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Erschienen in: Arabian Journal for Science and Engineering 6/2020

10.04.2020 | Research Article-Chemistry

Synthesis of Trifluoroacetylacetone Resin Through Schiff’s Base Reaction for Treatment of Cadmium-Contaminated Water

verfasst von: Abdul Majid Channa, Saima Qayoom Memon, Muhammad Yar Khuhawar, Sıtkı Baytak

Erschienen in: Arabian Journal for Science and Engineering | Ausgabe 6/2020

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Abstract

The present study reports two-step synthesis of a new resin, i.e. trifluoroacetylacetone (TFAA)-XAD (X) resin via Schiff’s base reaction. Synthesized resin was used to treat cadmium-contaminated water. Before application to the real water system, a method for the removal of Cd(II) ions was optimized using design of experiment. A face-centred composite design (CCD) predicted 97.0% removal at pH 10; other optimum parameters were concentration of Cd(II) ion 10 mg l−1, sorbent amount 82.0 mg, shaking speed 200 rpm and shaking time 63 min. Predicted removal was found to be in good agreement with experimental removal. Equilibrium data were good fit to Langmuir, Freundlich and D–R isotherms with a correlation coefficient (R2) of 0.98, 0.97 and 0.98, respectively. Monolayer sorption capacity of X-TFAA resin for Cd(II) ions calculated was 403 mg g−1. The sorption energy (E) calculated was 9.2 kJ mol−1, revealed chemisorption of Cd(II) ions onto the X-TFAA resin. The developed method was applied successfully for the removal of Cd(II) ions in environmental water samples.

