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2019 | OriginalPaper | Buchkapitel

Synthesis of Metal/Metal Oxide Supported Reduced Graphene Oxide (RGO) for the Applications of Electrocatalysis and Supercapacitors

verfasst von : Lakshmanan Karuppasamy, Lakshmanan Gurusamy, Gang-Juan Lee, Jerry J. Wu

Erschienen in: Graphene Functionalization Strategies

Verlag: Springer Singapore

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Abstract

Reduced graphene oxide (RGO), atomically thin two-dimensional carbon nanosheets, owns outstanding chemical, electrical, material, optical, and physical properties due to its large surface area, high electron mobility, thermal conductivity, and stability. These unique properties have made reduced graphene oxide an ideal platform for constructing a series of RGO-based functional nanomaterials. Specifically, RGO and RGO derivatives have been utilized as templates for the synthesis of various noble-metal/metal oxide nanocomposites. These hybrid nanocomposites materials are promising alternatives to reduce the drawback of using only transition metal nanoparticles in various applications, such as electrochemical energy storage and conversion technology of supercapacitors and fuel cells. The goal of this chapter is to discuss the state-of-the-art of reduced graphene oxide-based metal and metal oxide nanocomposites with a detailed account of their synthesis and properties. Especially, much attention has been paid to their synthesis and a wide range of applications in various fields, such as electrochemical and electrical fields. This chapter is presented first time with an introduction, followed by synthetic methods of RGO and RGO-based nanocomposites. Then, the application of this novel RGO/metal-metal oxide nanocomposites in fuel cells and supercapacitors are summarized and discussed. Finally, the future research trends and challenges of design and synthesis of RGO/metal-metal oxide nanocomposites are presented.

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Literatur
1.
Novoselov, K.S., Geim, A.K., Morozov, S.V., Jiang, D.A., Zhang, Y., Dubonos, S.V., Firsov, A.A.: Electric field effect in atomically thin carbon films. Science 306(5696), 666–669 (2004)CrossRef
2.
Guo, S., Dong, S.: Graphene nanosheet: synthesis, molecular engineering, thin film, hybrids, and energy and analytical applications. Chem. Soc. Rev. 40(5), 2644–2672 (2011)CrossRef
3.
Allen, M.J., Tung, V.C., Kaner, R.B.: Honeycomb carbon: a review of graphene. Chem. Rev. 110(1), 132–145 (2009)CrossRef
4.
Liang, H.W., Zhuang, X., Brüller, S., Feng, X., Müllen, K.: Hierarchically porous carbons with optimized nitrogen doping as highly active electrocatalysts for oxygen reduction. Nat. Commun. 5, 4973 (2014)CrossRef
5.
Kroto, H.W., Heath, J.R., O’Brien, S.C., Curl, R.F., Smalley, R.E.: C60: Buckminsterfullerene. Nature 318(6042), 162 (1985)CrossRef
6.
Ajayan, P.M.: Capillarity-induced filling of carbon nanotubes. Nature 361(6410), 333 (1993)CrossRef
7.
Kauffman, D.R., Star, A.: Graphene versus carbon nanotubes for chemical sensor and fuel cell applications. Analyst 135(11), 2790–2797 (2010)CrossRef
8.
Fasolino, A., Los, J.H., Katsnelson, M.I.: Intrinsic ripples in graphene. Nat. Mater. 6(11), 858 (2007)CrossRef
9.
Antonietti, M., Müllen, K.: Carbon: the sixth element. Adv. Mater. 22(7), 787 (2010)CrossRef
10.
Khan, M., Tahir, M.N., Adil, S.F., Khan, H.U., Siddiqui, M.R.H., Al-Warthan, A.A., Tremel, W.: Graphene-based metal and metal oxide nanocomposites: synthesis, properties, and their applications. J. Mater. Chem. A 3(37), 18753–18808 (2015)CrossRef
11.
Zhu, C., Guo, S., Fang, Y., Han, L., Wang, E., Dong, S.: One-step electrochemical approach to the synthesis of graphene/MnO2 nanowall hybrids. Nano Res. 4(7), 648–657 (2011)CrossRef
12.
Zhu, C., Zhai, J., Wen, D., Dong, S.: Graphene oxide/polypyrrole nanocomposites: one-step electrochemical doping, coating and synergistic effect for energy storage. J. Mater. Chem. 22(13), 6300–6306 (2012)CrossRef
13.
Paek, S.M., Yoo, E., Honma, I.: Enhanced cyclic performance and lithium storage capacity of SnO2/graphene nanoporous electrodes with three-dimensionally delaminated flexible structure. Nano Lett. 9(1), 72–75 (2008)CrossRef
14.
Huang, X., Yin, Z., Wu, S., Qi, X., He, Q., Zhang, Q., Zhang, H.: Graphene-based materials: synthesis, characterization, properties, and applications. Small 7(14), 1876–1902 (2011)CrossRef
15.
Porada, S., Weingarth, D., Hamelers, H.V.M., Bryjak, M., Presser, V., Biesheuvel, P.M.: Carbon flow electrodes for continuous operation of capacitive deionization and capacitive mixing energy generation. J. Mater. Chem. A 2, 9313–9321 (2014)CrossRef
16.
