Skip to main content
Fachgebiete
Automobil + Motoren Bauwesen + Immobilien Business IT + Informatik Elektrotechnik + Elektronik Energie + Nachhaltigkeit Finance + Banking Management + Führung Marketing + Vertrieb Maschinenbau + Werkstoffe Versicherung + Risiko
DE
EN
Bücher
Zeitschriften
Themenseiten
Organisationspsychologie Projektmanagement Marketing Smart Manufacturing
Weitere Formate
Podcasts Webinare Technik Webinare Wirtschaft Kongresse Veranstaltungskalender Awards
Jetzt Einzelzugang starten
Zugang für Unternehmen
Referenzkunden
SLX-Digitalkonferenz: Zukunftswerkstatt 2024

Mehr Umsatz mit Top-Kontakten

Am 7. Mai erfahren Sie, wie Vertriebsteams Leadgenerierung, Leadnurturing und Leadstrategien effizient steuern können.
Erweiterte Suche
Anmelden
nach oben
Journal of Sol-Gel Science and Technology
Erschienen in: Journal of Sol-Gel Science and Technology 1/2017

27.12.2016 | Original Paper: Sol-gel and hybrid materials for catalytic, photoelectrochemical and sensor applications

Synthesis of mesoporous tungsten oxide by template-assisted sol–gel method and its photocatalytic degradation activity

verfasst von: Banafsheh Mirtaheri, Mohammadreza Shokouhimehr, Ali Beitollahi

Erschienen in: Journal of Sol-Gel Science and Technology | Ausgabe 1/2017

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config
loading …

Abstract

In this study, mesoporous tungsten oxide nanostructure was successfully synthesized using inexpensive peroxotungstic acid as a tungsten precursor, and pluronic P123 blockcopolymer as a template. Various techniques such as differential thermal analysis, thermogravimetric analysis, Fourier transformed infrared spectroscopy, X-ray diffraction, field emission scanning electron microscopy, nitrogen adsorption/desorption analysis, and UV–Vis spectroscopy were utilized to characterize the prepared tungsten oxide. Nitrogen adsorption/desorption analysis demonstrated the formation of mesoporous structure with the specific surface area of 67 m2/g and pore size of ~ 6 nm after calcination at 500 oC for 1 h. Microstuctural investigation by field emission scanning electron microscopy images revealed the existence of spherical morphology for the prepared mesoporous tungsten oxide powder. X-ray diffraction analysis confirmed the formation of orthorhombic crystalline structure. In addition, the calculated energy band gap of the calcined product was found to be 2.60 eV. Further, photocatalytic activity of the synthesized crystalline powder was verified for Rhodamine B degradation, giving rise to 79% dye removal from aqueous solution with 6 mg/L concentration under ultraviolet irradiation.

Graphical Abstract

https://static-content.springer.com/image/art%3A10.1007%2Fs10971-016-4289-4/MediaObjects/10971_2016_4289_Figa_HTML.gif
Vorheriger Artikel Effect of ethylene glycol on structure, thermal stability, oxygen storage capacity, and catalytic CO and CH4 oxidation activities of binary CeO2–Al2O3 and ternary CeO2–ZrO2–Al2O3 cryogels
Nächster Artikel TiO2 hierarchical porous films sensitized by Sb2S3 nanoparticles for enhanced photoelectrochemical properties

