Skip to main content
Erschienen in: Journal of Materials Science 9/2019

22.01.2019 | Energy materials

Synthesis of porous polymer-based metal–organic frameworks monolithic hybrid composite for hydrogen storage application

verfasst von: Lerato Y. Molefe, Nicholas M. Musyoka, Jianwei Ren, Henrietta W. Langmi, Patrick G. Ndungu, Robert Dawson, Mkhulu Mathe

Erschienen in: Journal of Materials Science | Ausgabe 9/2019

Einloggen

Aktivieren Sie unsere intelligente Suche um passende Fachinhalte oder Patente zu finden.

search-config
loading …

Abstract

Herein, we report a simple method for the preparation of cross-linked polymer of intrinsic microporosity (PIM-1)/Materials Institute Lavoisier chromium (III) terephthalate [MIL-101(Cr)] monoliths which involves direct impregnation of PIM-1 with MIL-101(Cr) powder by physical mixing in tetrachloroethane solvent. This procedure yields monoliths with high metal–organic framework (MOF) loading weight percentages of up to 80 wt% of MIL-101 powder with little loss of composite mechanical strength. From the nitrogen adsorption isotherms, it was observed that the PIM-1/80 wt% MIL-101(Cr) had good retention of MOF filler surface area and accessibility of its micropores with nearly no pore blocking effects. The hydrogen adsorption was also not far from the estimated hydrogen uptake capacity based on the MIL-101 weight percentage estimation. As a consequence of the highly porous nature of the hybrid material, PIM-1/MIL-101(Cr) composite has been considered as a promising material for inclusion in hybrid hydrogen storage cylinders. Moreover, these composites provided better handling compared to the crystalline powder MOFs without compromising the properties of MOF.