Porada, S., Zhao, R., van der Wal, A., Presser, V., Biesheuvel, P.M.: Review on the science and technology of water desalination by capacitive deionization. Prog. Mater. Sci. 58, 1388–1442 (2013)CrossRef
17.
Singh, K., Arora, S.: Removal of synthetic textile dyes from wastewaters: a critical review on present treatment technologies. Crit. Rev. Environ. Sci. Technol. 41, 807–878 (2011)CrossRef
18.
Resch-Genger, U., Grabolle, M., Cavaliere-Jaricot, S., Nitschke, R., Nann, T.: Quantum dots versus organic dyes as fluorescent labels. Nat. Methods 5, 763–775 (2008)CrossRef
19.
Peng, C., et al.: Carbon nanotube and conducting polymer composites for supercapacitors. Nat. Sci. 18, 777–788 (2008)
20.
Burke, A.: Ultra capacitors: why, how, and where is the technology. J. Power Sources 9(1), 37–50 (2000)CrossRef
21.
Li, X., Cai, W., An, J., Kim, S., Nah, J., Yang, D., Banerjee, S.K.: Large-area synthesis of high-quality and uniform graphene films on copper foils. Science 324(5932), 1312–1314 (2009)CrossRef
22.
Capasso, A., Dikonimos, T., Sarto, F., Tamburrano, A., De Bellis, G., Sarto, M.S., Lisi, N.: Nitrogen-doped graphene films from chemical vapor deposition of pyridine: influence of process parameters on the electrical and optical properties. Beilstein J. Nanotechnol. 6, 2028 (2015)CrossRef
23.
Subrahmanyam, K.S., Panchakarla, L.S., Govindaraj, A., Rao, C.N.R.: A simple method of preparing graphene flakes by an arc-discharge method. J. Phys. Chem. C 113(11), 4257–4259 (2009)CrossRef
24.
Sutter, P.W., Flege, J.I., Sutter, E.A.: Epitaxial graphene on ruthenium. Nat. Mater. 7(5), 406 (2008)CrossRef
25.
Hummers Jr., W.S., Offeman, R.E.: Preparation of graphitic oxide. J. Am. Chem. Soc. 80(6), 1339 (1958)CrossRef
26.
Pei, S., Cheng, H.M.: The reduction of graphene oxide. Carbon 50(9), 3210–3228 (2012)CrossRef
27.
McAllister, M.J., Li, J.L., Adamson, D.H., Schniepp, H.C., Abdala, A.A., Liu, J., Aksay, I.A.: Single sheet functionalized graphene by oxidation and thermal expansion of graphite. Chem. Mater. 19(18), 4396–4404 (2007)CrossRef
28.
Sun, X., Luo, D., Liu, J., Evans, D.G.: Monodisperse chemically modified graphene obtained by density gradient ultracentrifugal rate separation. ACS Nano 4(6), 3381–3389 (2010)CrossRef
29.
An, C., Wang, Y., Wang, Y., Liu, G., Li, L., Qiu, F., Yuan, H.: Facile synthesis and superior supercapacitor performances of Ni2P/rGO nanoparticles. RSC Adv. 3(14), 4628–4633 (2013)CrossRef
30.
Xu, Y., Sheng, K., Li, C., Shi, G.: Highly conductive chemically converted graphene prepared from mildly oxidized graphene oxide. J. Mater. Chem. 21(20), 7376–7380 (2011)CrossRef
31.
Bera, R., Kundu, S., Patra, A.: 2D hybrid nanostructure of reduced graphene oxide–CdS nanosheet for enhanced photocatalysis. ACS Appl. Mater. Interfaces 7(24), 13251–13259 (2015)CrossRef
32.
Gilje, S., Han, S., Wang, M., Wang, K.L., Kaner, R.B.: A chemical route to graphene for device applications. Nano Lett. 7(11), 3394–3398 (2007)CrossRef
33.
Stankovich, S., Piner, R.D., Chen, X., Wu, N., Nguyen, S.T., Ruoff, R.S.: Stable aqueous dispersions of graphitic nanoplatelets via the reduction of exfoliated graphite oxide in the presence of poly (sodium 4-styrenesulfonate). J. Mater. Chem. 16(2), 155–158 (2006)CrossRef
34.
Stankovich, S., Dikin, D.A., Dommett, G.H., Kohlhaas, K.M., Zimney, E.J., Stach, E.A., Ruoff, R.S.: Graphene-based composite materials. Nature 442(7100), 282 (2006)CrossRef
35.
Shin, H.J., Kim, K.K., Benayad, A., Yoon, S.M., Park, H.K., Jung, I.S., Lee, Y.H.: Efficient reduction of graphite oxide by sodium borohydride and its effect on electrical conductance. Adv. Funct. Mater. 19(12), 1987–1992 (2009)CrossRef
36.
Wang, G., Yang, J., Park, J., Gou, X., Wang, B., Liu, H., Yao, J.: Facile synthesis and characterization of graphene nanosheets. J. Phys. Chem. C 112(22), 8192–8195 (2008)CrossRef
37.
Novoselov, K.S., Fal, V.I., Colombo, L., Gellert, P.R., Schwab, M.G., Kim, K.: A roadmap for graphene. Nature 490(7419), 192 (2012)CrossRef
38.