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Jetzt informieren
Literatur
1.
Wen R-T, Granqvist CG, Niklasson Ga (2015) Eliminating degradation and uncovering ion-trapping dynamics in electrochromic WO3 thin films. Nat Mater 14:996–1001CrossRef
2.
He T, Yao J (2007) Photochromic materials based on tungsten oxide. J Mater Chem 17:4547–4557CrossRef
3.
Hagizawa T, Honma T, Kuroki Y, Okamoto T, Takata M (2013) Relationship between particle size and photochromic characteristics of tungsten oxide films prepared by electric current heating method using tungsten wire. Ceram Int 39:2851–2855CrossRef
4.
Kundu S, Subramanian I, Narjinary M, Manna R (2016) Enhanced performance of γ-Fe2O3:WO3 nanocomposite towards selective acetone vapor detection. Ceram Int 42:7309–7314CrossRef
5.
Liu S, Zhang F, Li H, Chen T, Wang Y (2012) Acetone detection properties of single crystalline tungsten oxide plates synthesized by hydrothermal method using cetyltrimethyl ammonium bromide supermolecular template. Sensors Actuators B Chem 162:259–268CrossRef
6.
Jo C, Hwang J, Song H, Dao AH, Kim Y-T, Lee SH, Hong SW, Yoon S, Lee J (2013) Block-copolymer-assisted one-pot synthesis of ordered mesoporous WO3–x /Carbon nanocomposites as high-rate-performance electrodes for pseudocapacitors. Adv Funct Mater 23:3747–3754CrossRef
7.
Hunge YM, Mahadik Ma, Kumbhar SS, Mohite VS, Rajpure KY, Deshpande NG, Moholkar aV, Bhosale CH (2016) Visible light catalysis of methyl orange using nanostructured WO3 thin films. Ceram Int 42:789–798CrossRef
8.
Schieder M, Lunkenbein T, Martin T, Milius W, Auffermann G, Breu J (2013) Hierarchically porous tungsten oxide nanotubes with crystalline walls made of the metastable orthorhombic polymorph. J Mater Chem A 1:381–387CrossRef
9.
Wicaksana Y, Liu S, Scott J, Amal R (2014) Tungsten Trioxide as a Visible Light Photocatalyst for Volatile Organic Carbon Removal. Molecules 19:17747–17762CrossRef
10.
Zhao Z-G, Miyauchi M (2008) Nanoporous-walled tungsten oxide nanotubes as highly active visible-light-driven photocatalysts. Angew Chemie 47:7051–7055CrossRef
11.
Usami Y, Hongo T, Yamazaki A (2012) Phosphate constituent effects on the structure and photocatalytic properties of mesoporous tungsten oxides. Microporous Mesoporous Mater 158:13–18CrossRef
12.
Miao R, Luo Z, Zhong W, Chen S-Y, Jiang T, Dutta B, Nasr Y, Zhang Y, Suib SL (2016) Mesoporous TiO2 modified with carbon quantum dots as a high-performance visible light photocatalyst. Appl Catal B Environ 189:26–38CrossRef
13.
Kamali E, Zamani C, Marzbanrad E, Raissi B, Nazarpour S (2010) Chemical WO3 -based NO2 sensors fabricated through low frequency AC electrophoretic deposition. Sensors Actuators B Chem 146:165–170CrossRef
14.
Zamani C, Casals O, Andreu T, Morante JR, Romano-Rodriguez A (2009) Detection of amines with chromium-doped WO3 mesoporous material. Sensors Actuators B Chem 140:557–562CrossRef
15.
Hoa ND, Van Duy N, Van Hieu N (2013) Crystalline mesoporous tungsten oxide nanoplate monoliths synthesized by directed soft template method for highly sensitive NO2 gas sensor applications. Mater Res Bull 48:440–448CrossRef
16.
Pal N, Bhaumik A (2013) Soft templating strategies for the synthesis of mesoporous materials: inorganic, organic-inorganic hybrid and purely organic solids. Adv Colloid Interface Sci 189–190:21–41CrossRef
17.
Gu D, Schüth F (2014) Synthesis of non-siliceous mesoporous oxides. Chem Soc Rev 43:313–344CrossRef
18.
Ruren xu JC, PANG W, YU J, HUO Q (2007) Chemistry of zeolites and related porous materials  synthesis and structure. Wiley, Asia Pte Ltd. Singapore
19.
Teoh LG, Shieh J, Lai WH, Hon MH (2011) Effects of mesoporous structure on grain growth of nanostructured tungsten oxide. J Mater Res 19:2687–2693CrossRef
20.
Li C-P, Engtrakul C, Tenent RC, Wolden Ca (2015) Scalable synthesis of improved nanocrystalline, mesoporous tungsten oxide films with exceptional electrochromic performance. Sol Energy Mater Sol Cells 132:6–14CrossRef
21.
Yuan J, Zhang Y, Le J, Song L, Hu X (2007) New templated method to synthesize electrochromic mesoporous tungsten oxides. Mater Lett 61:1114–1117CrossRef
22.
Wang W, Pang Y, Hodgson SNB (2010) On key factors for the fabrication of mesoporous tungsten oxide films from tungstic acid. J Sol-Gel Sci Technol 58:135–141CrossRef
23.
Wang W, Pang Y, Hodgson SNB (2009) XRD studies of thermally stable mesoporous tungsten oxide synthesised by a templated sol—gel process from tungstic acid precursor. Microporous Mesoporous Mater 121:121–128CrossRef
24.
Wang W, Pang Y, Hodgson SNB (2010) Preparation, characterisation and electrochromic property of mesostructured tungsten oxide films via a surfactant templated sol—gel process from tungstic acid. J Sol-Gel Sci Technol 54:19–28CrossRef