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Literatur
1.
Zurück zum Zitat Schlapbach L, Züttel A (2011) Hydrogen-storage materials for mobile applications. Materials for sustainable energy: a collection of peer-reviewed research and review articles from Nature Publishing Group 265–270 Schlapbach L, Züttel A (2011) Hydrogen-storage materials for mobile applications. Materials for sustainable energy: a collection of peer-reviewed research and review articles from Nature Publishing Group 265–270
2.
Zurück zum Zitat Lim KL, Kazemian H, Yaakob Z, Daud WW (2010) Solid-state materials and methods for hydrogen storage: a critical review. Chem Eng Technol 33:213–226CrossRef Lim KL, Kazemian H, Yaakob Z, Daud WW (2010) Solid-state materials and methods for hydrogen storage: a critical review. Chem Eng Technol 33:213–226CrossRef
3.
Zurück zum Zitat Ren J, Langmi HW, North BC, Mathe M (2015) Review on processing of metal–organic framework (MOF) materials towards system integration for hydrogen storage. Int J Energy Res 39:607–620CrossRef Ren J, Langmi HW, North BC, Mathe M (2015) Review on processing of metal–organic framework (MOF) materials towards system integration for hydrogen storage. Int J Energy Res 39:607–620CrossRef
5.
Zurück zum Zitat Ren J, Musyoka NM, Langmi HW, Swartbooi A, North BC, Mathe M (2015) A more efficient way to shape metal–organic framework (MOF) powder materials for hydrogen storage applications. Int J Hydrogen Energy 40:4617–4622CrossRef Ren J, Musyoka NM, Langmi HW, Swartbooi A, North BC, Mathe M (2015) A more efficient way to shape metal–organic framework (MOF) powder materials for hydrogen storage applications. Int J Hydrogen Energy 40:4617–4622CrossRef
6.
Zurück zum Zitat Ren J, Dyosiba X, Musyoka NM, Langmi HW, Mathe M, Liao S (2017) Review on the current practices and efforts towards pilot-scale production of metal-organic frameworks (MOFs). Coord Chem Rev 352:187–219CrossRef Ren J, Dyosiba X, Musyoka NM, Langmi HW, Mathe M, Liao S (2017) Review on the current practices and efforts towards pilot-scale production of metal-organic frameworks (MOFs). Coord Chem Rev 352:187–219CrossRef
7.
Zurück zum Zitat Huo J, Marcello M, Garai A, Bradshaw D (2013) MOF-polymer composite microcapsules derived from pickering emulsions. Adv Mater 25:2717–2722CrossRef Huo J, Marcello M, Garai A, Bradshaw D (2013) MOF-polymer composite microcapsules derived from pickering emulsions. Adv Mater 25:2717–2722CrossRef
8.
Zurück zum Zitat Zornoza B, Tellez C, Coronas J, Gascon J, Kapteijn F (2013) Metal organic framework based mixed matrix membranes: an increasingly important field of research with a large application potential. Microporous Mesoporous Mater 166:67–78CrossRef Zornoza B, Tellez C, Coronas J, Gascon J, Kapteijn F (2013) Metal organic framework based mixed matrix membranes: an increasingly important field of research with a large application potential. Microporous Mesoporous Mater 166:67–78CrossRef
9.
Zurück zum Zitat Zhu QL, Xu Q (2014) Metal-organic framework composites. Chem Soc Rev 43:5468–5512CrossRef Zhu QL, Xu Q (2014) Metal-organic framework composites. Chem Soc Rev 43:5468–5512CrossRef
10.
Zurück zum Zitat Denny MS, Cohen SM (2015) In situ modification of metal-organic frameworks in mixed-matrix membranes. Angew Chem Int Ed 54:9029–9032CrossRef Denny MS, Cohen SM (2015) In situ modification of metal-organic frameworks in mixed-matrix membranes. Angew Chem Int Ed 54:9029–9032CrossRef
11.
Zurück zum Zitat Seoane B, Coronas J, Gascon I, Benavides ME, Karvan O, Caro J, Kapteijn F, Gascon J (2015) Metal–organic framework based mixed matrix membranes: a solution for highly efficient CO2 capture? Chem Soc Rev 44:2421–2454CrossRef Seoane B, Coronas J, Gascon I, Benavides ME, Karvan O, Caro J, Kapteijn F, Gascon J (2015) Metal–organic framework based mixed matrix membranes: a solution for highly efficient CO2 capture? Chem Soc Rev 44:2421–2454CrossRef
12.