Reina, A., Jia, X., Ho, J., Nezich, D., Son, H., Bulovic, V., Kong, J.: Large area, few-layer graphene films on arbitrary substrates by chemical vapor deposition. Nano Lett. 9(1), 30–35 (2008)CrossRef
39.
Jiao, L., Zhang, L., Wang, X., Diankov, G., Dai, H.: Narrow graphene nanoribbons from carbon nanotubes. Nature 458(7240), 877 (2009)CrossRef
40.
Yin, P.T., Shah, S., Chhowalla, M., Lee, K.B.: Design, synthesis, and characterization of graphene–nanoparticle hybrid materials for bioapplications. Chem. Rev. 115(7), 2483–2531 (2015)CrossRef
41.
Wu, Z.S., Ren, W., Gao, L., Liu, B., Jiang, C., Cheng, H.M.: Synthesis of high-quality graphene with a pre-determined number of layers. Carbon 47(2), 493–499 (2009)CrossRef
42.
Fan, X., Peng, W., Li, Y., Li, X., Wang, S., Zhang, G., Zhang, F.: Deoxygenation of exfoliated graphite oxide under alkaline conditions: a green route to graphene preparation. Adv. Mater. 20(23), 4490–4493 (2008)CrossRef
43.
Boehm, H.P., Clauss, A., Fischer, G.O., Hofmann, U.: Das adsorptionsverhalten sehr dünner kohlenstoff-folien. Z. Anorg. Allg. Chem. 316(3–4), 119–127 (1962)CrossRef
44.
Fernández-Merino, M.J., Guardia, L., Paredes, J.I., Villar-Rodil, S., Solís-Fernández, P., Martínez-Alonso, A., Tascon, J.M.D.: Vitamin C is an ideal substitute for hydrazine in the reduction of graphene oxide suspensions. J. Phys. Chem. C 114(14), 6426–6432 (2010)CrossRef
45.
Han, H.J., Chen, Y.N., Wang, Z.J.: Effect of microwave irradiation on reduction of graphene oxide films. RSC Adv. 5(113), 92940–92946 (2015)CrossRef
46.
Zhu, Y., Murali, S., Stoller, M.D., Velamakanni, A., Piner, R.D., Ruoff, R.S.: Microwave assisted exfoliation and reduction of graphite oxide for ultracapacitors. Carbon 48(7), 2118–2122 (2010)CrossRef
47.
Zhou, M., Wang, Y., Zhai, Y., Zhai, J., Ren, W., Wang, F., Dong, S.: Controlled synthesis of large-area and patterned electrochemically reduced graphene oxide films. Chem. Eur. J. 15(25), 6116–6120 (2009)CrossRef
48.
Ramesha, G.K., Sampath, S.: Electrochemical reduction of oriented graphene oxide films: an in situ Raman spectroelectrochemical study. J. Phys. Chem. C 113(19), 7985–7989 (2009)CrossRef
49.
Kudin, K.N., Ozbas, B., Schniepp, H.C., Prud’Homme, R.K., Aksay, I.A., Car, R.: Raman spectra of graphite oxide and functionalized graphene sheets. Nano Lett. 8(1), 36–41 (2008)CrossRef
50.
Becerril, H.A., Mao, J., Liu, Z., Stoltenberg, R.M., Bao, Z., Chen, Y.: Evaluation of solution-processed reduced graphene oxide films as transparent conductors. ACS Nano 2(3), 463–470 (2008)CrossRef
51.
Wang, H., Casalongue, H.S., Liang, Y., Dai, H.: Ni(OH)2 nanoplates grown on graphene as advanced electrochemical pseudocapacitor materials. J. Am. Chem. Soc. 132(21), 7472–7477 (2010)CrossRef
52.
Yuan, B., Bao, C., Qian, X., Wen, P., Xing, W., Song, L., Hu, Y.: A facile approach to prepare graphene via solvothermal reduction of graphite oxide. Mater. Res. Bull. 55, 48–52 (2014)CrossRef
53.
Gao, X., Jang, J., Nagase, S.: Hydrazine and thermal reduction of graphene oxide: reaction mechanisms, product structures, and reaction design. J. Phys. Chem. C 114(2), 832–842 (2009)CrossRef
54.
Pei, S., Zhao, J., Du, J., Ren, W., Cheng, H.M.: Direct reduction of graphene oxide films into highly conductive and flexible graphene films by hydrohalic acids. Carbon 48(15), 4466–4474 (2010)CrossRef
55.
Wei, Z., Chen, Y., Wang, J., Su, D., Tang, M., Mao, S., Wang, Y.: Cobalt encapsulated in N-doped graphene layers: an efficient and stable catalyst for hydrogenation of quinoline compounds. ACS Catal. 6(9), 5816–5822 (2016)CrossRef
56.
Lee, J.S., You, K.H., Park, C.B.: Highly photoactive, low bandgap TiO2 nanoparticles wrapped by graphene. Adv. Mater. 24(8), 1084–1088 (2012)CrossRef
57.
Zhang, Y., Li, D., Zhang, Y., Zhou, X., Guo, S., Yang, L.: Graphene-wrapped Bi2O2CO3 core–shell structures with enhanced quantum efficiency profit from an ultrafast electron transfer process. J. Mater. Chem. A 2(22), 8273–8280 (2014)CrossRef
58.
