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Journal of Materials Science: Materials in Electronics
Erschienen in: Journal of Materials Science: Materials in Electronics 8/2014

01.08.2014

Synthesis of novel D–Pi–A chromophore with two reactive groups in the middle section

verfasst von: Li Guo, Zupeng Guo, Haiying Chen

Erschienen in: Journal of Materials Science: Materials in Electronics | Ausgabe 8/2014

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Abstract

D–Pi–A chromophore with strong electron donor and isolated groups on both sides was synthesized and characterized by mass spectrum and hydrogen nuclear magnetic resonance. Reactive groups, which could both improve the chromophore’s electro optic activity and make the chromophore be easily reacted with other monomers or polymers, were introduced to the middle section of the chromophore. Electro-optical (EO) polymers with different chromophore loading densities were prepared and all of them showed us good thermal stabilities, their thermal decomposition temperatures were all higher than 275 °C. Large EO coefficients were also gotten by second harmonic generation method, 58, 76 and 91 pm/V respectively for PU-C10, PU-C15 and PU-C20. Solvatochromism of polymer PU-C10 was studied; the result indicated us that this kind of polymers could be used as solvent polarity indicators.
Vorheriger Artikel Growth characteristics and device properties of MOD derived β-Ga2O3 films
Nächster Artikel Advanced research into the growth mechanism and optical properties of wurtzite ZnSe quantum dots

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Metadaten
Titel
Synthesis of novel D–Pi–A chromophore with two reactive groups in the middle section
verfasst von
Li Guo
Zupeng Guo
Haiying Chen
Publikationsdatum
01.08.2014
Verlag
Springer US
Erschienen in
Journal of Materials Science: Materials in Electronics / Ausgabe 8/2014
Print ISSN: 0957-4522
Elektronische ISSN: 1573-482X
DOI
https://doi.org/10.1007/s10854-014-2067-z

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