25.
Wang W, Pang Y, Hodgson SNB (2010) Design and fabrication of bimodal meso-mesoporous WO3 thin films and their electrochromic properties. J Mater Chem 20:8591–8599
26.
Qi Z-M, Zhou H-S, Watanabe T, Honma I (2004) Synthesis, characterization and optical gas-sensing application of block copolymer templated mesostructured peroxopolytungstic acid films. J Mater Chem 14:3540CrossRef
27.
Solarska R, Alexander B, Augustynski J (2004) Electrochromic and structural characteristics of mesoporous WO3 films prepared by a sol-gel method. J Solid State Electrochem 8:748–756CrossRef
28.
Pecquenard B, Castro-garcia S, Livage J, Zavalij PY, Whittingham MS (1998) Structure of hydrated tungsten peroxides [WO2(O2)H2O ].nH2O. Chem Mater 2:1882–1888CrossRef
29.
Soliman HMA, Kashyout AB, El Nouby MS, Abosehly AM (2012) Effect of hydrogen peroxide and oxalic acid on electrochromic nanostructured tungsten oxide thin films. Int J Electrochem Sci 7:258–271
30.
Teoh LG, Shieh J, Lai WH, Hung IM, Hon MH (2005) Structure and optical properties of mesoporous tungsten oxide. J Alloys Compd 396:251–254CrossRef
31.
Shameli K, Bin Ahmad M, Jazayeri SD, Sedaghat S, Shabanzadeh P, Jahangirian H, Mahdavi M, Abdollahi Y (2012) Synthesis and characterization of polyethylene glycol mediated silver nanoparticles by the green method. Int J Mol Sci 13:6639–6650CrossRef
32.
Lassner E, Schubert W (1999) Tungsten: properties, Chemistry, technology of the element, alloys, and chemical compounds erik lassner and wolf-dieter schubert. Kluwer Academic/Plenum Publishers, Asia Pte Ltd. Singapore
33.
Boulova M, Lucazeau G (2002) Crystallite Nanosize Effect on the Structural Transitions of WO3 Studied by Raman Spectroscopy. J Solid State Chem 167:425–434CrossRef
34.
Pecquenard B, Lecacheux H, Livage J, Julien C (1998) Orthorhombic WO3 formed via a Ti-Stabilized WO3.1/3H2O phase. J Solid State Chem 135:159–168CrossRef
35.
Balaji S, Djaoued Y, Albert A-S, Brüning R, Beaudoin N, Robichaud J (2011) Porous orthorhombic tungsten oxide thin films: synthesis, characterization, and application in electrochromic and photochromic devices. J Mater Chem 21:3940CrossRef
36.
Zhu K-R, Zhang M-S, Hong J-M, Yin Z (2005) Size effect on phase transition sequence of TiO2 nanocrystal. Mater Sci Eng A 403:87–93CrossRef
37.
Niepce JC, Caboche G (1994) Thermodynamic considerations of the grain size dependency of material properties a new approach to explain the variation of the dielectric permitlivity of BaTiO3 with grain size. J Therm Anal 41:635–649CrossRef
38.
Chang P-L, Wu Y-C, Lai S-J, Yen F-S (2009) Size effects on χ- to α-Al2O3 phase transformation. J Eur Ceram Soc 29:3341–3348CrossRef
39.
Frey MH, Payne Da (1996) Grain-size effect on structure and phase transformations for barium titanate. Phys Rev B 54:3158–3168CrossRef
40.
Sun Q, Aslan A, Li M, Chen M (2014) Effects of grain size on phase transition behavior of nanocrystalline shape memory alloys. Sci China Technol Sci 57:671–679CrossRef
41.
Lowell S, Shields JE, Thomas Ma, Thommes M (2004) Characterization of Porous Solids and Powders: Surface Area, Pore Size and Density. Springer, Netherlands, DordrechtCrossRef
42.
Kondo JN, Domen K (2008) Crystallization of mesoporous metal oxides. Chem Mater 20:835–847CrossRef
43.
Samiee L, Beitollahi a, Vinu a (2012) Effect of calcination atmosphere on the structure and photocatalytic properties of titania mesoporous powder. Res Chem Intermed 38:1467–1482CrossRef
44.
Watanabe H, Fujikata K, Oaki Y, Imai H (2013) Band-gap expansion of tungsten oxide quantum dots synthesized in sub-nano porous silica. Chem Commun (Camb) 49:8477CrossRef
45.
He Y, Wu Z, Fu L, Li C, Miao Y, Cao L, Fan H, Zou B (2003) Photochromism and Size Effect of WO3 and WO3—TiO2 Aqueous Sol Chem Mater 15:4039–4045CrossRef
46.
Li X, Ye J (2007) Photocatalytic degradation of Rhodamine B over Pb3Nb4O13 / fumed SiO2 composite under visible light irradiation. J Phys Chem 111:13109–13116
47.
Kim A, Rafiaei SM, Abolhosseini S, Shokouhimehr M (2015) Palladium nanocatalysts confined in mesoporous silica for heterogeneous reduction of nitroaromatics. energy environ. Focus 4:18–23
Metadaten
Titel
Synthesis of mesoporous tungsten oxide by template-assisted sol–gel method and its photocatalytic degradation activity
verfasst von
Banafsheh Mirtaheri
Mohammadreza Shokouhimehr
Ali Beitollahi
Publikationsdatum
27.12.2016
Verlag
Springer US
Erschienen in
Journal of Sol-Gel Science and Technology / Ausgabe 1/2017
Print ISSN: 0928-0707
Elektronische ISSN: 1573-4846
DOI
https://doi.org/10.1007/s10971-016-4289-4