Myung, S., Solanki, A., Kim, C., Park, J., Kim, K.S., Lee, K.B.: Graphene-encapsulated nanoparticle-based biosensor for the selective detection of cancer biomarkers. Adv. Mater. 23(19), 2221–2225 (2011)CrossRef
59.
Wu, Z.S., Wang, D.W., Ren, W., Zhao, J., Zhou, G., Li, F., Cheng, H.M.: Anchoring hydrous RuO2 on graphene sheets for high-performance electrochemical capacitors. Adv. Funct. Mater. 20(20), 3595–3602 (2010)CrossRef
60.
Lv, W., Sun, F., Tang, D.M., Fang, H.T., Liu, C., Yang, Q.H., Cheng, H.M.: A sandwich structure of graphene and nickel oxide with excellent supercapacitive performance. J. Mater. Chem. 21(25), 9014–9019 (2011)CrossRef
61.
Dutta, A., Ouyang, J.: Ternary NiAuPt nanoparticles on reduced graphene oxide as catalysts toward the electrochemical oxidation reaction of ethanol. ACS Catal. 5(2), 1371–1380 (2015)CrossRef
62.
Li, J., Tang, W., Liu, G., Li, W., Deng, Y., Yang, J., Chen, Y.: Reduced graphene oxide modified platinum catalysts for the oxidation of volatile organic compounds. Catal. Today 278, 203–208 (2016)CrossRef
63.
Zhou, Y., Hu, X.C., Fan, Q., Wen, H.R.: Three-dimensional crumpled graphene as an electro-catalyst support for formic acid electro-oxidation. J. Mater. Chem. A 4(12), 4587–4591 (2016)CrossRef
64.
Eigler, S., Hirsch, A.: Chemistry with graphene and graphene oxide—challenges for synthetic chemists. Angew. Chem. Int. Ed. 53(30), 7720–7738 (2014)CrossRef
65.
Fan, X., Zhang, G., Zhang, F.: Multiple roles of graphene in heterogeneous catalysis. Chem. Soc. Rev. 44(10), 3023–3035 (2015)CrossRef
66.
Julkapli, N.M., Bagheri, S.: Graphene-supported heterogeneous catalysts: an overview. Int. J. Hydrogen Energy 40(2), 948–979 (2015)CrossRef
67.
Wang, J., Kondrat, S.A., Wang, Y., Brett, G.L., Giles, C., Bartley, J.K., Hutchings, G.J.: Au–Pd nanoparticles dispersed on composite titania/graphene oxide-supports as a highly active oxidation catalyst. ACS Catal. 5(6), 3575–3587 (2015)CrossRef
68.
Sun, Y., Du, C., An, M., Du, L., Tan, Q., Liu, C., Yin, G.: Boron-doped graphene as promising support for a platinum catalyst with superior activity towards the methanol electrooxidation reaction. J. Power Sources 300, 245–253 (2015)CrossRef
69.
Wang, C., Astruc, D.: Recent developments of metallic nanoparticle-graphene nanocatalysts. Prog. Mater. Sci. (2018)
70.
Li, D., Xu, H., Zhang, L., Leung, D.Y., Vilela, F., Wang, H., Xuan, J.: Boosting the performance of formic acid microfluidic fuel cell: oxygen annealing enhanced Pd@ graphene electrocatalyst. Int. J. Hydrogen Energy 41(24), 10249–10254 (2016)CrossRef
71.
Zhang, L.Y., Zhao, Z.L., Yuan, W., Li, C.M.: Facile one-pot surfactant-free synthesis of uniform Pd6Co nanocrystals on 3D graphene as an efficient electrocatalyst toward formic acid oxidation. Nanoscale 8(4), 1905–1909 (2016)CrossRef
72.
Zhang, X., Zhu, J., Tiwary, C.S., Ma, Z., Huang, H., Zhang, J., Wu, Y.: Palladium nanoparticles supported on nitrogen and sulfur dual-doped graphene as highly active electrocatalysts for formic acid and methanol oxidation. ACS Appl. Mater. Interfaces 8(17), 10858–10865 (2016)CrossRef
73.
Zhang, L.Y., Zhao, Z.L., Li, C.M.: Formic acid-reduced ultrasmall Pd nanocrystals on graphene to provide superior electrocatalytic activity and stability toward formic acid oxidation. Nano Energy 11, 71–77 (2015)CrossRef
74.
Kim, J., Park, J.E., Momma, T., Osaka, T.: Synthesis of Pd–Sn nanoparticles by ultrasonic irradiation and their electrocatalytic activity for oxygen reduction. Electrochim. Acta 54(12), 3412–3418 (2009)CrossRef
75.
Karuppasamy, L., Chen, C.Y., Anandan, S., Wu, J.J.: Sonochemical fabrication of reduced graphene oxide supported Au nano dendrites for ethanol electrooxidation in alkaline medium. Catal. Today 307, 308–317 (2018)CrossRef
76.
Zhang, B., Zhang, C., He, H., Yu, Y., Wang, L., Zhang, J.: Electrochemical synthesis of catalytically active Ru/RuO2 core–shell nanoparticles without stabilizer. Chem. Mater. 22(13), 4056–4061 (2010)CrossRef
77.