Zurück zum Zitat Zhang ZJ, Nguyen HTH, Miller SA, Cohen SM (2015) PolyMOFs: a class of interconvertible polymer-metal–organic-framework hybrid materials. Angew Chem Int Ed 54:6152–6157CrossRef Zhang ZJ, Nguyen HTH, Miller SA, Cohen SM (2015) PolyMOFs: a class of interconvertible polymer-metal–organic-framework hybrid materials. Angew Chem Int Ed 54:6152–6157CrossRef
13.
Zurück zum Zitat Kubica P, Wolinska-Grabczyk A, Grabiec E, Libera M, Wojtyniak M, Czajkowska S, Domański M (2016) Gas transport through mixed matrix membranes composed of polysulfone and copper terephthalate particles. Microporous Mesoporous Mater 235:120–134CrossRef Kubica P, Wolinska-Grabczyk A, Grabiec E, Libera M, Wojtyniak M, Czajkowska S, Domański M (2016) Gas transport through mixed matrix membranes composed of polysulfone and copper terephthalate particles. Microporous Mesoporous Mater 235:120–134CrossRef
14.
Zurück zum Zitat DeCoste JB, Denny MS, Peterson GW, Mahle JJ, Cohen SM (2016) Enhanced aging properties of HKUST-1 in hydrophobic mixed-matrix membranes for ammonia adsorption. Chem Sci 7:2711–2716CrossRef DeCoste JB, Denny MS, Peterson GW, Mahle JJ, Cohen SM (2016) Enhanced aging properties of HKUST-1 in hydrophobic mixed-matrix membranes for ammonia adsorption. Chem Sci 7:2711–2716CrossRef
15.
Zurück zum Zitat Ling RJ, Ge L, Diao H, Rudolph V, Zhu ZH (2016) Ionic liquids as the MOFs/polymer interfacial binder for efficient membrane separation. ACS Appl Mater Interfaces 8:32041–32049CrossRef Ling RJ, Ge L, Diao H, Rudolph V, Zhu ZH (2016) Ionic liquids as the MOFs/polymer interfacial binder for efficient membrane separation. ACS Appl Mater Interfaces 8:32041–32049CrossRef
16.
Zurück zum Zitat Zhang ZJ, Nguyen HTH, Miller SA, Ploskonka AM, DeCoste JB, Cohen SM (2016) Polymer-metal–organic frameworks (polyMOFs) as water tolerant materials for selective carbon dioxide separations. J Am Chem Soc 138:920–925CrossRef Zhang ZJ, Nguyen HTH, Miller SA, Ploskonka AM, DeCoste JB, Cohen SM (2016) Polymer-metal–organic frameworks (polyMOFs) as water tolerant materials for selective carbon dioxide separations. J Am Chem Soc 138:920–925CrossRef
17.
Zurück zum Zitat Wickenheisser M, Herbst A, Tannert R, Milow B, Janiak C (2015) Hierarchical MOF-xerogel monolith composites from embedding MIL-100 (Fe, Cr) and MIL-101 (Cr) in resorcinol-formaldehyde xerogels for water adsorption applications. Microporous Mesoporous Mater 215:143–153CrossRef Wickenheisser M, Herbst A, Tannert R, Milow B, Janiak C (2015) Hierarchical MOF-xerogel monolith composites from embedding MIL-100 (Fe, Cr) and MIL-101 (Cr) in resorcinol-formaldehyde xerogels for water adsorption applications. Microporous Mesoporous Mater 215:143–153CrossRef
18.
Zurück zum Zitat Wickenheisser M, Janiak C (2015) Hierarchical embedding of micro-mesoporous MIL-101 (Cr) in macroporous poly (2-hydroxyethyl methacrylate) high internal phase emulsions with monolithic shape for vapor adsorption applications. Microporous Mesoporous Mater 204:242–250CrossRef Wickenheisser M, Janiak C (2015) Hierarchical embedding of micro-mesoporous MIL-101 (Cr) in macroporous poly (2-hydroxyethyl methacrylate) high internal phase emulsions with monolithic shape for vapor adsorption applications. Microporous Mesoporous Mater 204:242–250CrossRef
19.
Zurück zum Zitat Channell MN, Sefa M, Fedchak JA, Scherschligt J, Miller AE, Ahmed Z, Hartings MR (2017) Toward 3D printed hydrogen storage materials made with ABS-MOF composites. Polym Adv Technol 1–7 Channell MN, Sefa M, Fedchak JA, Scherschligt J, Miller AE, Ahmed Z, Hartings MR (2017) Toward 3D printed hydrogen storage materials made with ABS-MOF composites. Polym Adv Technol 1–7
20.
Zurück zum Zitat Rochat S, Polak-Kraśna K, Tian M, Holyfield LT, Mays TJ, Bowen CR, Burrows AD (2017) Hydrogen storage in polymer-based processable microporous composites. J Mater Chem A 5:18752–18761CrossRef Rochat S, Polak-Kraśna K, Tian M, Holyfield LT, Mays TJ, Bowen CR, Burrows AD (2017) Hydrogen storage in polymer-based processable microporous composites. J Mater Chem A 5:18752–18761CrossRef