Weitere Artikel der Ausgabe 1/2017

Journal of Sol-Gel Science and Technology 1/2017 Zur Ausgabe

Original Paper: Sol-gel and hybrid materials for biological and health (medical) applications

Effect of mass concentration on bioactivity and cell viability of calcined silica aerogel synthesized from rice husk ash as silica source

Original Paper: Nano-structured materials (particles, fibers, colloids, composites, etc.)

Influence of alcohol solvents on morphology of hollow silica–alumina composite spheres and their activity for hydrolytic dehydrogenation of ammonia borane

Original Paper: Nano-structured materials (particles, fibers, colloids, composites, etc.)

FeVO4 nanobelts: controllable synthesis by electrospinning and visible-light photocatalytic properties

Original Paper: Functional coatings, thin films and membranes (including deposition techniques)

Solubility of porous MgF2 films in water: influence of glass substrates

Original Paper: Functional coatings, thin films and membranes (including deposition techniques)

Reversible photochromic effect in the TiO2—polymer hybrid system

Original Paper: Sol-gel and hybrid materials with surface modification for applications

Facile fabrication of superhydrophobic SiO2-coated mesh used for corrosive and hot water/oil separation

Premium Partner

    Marktübersichten

    Die im Laufe eines Jahres in der „adhäsion“ veröffentlichten Marktübersichten helfen Anwendern verschiedenster Branchen, sich einen gezielten Überblick über Lieferantenangebote zu verschaffen. 

    Zur Marktübersicht
    Bildnachweise