Rao, C.R., Trivedi, D.C.: Chemical and electrochemical depositions of platinum group metals and their applications. Coord. Chem. Rev. 249(5–6), 613–631 (2005)CrossRef
78.
Shahrokhian, S., Rezaee, S.: Vertically standing Cu2O nanosheets promoted flower-like PtPd nanostructures supported on reduced graphene oxide for methanol electro-oxidation. Electrochim. Acta 259, 36–47 (2018)CrossRef
79.
Liu, J., Ma, Q., Huang, Z., Liu, G., Zhang, H.: Recent progress in graphene-based noble-metal nanocomposites for electrocatalytic applications. Adv. Mater. 1800696 (2018)
80.
Liu, M., Zhang, R., Chen, W.: Graphene-supported nanoelectrocatalysts for fuel cells: synthesis, properties, and applications. Chem. Rev. 114(10), 5117–5160 (2014)CrossRef
81.
Li, Q., Mahmood, N., Zhu, J., Hou, Y., Sun, S.: Graphene and its composites with nanoparticles for electrochemical energy applications. Nano Today 9(5), 668–683 (2014)CrossRef
82.
Xia, B., Yan, Y., Wang, X., Lou, X.W.D.: Recent progress on graphene-based hybrid electrocatalysts. Mater. Horizons 1(4), 379–399 (2014)CrossRef
83.
Ambrosi, A., Chua, C.K., Latiff, N.M., Loo, A.H., Wong, C.H.A., Eng, A.Y.S., Pumera, M.: Graphene and its electrochemistry—an update. Chem. Soc. Rev. 45(9), 2458–2493 (2016)CrossRef
84.
Su, D.S., Perathoner, S., Centi, G.: Nanocarbons for the development of advanced catalysts. Chem. Rev. 113(8), 5782–5816 (2013)CrossRef
85.
Kumar, A., Xu, Q.: Two-dimensional layered materials as catalyst supports. ChemNanoMat 4(1), 28–40 (2018)CrossRef
86.
Sun, S.H., Yang, D.Q., Villers, D., Zhang, G.X., Sacher, E., Dodelet, J.P.: Template- and surfactant-free room temperature synthesis of self-assembled 3D Pt nanoflowers from single-crystal nanowires. Adv. Mater. 20(3), 571–574 (2008)CrossRef
87.
Wang, M., Wang, X., Li, J., Liu, L.: In situ synthesis of 3D platinum nanoflowers on porous silicon for monolithic integrated micro direct methanol fuel cells. J. Mater. Chem. A 1(28), 8127–8133 (2013)CrossRef
88.
Yin, A.X., Min, X.Q., Zhang, Y.W., Yan, C.H.: Shape-selective synthesis and facet-dependent enhanced electrocatalytic activity and durability of monodisperse sub-10 nm Pt–Pd tetrahedrons and cubes. J. Am. Chem. Soc. 133(11), 3816–3819 (2011)CrossRef
89.
Lu, Y., Jiang, Y., Wu, H., Chen, W.: Nano-PtPd cubes on graphene exhibit enhanced activity and durability in methanol electrooxidation after CO stripping–cleaning. J. Phys. Chem. C 117(6), 2926–2938 (2013)CrossRef
90.
Li, S.S., Zheng, J.N., Ma, X., Hu, Y.Y., Wang, A.J., Chen, J.R., Feng, J.J.: Facile synthesis of hierarchical dendritic PtPd nanogarlands supported on reduced graphene oxide with enhanced electrocatalytic properties. Nanoscale 6(11), 5708–5713 (2014)CrossRef
91.
Du, S., Lu, Y., Steinberger-Wilckens, R.: PtPd nanowire arrays supported on reduced graphene oxide as advanced electrocatalysts for methanol oxidation. Carbon 79, 346–353 (2014)CrossRef
92.
Chen, Z., Waje, M., Li, W., Yan, Y.: Supportless Pt and PtPd nanotubes as electrocatalysts for oxygen-reduction reactions. Angew. Chem. 119(22), 4138–4141 (2007)CrossRef
93.
Lu, Y., Jiang, Y., Chen, W.: PtPd porous nanorods with enhanced electrocatalytic activity and durability for oxygen reduction reaction. Nano Energy 2(5), 836–844 (2013)CrossRef
94.
Lv, J.J., Wisitruangsakul, N., Feng, J.J., Luo, J., Fang, K.M., Wang, A.J.: Biomolecule-assisted synthesis of porous PtPd alloyed nanoflowers supported on reduced graphene oxide with highly electrocatalytic performance for ethanol oxidation and oxygen reduction. Electrochim. Acta 160, 100–107 (2015)CrossRef
95.
Xu, C., Tian, Z., Shen, P., Jiang, S.P.: Oxide (CeO2, NiO, Co3O4 and Mn3O4)-promoted Pd/C electrocatalysts for alcohol electrooxidation in alkaline media. Electrochim. Acta 53(5), 2610–2618 (2008)CrossRef
96.
Rostami, H., Rostami, A.A., Omrani, A.: An electrochemical method to prepare of Pd/Cu2O/MWCNT nanostructure as an anode electrocatalyst for alkaline direct ethanol fuel cells. Electrochim. Acta 194, 431–440 (2016)CrossRef
97.
