication assisted process

Original Paper

The effects of two-step reactive processing on the properties of recycled poly(ethylene terephthalate)

Original Paper

Synthesis and properties of thiophene- and quinoxaline-based random copolymers for organic photovoltaics

Original Paper

Synthesis and properties of castor oil based polyurethanes reinforced with double-decker silsesquioxane

Original Paper

Electrospinning TPU/poly o-phenetidine (POEA) fibers: influence of POEA on fiber morphology

Premium Partner

    Marktübersichten

    Die im Laufe eines Jahres in der „adhäsion“ veröffentlichten Marktübersichten helfen Anwendern verschiedenster Branchen, sich einen gezielten Überblick über Lieferantenangebote zu verschaffen. 

    Zur Marktübersicht
    Bildnachweise