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Journal of Coatings Technology and Research

Erschienen in:

19.02.2020

Synthesis of butyl acrylate–styrene–TMI latexes and their application as water-based coatings

verfasst von: Luis E. Elizalde, Juan J. Mendoza, Raquel Ledezma-Rodríguez, María E. Treviño, Margarita Mondragon

Erschienen in: Journal of Coatings Technology and Research | Ausgabe 4/2020

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Abstract

Self-crosslinking styrene-acrylic latexes functionalized with 3-isopropenyl-α,α-dimethyl benzyl isocyanate (TMI) by semibatch emulsion polymerization were prepared. Polymerizations were performed in emulsions with aerosol EF-800 surfactant; remarkable colloidal stability of the copolymer latexes was measured in fresh and aged samples. The effects on film formation, tensile properties, permeability to water vapor, and oxygen were evaluated by varying the TMI concentrations (from 0 to 6 wt%). The obtained latexes were used as binder to prepare water-based coatings, which were applied on steel specimens; hydrolysis of TMI acts as a self-crosslinked promoter once the film was applied. Adhesion tests, scratch hardness, and gloss properties were evaluated.

Graphic abstract

Water vapor permeability of latex films

Vorheriger Artikel Computations of coating windows for reverse roll coating of liquid films

Nächster Artikel Exploration of high corrosion resistance property of less hazardous pyrazolidine-based benzoxazines in comparison with bisphenol-F derivatives

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Sørensen, PA, Kiil, S, Dam-Johansen, K, Weinell, CE, “Anticorrosive Coatings: A Review.” J. Coat. Technol. Res., 6 135–176 (2009)CrossRef

Mohamed, HA, “Eco-Friendly Zero VOC Anticorrosive Paints for Steel Protection.” J. Appl. Polym. Sci., 125 1790–1795 (2012)CrossRef

Slomkowski, S, Aleman, JV, Gilbert, RG, Hess, M, Horie, K, Jones, RG, Kubisa, P, Meisel, I, Mormann, W, Penczeck, S, Stepto, RFT, “Terminology of Polymers and Polymerization Processes in Dispersed Systems (IUPAC Recommendations 2011).” Pure Appl. Chem., 83 2229–2259 (2011)CrossRef

Lovell, PA, El-Aasser, MS, Emulsion Polymerization and Emulsion Polymers. Wiley, New York (1997)

Mohammed, S, Daniels, ES, Klein, A, El-Aasser, MS, “Emulsion Terpolymerization of Dimethyl Meta-lsopropenyl Benzyl Isocyanate (TMP) with Acrylic Monomers: Process Development and Kinetics.” J. Appl. Polym. Sci., 61 911–921 (1996)CrossRef

Mohammed, S, Daniels, ES, Sperling, LH, Klein, A, “Isocyanate-Functionalized Latexes: Film Formation and Tensile Properties.” J. Appl. Polym. Sci., 66 1869–1884 (1997)CrossRef

Mohammed, S, Daniels, ES, Klein, A, El-Aasser, MS, “Seeded Emulsion Terpolymerization of Dimethyl Meta-isopropenyl Benzyl Isocyanate (TMI^®) with Acrylic Monomers.” J. Appl. Polym. Sci., 67 685–694 (1998)CrossRef

Ramirez, JC, Treviño, ME, Herrera, J, Macossay, J, “Hydrolysis of Dimethyl Meta-Isopropenylbenzyl Isocyanate (TMI) and Colloidal Stability of Latexes During Storage: Effect of pH.” J. Macromol. Sci. B Phys., 51 767–776 (2012)CrossRef

Lovell, PA, Yoon, J, “Studies of Dimethyl Meta-Isopropenylbenzyl Isocyanate (TMI) for Preparation of Ambient Cross-Linkable Latexes—Stability of NCO Groups in Latex Form.” J. Macromol. Sci. B, 44 1041–1063 (2005)CrossRef

10.

Lovell, PA, Yoon, J, “Studies of Dimethyl Meta-Isopropenylbenzyl Isocyanate (TMI) for Preparation of Ambient Cross-Linkable Latexes—Film Formation and Cross-Linking.” J. Macromol. Sci. B, 44 1065–1086 (2005)CrossRef

11.