Liu, P., Cheng, Z., Ma, L., Zhang, M., Qiu, Y., Chen, M., Cheng, F.: Cuprous oxide template synthesis of hollow-cubic Cu2O@PdxRuy nanoparticles for ethanol electrooxidation in alkaline media. RSC Adv. 6(80), 76684–76690 (2016)CrossRef
98.
Zhang, N., Fan, Y., Fan, H., Shao, H., Wang, J., Zhang, J., Cao, C.: Cross-linked Co3O4 nanowalls synthesized by electrochemical oxidation of metallic cobalt layer for oxygen evolution. ECS Electrochem. Lett. 1(2), H8–H10 (2012)CrossRef
99.
Ye, L., Li, Z., Zhang, X., Lei, F., Lin, S.: One-step microwave synthesis of Pt (Pd)/Cu2O/GNs composites and their electro-photo-synergistic catalytic properties for methanol oxidation. J. Mater. Chem. A 2(48), 21010–21019 (2014)CrossRef
100.
Zhao, Y., Zhan, L., Tian, J., Nie, S., Ning, Z.: MnO2 modified multi-walled carbon nanotubes supported Pd nanoparticles for methanol electro-oxidation in alkaline media. Int. J. Hydrogen Energy 35(19), 10522–10526 (2010)CrossRef
101.
Zheng, J.N., Li, S.S., Ma, X., Chen, F.Y., Wang, A.J., Chen, J.R., Feng, J.J.: Green synthesis of core–shell gold–palladium@ palladium nanocrystals dispersed on graphene with enhanced catalytic activity toward oxygen reduction and methanol oxidation in alkaline media. J. Power Sources 262, 270–278 (2014)CrossRef
102.
Wang, S., Iyyamperumal, E., Roy, A., Xue, Y., Yu, D., Dai, L.: Vertically aligned BCN nanotubes as efficient metal-free electrocatalysts for the oxygen reduction reaction: a synergetic effect by Co-doping with boron and nitrogen. Angew. Chem. 123(49), 11960–11964 (2011)CrossRef
103.
Lv, J.J., Li, S.S., Zheng, J.N., Wang, A.J., Chen, J.R., Feng, J.J.: Facile synthesis of reduced graphene oxide supported PtAg nanoflowers and their enhanced electrocatalytic activity. Int. J. Hydrogen Energy 39(7), 3211–3218 (2014)CrossRef
104.
Ye, W., Chen, Y., Zhou, F., Wang, C., Li, Y.: Fluoride-assisted galvanic replacement synthesis of Ag and Au dendrites on aluminum foil with enhanced SERS and catalytic activities. J. Mater. Chem. 22(35), 18327–18334 (2012)CrossRef
105.
Huang, D., Bai, X., Zheng, L.: Ultrafast preparation of three-dimensional dendritic gold nanostructures in aqueous solution and their applications in catalysis and SERS. J. Phys. Chem. C 115(30), 14641–14647 (2011)CrossRef
106.
Guo, Y., Sun, X., Liu, Y., Wang, W., Qiu, H., Gao, J.: One pot preparation of reduced graphene oxide (RGO) or Au (Ag) nanoparticle-RGO hybrids using chitosan as a reducing and stabilizing agent and their use in methanol electrooxidation. Carbon 50(7), 2513–2523 (2012)CrossRef
107.
Rodriguez, P., Kwon, Y., Koper, M.T.: The promoting effect of adsorbed carbon monoxide on the oxidation of alcohols on a gold catalyst. Nat. Chem. 4(3), 177 (2012)CrossRef
108.
Tateishi, N., Nishimura, K., Yahikozawa, K., Nakagawa, M., Yamada, M., Takasu, Y.: Electrocatalytic properties of ultrafine gold particles towards oxidation of acetaldehyde and ethanol. J. Electroanal. Chem. 352(1–2), 243–252 (1993)CrossRef
109.
Xu, C., Cheng, L., Shen, P., Liu, Y.: Methanol and ethanol electrooxidation on Pt and Pd supported on carbon microspheres in alkaline media. Electrochem. Commun. 9(5), 997–1001 (2007)CrossRef
110.
Choi, C.H., Kim, M., Kwon, H.C., Cho, S.J., Yun, S., Kim, H.T., Choi, M.: Tuning selectivity of electrochemical reactions by atomically dispersed platinum catalyst. Nat. Commun. 7, 10922 (2016)CrossRef
111.
Wang, H., Yang, Y., Liang, Y., Zheng, G., Li, Y., Cui, Y., Dai, H.: Rechargeable Li–O2 batteries with a covalently coupled MnCo2O4–graphene hybrid as an oxygen cathode catalyst. Energy Environ. Sci. 5(7), 7931–7935 (2012)CrossRef
112.
Xuan, L., Chen, L., Yang, Q., Chen, W., Hou, X., Jiang, Y., et al.: Engineering 2D multi-layer graphene-like Co3O4 thin sheets with vertically aligned nanosheets as basic building units for advanced pseudo capacitor materials. J. Mater. Chem. A. 3, 17525–17533 (2015)CrossRef
113.
Moosavifard, S.E., Shamsi, J., Fani, S., Kadkhodazade, S.: 3D ordered nanoporous NiMoO4 for high-performance supercapacitor electrode materials. RSC Adv. 4, 52555–52561 (2014)CrossRef
114.