22.
Zurück zum Zitat Ren J, Musyoka NM, Langmi HW, Segakweng T, North BC, Mathe M, Kang X (2014) Modulated synthesis of chromium-based metal-organic framework (MIL-101) with enhanced hydrogen uptake. Int J Hydrogen Energy 39:12018–12023CrossRef Ren J, Musyoka NM, Langmi HW, Segakweng T, North BC, Mathe M, Kang X (2014) Modulated synthesis of chromium-based metal-organic framework (MIL-101) with enhanced hydrogen uptake. Int J Hydrogen Energy 39:12018–12023CrossRef
23.
Zurück zum Zitat Budd PM, Elabas ES, Ghanem BS, Makhseed S, McKeown NB, Msayib KJ, Tattershall CE, Wang D (2004) Solution-processed, organophilic membrane derived from a polymer of intrinsic microporosity. Adv Mater 16:456–459CrossRef Budd PM, Elabas ES, Ghanem BS, Makhseed S, McKeown NB, Msayib KJ, Tattershall CE, Wang D (2004) Solution-processed, organophilic membrane derived from a polymer of intrinsic microporosity. Adv Mater 16:456–459CrossRef
24.
Zurück zum Zitat Wu X, Liu W, Wu H, Zong X, Yang L, Wu Y, Ren Y, Shi C, Wang S, Jiang Z (2018) Nanoporous ZIF-67 embedded polymers of intrinsic microporosity membranes with enhanced gas separation performance. J Membr Sci 548:309–318CrossRef Wu X, Liu W, Wu H, Zong X, Yang L, Wu Y, Ren Y, Shi C, Wang S, Jiang Z (2018) Nanoporous ZIF-67 embedded polymers of intrinsic microporosity membranes with enhanced gas separation performance. J Membr Sci 548:309–318CrossRef
25.
Zurück zum Zitat Yang JF, Zhao Q, Li JP, Dong JX (2010) Synthesis of metal–organic framework MIL-101 in TMAOH-Cr(NO3)3-H2BDC-H2O and its hydrogen-storage behaviour. Microporous Mesoporous Mater 130:174–179CrossRef Yang JF, Zhao Q, Li JP, Dong JX (2010) Synthesis of metal–organic framework MIL-101 in TMAOH-Cr(NO3)3-H2BDC-H2O and its hydrogen-storage behaviour. Microporous Mesoporous Mater 130:174–179CrossRef
26.
Zurück zum Zitat Du N, Robertson GP, Song J, Pinnau I, Thomas S, Guiver MD (2008) Polymers of intrinsic microporosity containing trifluoromethyl and phenylsulfone groups as materials for membrane gas separation. Macromolecules 41:9656–9662CrossRef Du N, Robertson GP, Song J, Pinnau I, Thomas S, Guiver MD (2008) Polymers of intrinsic microporosity containing trifluoromethyl and phenylsulfone groups as materials for membrane gas separation. Macromolecules 41:9656–9662CrossRef
27.
Zurück zum Zitat Broom DP, Webb CJ, Hurst KE, Parilla PA, Gennett T, Brown CM, Zacharia R, Tylianakis E, Klontzas E, Froudakis GE, Steriotis TA (2016) Outlook and challenges for hydrogen storage in nanoporous materials. Appl Phys A 122:151–171CrossRef Broom DP, Webb CJ, Hurst KE, Parilla PA, Gennett T, Brown CM, Zacharia R, Tylianakis E, Klontzas E, Froudakis GE, Steriotis TA (2016) Outlook and challenges for hydrogen storage in nanoporous materials. Appl Phys A 122:151–171CrossRef
28.
Zurück zum Zitat Ren J, Musyoka NM, Langmi HW, North BC, Mathe M, Kang X (2014) Fabrication of core-shell MIL-101(Cr)@UiO-66(Zr) nanocrystals for hydrogen storage. Int J Hydrogen Energy 39:14912–14917CrossRef Ren J, Musyoka NM, Langmi HW, North BC, Mathe M, Kang X (2014) Fabrication of core-shell MIL-101(Cr)@UiO-66(Zr) nanocrystals for hydrogen storage. Int J Hydrogen Energy 39:14912–14917CrossRef
Metadaten
Titel
Synthesis of porous polymer-based metal–organic frameworks monolithic hybrid composite for hydrogen storage application
verfasst von
Lerato Y. Molefe
Nicholas M. Musyoka
Jianwei Ren
Henrietta W. Langmi
Patrick G. Ndungu
Robert Dawson
Mkhulu Mathe
Publikationsdatum
22.01.2019
Verlag
Springer US
Erschienen in
Journal of Materials Science / Ausgabe 9/2019
Print ISSN: 0022-2461
Elektronische ISSN: 1573-4803
DOI
https://doi.org/10.1007/s10853-019-03367-1

Weitere Artikel der Ausgabe 9/2019

Journal of Materials Science 9/2019 Zur Ausgabe

    Marktübersichten

    Die im Laufe eines Jahres in der „adhäsion“ veröffentlichten Marktübersichten helfen Anwendern verschiedenster Branchen, sich einen gezielten Überblick über Lieferantenangebote zu verschaffen.