Yoon, J, Lovell, PA, “Model Reaction Studies and Crosslinking of Dimethyl-Meta-Isopropenylbenzyl Isocyanate Containing Ambient Crosslinkable Latex.” Macromol. Chem. Phys., 209 279–289 (2008)CrossRef

12.

Treviño, ME, Dubé, MA, “Synthesis of Self-Crosslinkable Water-Borne Pressure Sensitive Adhesives.” Macromol. React. Eng., 7 484–492 (2013)CrossRef

13.

Sajjadi, S, Brooks, BW, “Butyl Acrylate Batch Emulsion Polymerization in the Presence of Sodium Lauryl Sulphate and Potassium Persulphate.” J. Polym. Sci. A Polym. Chem., 37 3957–3972 (1999)CrossRef

14.

Xu, J, Dimonie, VL, Sudol, ED, El-Aasser, MS, “Crosslinking of Isocyanate Functional Acrylic Latex with Telechelic Polybutadiene. I. Synthesis and Characterization.” J. Appl. Polym. Sci., 69 965–975 (1998)CrossRef

15.

Li, S, Guan, Y, Liu, L, “Effect of Latex Conversion on Glass Transition Temperature.” Nat. Sci., 2 515–518 (2010)

16.

Sajjadi, S, Brooks, BW, “Semibatch Emulsion Polymerization of Butyl Acrylate. I. Effect of Monomer Distribution.” J. Appl. Polym. Sci., 74 3094–3110 (1999)CrossRef

17.

Herrera, J, Olayo, R, Carro, S, “The Kinetics of Emulsion Polymerization: Some Controversial Aspects.” J. Macromol. Sci. C Polym. Rev., 44 207–229 (2004)CrossRef

18.

Mendoza, JJ, Ledezma, R, Elizalde, LE, “Self-Crosslinking Water Base Latex with Low VOC Emission.” MRS Proc., 1613 61–66 (2014)CrossRef

19.

Barner, L, Barner-Kowollik, C, Davis, TP, “Free-Radical Copolymerization of Styrene and m-Isopropenyl-α,α′-Dimethylbenzyl Isocyanate Studied by ¹H NMR Kinetic Experiments.” J. Polym. Sci. A Polym. Chem., 40 1064–1074 (2002)CrossRef

20.

He, Y, Daniels, ES, Klein, A, El-Aasser, MS, “Study of the Consumption of TMI^® in Latex Using Attenuated Total Reflectance FTIR (ATR-FTIR).” J. Appl. Polym. Sci., 65 1967–1973 (1997)CrossRef

21.

Pauly, AS, “Permeability and Diffusion Data.” In: Brandrup, J, Immergut, EH, Grulke, EA (eds.) Polymer Handbook VI, pp. 543–569. Wiley, New York (1999)

22.

Devona, JE, Essigmann, ML, “Vinylidene Chloride and Styrene-Containing Copolymer Latices.” US Patent 4500673A, 1983

23.

Mirzataheri, M, “High Solid Contents Copoly (Styrene/Butyl Acrylate)-Cloisite 30B Nanocomposites.” J. Nanostruct., 3 93–101 (2013)

24.

Badran, BM, Mohammed, HA, Aglan, HA, “Effect of Different Polymers on the Efficiency of Water-Borne Methyl Amine Adduct as Corrosion Inhibitor for Surface Coatings.” J. Appl. Polym. Sci., 85 879–885 (2002)CrossRef

Titel: Synthesis of butyl acrylate–styrene–TMI latexes and their application as water-based coatings
verfasst von: Luis E. Elizalde
Juan J. Mendoza
Raquel Ledezma-Rodríguez
María E. Treviño
Margarita Mondragon
Publikationsdatum: 19.02.2020
Verlag: Springer US
Erschienen in: Journal of Coatings Technology and Research / Ausgabe 4/2020
Print ISSN: 1547-0091
Elektronische ISSN: 1935-3804
DOI: https://doi.org/10.1007/s11998-020-00325-4

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