Lu, X., Yu, M., Wang, G., Tong, Y., Li, Y.: Flexible solid-state supercapacitors: design, fabrication and applications. Energy Environ. Sci. 7, 2160–2181 (2014)CrossRef
115.
Chen, T., Dai, L.: Carbon nanomaterials for high-performance supercapacitors. Mater. Today 16, 272–280 (2013)CrossRef
116.
Guo, D., Luo, Y., Yu, X., Li, Q., Wang, T.: High performance NiMoO4 nanowires supported on carbon cloth as advanced electrodes for symmetric supercapacitors. Nano Energy 8, 174–182 (2014)CrossRef
117.
Hall, P.J., Mirzaeian, M., Fletcher, S.I., Sillars, F.B., Rennie, A.J., Shitta-Bey, G.O., Wilson, G., Cruden, A., Carter, R.: Energy storage in electrochemical capacitors: designing functional materials to improve performance. Energy Environ. Sci. 3, 1238–1251 (2010)CrossRef
118.
Miller, J.R., Burke, A.F.: Electrochemical capacitors: challenges and opportunities for real-world applications. Electrochem. Soc. Interface 4(Spring), 53–57 (2008)
119.
Conway, B.E.: Electrochemical Supercapacitors: Scientific Fundamentals and Technological Applications, 2nd edn. Kluwer Academic/Plenum Publishers, New York (1999)CrossRef
120.
Trasatti, S., Kurzweil, P.: Electrochemical supercapacitors as versatile energy stores. Platinum Met. Rev. 38, 46–56 (1994)
121.
Zhong, C., Deng, Y., Hu, W., Qiao, J., Zhang, L., Zhang, J.: A review of electrolyte materials and compositions for electrochemical supercapacitors. Chem. Soc. Rev. 44, 7484–7539 (2015)CrossRef
122.
Carter, R., Cruden, A.: Strategies for control of a battery/supercapacitor system in an electric vehicle. In: 2008 International Symposium on Power Electronics, Electrical Drives, Automation and Motion, vol. 1–3, pp. 727–732. IEEE (2008)
123.
Gao, Q., Demarconnay, L., Raymundo-Pinero, E., Beguin, F.: Exploring the large voltage range of carbon/carbon supercapacitors in aqueous lithium sulfate electrolyte. Energy Environ. Sci. 5, 9611–9617 (2012)CrossRef
124.
Fic, K., Lota, G., Meller, M., Frackowiak, E.: Novel insight into neutral medium as electrolyte for high-voltage supercapacitors. Energy Environ. Sci. 5, 5842–5850 (2012)CrossRef
125.
Zhang, Q., Rong, J., Ma, D., Wei, B.: The governing self-discharge processes in activated carbon fabric-based supercapacitors with different organic electrolytes. Energy Environ. Sci. 4, 2152–2159 (2011)CrossRef
126.
Wan, L., Sun, S., Zhai, T., Savilov, S.V., Lunin, V.V., Xia, H.: Multiscale porous graphene oxide network with high packing density for asymmetric supercapacitors. J. Mater. Res. 1–12 (2017)
127.
Yang, J., Hu, J., Zhu, M., Zhao, Y., Chen, H., Pan, F.: Ultrahigh surface area meso/microporous carbon formed with self-template for high-voltage aqueous supercapacitors. J. Power Sources 365, 362–371 (2017)CrossRef
128.
Jana, A., Scheer, E., Polarz, S.: Synthesis of graphene–transition metal oxide hybrid nanoparticles and their application in various fields. Beilstein J. Nanotechnol. 8, 688–714 (2017)CrossRef
129.
Fan, H., Niu, R., Duan, J., Liu, W., Shen, W.: Fe3O4@carbon nanosheets for all-solid-state supercapacitor electrodes. ACS Appl. Mater. Interfaces 8, 19475–19483 (2016)CrossRef
130.
Wu, Z.-S., Zhou, G., Yin, L.-C., Ren, W., Li, F., Cheng, H.-M.: Graphene/metal oxide composite electrode materials for energy storage. Nano Energy 1, 107–131 (2012)CrossRef
131.
Frackowiak, E.: Carbon materials for supercapacitor application. Phys. Chem. Chem. Phys. 9, 1774–1785 (2007)CrossRef
132.
Hu, C.-C., Chang, K.-H., Lin, M.-C., Wu, Y.-T.: Design and tailoring of the nanotubular arrayed architecture of hydrous RuO2 for next generation supercapacitors. Nano Lett. 6, 2690–2695 (2006)CrossRef
133.
Cheng, Q., Tang, J., Ma, J., Zhang, H., Shinya, N., Qin, L.-C.: Graphene and nanostructured MnO2 composite electrodes for supercapacitors. Carbon N. Y. 49, 2917–2925 (2011)CrossRef
134.
Deng, W., Ji, X., Chen, Q., Banks, C.E.: Electrochemical capacitors utilising transition metal oxides: an update of recent developments. RSC Adv. 1, 1171–1178 (2011)CrossRef
135.
Shanshan, L., Yansu, W., Zhiling, M.: Bi2O3 with reduced graphene oxide composite as a supercapacitor electrode. Int. J. Electrochem. Sci. 13, 12256–12265 (2018)
136.
Jinfeng, S., Zhangpeng, L., Jinqing, W., Wei, H., Peiwei, G., Ping, W., Zhaofeng, W., Shengrong, Y.: Ni/Bi battery based on Ni(OH)2 nanoparticles/graphene sheets and Bi2O3 rods/graphene sheets with high performance. J. Alloy. Compd. 643, 231–238 (2015)CrossRef
137.
Huan-Wen, W., Zhong-Ai, H., Yan-Qin, C., Yan-Li, C., Zi-Qiang, L., Zi-Yu, Z., Yu-Ying, Y.: Facile solvothermal synthesis of a graphene nanosheet–bismuth oxide composite and its electrochemical characteristics. Electrochim. Acta 55, 8974–8980 (2010)CrossRef
138.
Ezhil, V.A.T., Bose, D., Muruganantham, R., Seung-Kyu, H., Chang-Soo, J., Yun Suk, H., Young-Kyu, H.: Hexagonal Co3O4 anchored reduced graphene oxide sheets for high-performance supercapacitors and non-enzymatic glucose sensing. J. Mater. Chem. A 6, 14367 (2018)
139.
Rajesh, K., Hyun-Jun, K., Park, S., Anchal, S., Il-Kwon, O.: Graphene-wrapped and cobalt oxide-intercalated hybrid for extremely durable super-capacitor with ultrahigh energy and power densities. Carbon 79, 192–202 (2014)CrossRef
140.
Arshid, N., Navaneethan, D., Fatin, S., Mahipal, Y.K., Ramesh, K., Ramesh, S.: Enhanced electrochemical performance of cobalt oxide nanocube intercalated reduced graphene oxide for supercapacitor application. RSC Adv. 6, 34894 (2016)CrossRef
141.
Chengen, H., Yachao, L., Pengyuan, G., Long, C., Dean, S., Xiaolin, X., Robert, K., Yiu, L., Yingkui, Y.: Bioinspired Co3O4/graphene layered composite films as self-supported electrodes for supercapacitors. Compos. B 121, 68–74 (2017)CrossRef
142.
Jintao, Z., Jianwen, J., Zhao, X.S.: Synthesis and capacitive properties of manganese oxide nanosheets dispersed on functionalized graphene sheets. J. Phys. Chem. C 115, 6448–6454 (2011)CrossRef
143.
Jiayi, Z., Junhui, Y.: Facile synthesis of graphene-wrapped honeycomb MnO2 nanospheres and their application in supercapacitors. ACS Appl. Mater. Interfaces 4, 1770–1776 (2012)CrossRef
144.
Jian, C., Meihua, J., Fei, Y., Tae Hyung, K., Viet Thong, L., Hongyan, Y., Fethullah, G., Bing, L., Arunabha, G., Sishen, X., Young Hee, L.: Asymmetric supercapacitors based on graphene/MnO2 nanospheres and graphene/MoO3 nanosheets with high energy density. Adv. Funct. Mater. 23, 5074–5083 (2013)CrossRef
145.
Sheng, C., Junwu, Z., Xiaodong, W., Qiaofeng, H., Xin, W.: Graphene oxide-MnO2 nanocomposites for supercapacitors. ACS Nano 4, 2822–2830 (2010)CrossRef
146.
Xiehong, C., Bing, Z., Wenhui, S., Jian, Y., Zhanxi, F., Zhimin, L., Xianhong, R., Chen, B., Qingyu, Y., Hua, Z.: Reduced graphene oxide-wrapped MoO3 composites prepared by using metal–organic frameworks as precursor for all-solid-state flexible supercapacitors. Adv. Mater. 27, 4695–4701 (2015)CrossRef
147.
Alok, P., Abhijeet Sadashiv, G., Satyajit, R., Brahmananda, C., Chandra Sekhar, R.: Enhanced pseudocapacitance of MoO3-reduced graphene oxide hybrids with insight from density functional theory investigations. J. Phys. Chem. C 12, 18992–19001 (2017)
148.
Wujun, M., Shaohua, C., Shengyuan, Y., Wenping, C., Wei, W., Yanhua, C., Meifang, Z.: Flexible all-solid-state asymmetric supercapacitor based on transition metal oxide nanorods/reduced graphene oxide hybrid fibers with high energy density. Carbon 113, 151–158 (2017)CrossRef
149.
Kai, Z., Weijia, Z., Xiaojun, L., Yuanhua, S., Shaozheng, J., Wei, L., Jia, L., Ligui, L., Wenhan, N., Hong, L., Shaowei, C.: Ultrathin MoO3 nanocrystals self-assembled on graphene nanosheets via oxygen bonding as supercapacitor electrodes of high capacitance and long cycle life. Nano Energy 12, 510–520 (2015)CrossRef
Metadaten
Titel
Synthesis of Metal/Metal Oxide Supported Reduced Graphene Oxide (RGO) for the Applications of Electrocatalysis and Supercapacitors
verfasst von
Lakshmanan Karuppasamy
Lakshmanan Gurusamy
Gang-Juan Lee
Jerry J. Wu
Copyright-Jahr
2019
Verlag
Springer Singapore
Buch
Graphene Functionalization Strategies

Print ISBN: 978-981-329-056-3

Electronic ISBN: 978-981-329-057-0

Copyright-Jahr: 2019

DOI
https://doi.org/10.1007/978-981-32-9057-0_1

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