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Literatur
1.
Zurück zum Zitat Tchounwou, P.B.; Yedjou, C.G.; Patlolla, A.K.; Sutton, D.J.: Heavy Metals Toxicity and the Environment, Molecular, Clinical and Environmental Toxicology, pp. 133–164. Springer, Berlin (2012)CrossRef Tchounwou, P.B.; Yedjou, C.G.; Patlolla, A.K.; Sutton, D.J.: Heavy Metals Toxicity and the Environment, Molecular, Clinical and Environmental Toxicology, pp. 133–164. Springer, Berlin (2012)CrossRef
2.
Zurück zum Zitat Rao, K.S.; Mohapatra, M.; Anand, S.; Venkateswarlu, P.: Review on cadmium removal from aqueous solutions. Int. J. Eng., Sci. Technol. 2, 81–103 (2010) Rao, K.S.; Mohapatra, M.; Anand, S.; Venkateswarlu, P.: Review on cadmium removal from aqueous solutions. Int. J. Eng., Sci. Technol. 2, 81–103 (2010)
3.
Zurück zum Zitat Cheung, C.W.; Porter, J.F.; McKay, G.: Elovich equation and modified second-order equation for adsorption of cadmium ions onto bone char. J. Chem. Technol. Biotechnol. 75, 963–970 (2000)CrossRef Cheung, C.W.; Porter, J.F.; McKay, G.: Elovich equation and modified second-order equation for adsorption of cadmium ions onto bone char. J. Chem. Technol. Biotechnol. 75, 963–970 (2000)CrossRef
4.
Zurück zum Zitat Mohan, D.; Singh, K.P.: Single and multi-component adsorption of cadmium and zinc using activated carbon derived from bagasse—an agricultural waste. Carbon 36, 2304–2318 (2002) Mohan, D.; Singh, K.P.: Single and multi-component adsorption of cadmium and zinc using activated carbon derived from bagasse—an agricultural waste. Carbon 36, 2304–2318 (2002)
5.
Zurück zum Zitat Volesky, B.: Biosorption of Heavy Metals. CRC Press, Boston (1990) Volesky, B.: Biosorption of Heavy Metals. CRC Press, Boston (1990)
6.
Zurück zum Zitat Ko, Y.G.; Choi, U.S.; Kim, J.S.; et al.: Novel synthesis and characterization of activated carbon fiber and dye adsorption modelling. Carbon 40, 2661–2672 (2002)CrossRef Ko, Y.G.; Choi, U.S.; Kim, J.S.; et al.: Novel synthesis and characterization of activated carbon fiber and dye adsorption modelling. Carbon 40, 2661–2672 (2002)CrossRef
7.
Zurück zum Zitat Ejtemaei, M.; Gharabaghi, M.; Irannajad, M.: A review of zinc oxide mineral beneficiation using flotation method. Adv. Colloid Interface Sci. 206, 68–78 (2014)CrossRef Ejtemaei, M.; Gharabaghi, M.; Irannajad, M.: A review of zinc oxide mineral beneficiation using flotation method. Adv. Colloid Interface Sci. 206, 68–78 (2014)CrossRef
8.
Zurück zum Zitat Pustam, A.N.; Alexandratos, S.D.: Engineering selectivity into polymer supported reagents for transition metal ion complex formation. React. Funct. Polym. 70, 45–554 (2010)CrossRef Pustam, A.N.; Alexandratos, S.D.: Engineering selectivity into polymer supported reagents for transition metal ion complex formation. React. Funct. Polym. 70, 45–554 (2010)CrossRef
9.
Zurück zum Zitat Li, L.; Liu, F.; Jing, X.; et al.: Displacement mechanism of binary competitive adsorption for aqueous divalent metal ions onto a novel IDA chelating resin isotherm and kinetic modelling. Water Res. 45(3), 1177–1188 (2011)CrossRef Li, L.; Liu, F.; Jing, X.; et al.: Displacement mechanism of binary competitive adsorption for aqueous divalent metal ions onto a novel IDA chelating resin isotherm and kinetic modelling. Water Res. 45(3), 1177–1188 (2011)CrossRef
10.
Zurück zum Zitat Baytak, S.; Mertve, R.; Türker, A.R.: Determination of Cu(II), Fe(III), Mn(II) and Zn(II) in various samples after preconcentration with Rhizopus oryzae loaded natural cellulose (almond bark). Int. J. Environ. Anal. Chem. 94, 975–987 (2014)CrossRef Baytak, S.; Mertve, R.; Türker, A.R.: Determination of Cu(II), Fe(III), Mn(II) and Zn(II) in various samples after preconcentration with Rhizopus oryzae loaded natural cellulose (almond bark). Int. J. Environ. Anal. Chem. 94, 975–987 (2014)CrossRef
11.
Zurück zum Zitat Baytak, S.; Türker, A.R.: Determination of chromium, cadmium and manganese in water and fish samples after preconcentration using penicillium digitatum immobilized on pumice stone. CLEAN Soil Air Water 37, 314–318 (2009)CrossRef Baytak, S.; Türker, A.R.: Determination of chromium, cadmium and manganese in water and fish samples after preconcentration using penicillium digitatum immobilized on pumice stone. CLEAN Soil Air Water 37, 314–318 (2009)CrossRef
12.
Zurück zum Zitat Ahmad, A.; Siddique, J.A.; Laskar, M.A.; et al.: New generation Amberlite XAD resin for the removal of metal ions: a review. J. Environ. Sci. 31, 104–123 (2015)CrossRef Ahmad, A.; Siddique, J.A.; Laskar, M.A.; et al.: New generation Amberlite XAD resin for the removal of metal ions: a review. J. Environ. Sci. 31, 104–123 (2015)CrossRef
13.
Zurück zum Zitat Mottol, H.A.; Steimetz, J.R.: Chemically Modified Surfaces. Elsevier, Amsterdam (1992) Mottol, H.A.; Steimetz, J.R.: Chemically Modified Surfaces. Elsevier, Amsterdam (1992)
14.
Zurück zum Zitat Chowdhury, D.A.; UlHoque, M.I.; Fardous, Z.: Solid phase extraction of copper, cadmium and lead using Amberlite XAD-4 resin functionalized with 2-hydroxyl benzaldehydethiosemicarbazone and its application on green tea leaves. Jordan J. Chem. 8, 90–102 (2013) Chowdhury, D.A.; UlHoque, M.I.; Fardous, Z.: Solid phase extraction of copper, cadmium and lead using Amberlite XAD-4 resin functionalized with 2-hydroxyl benzaldehydethiosemicarbazone and its application on green tea leaves. Jordan J. Chem. 8, 90–102 (2013)
15.
Zurück zum Zitat Baytak, S.; Turker, A.R.: The use of Agrobacterium tumefacients immobilized on Amberlite XAD-4 as a new bio sorbent for the column preconcentration of iron(III), cobalt(II), manganese(II) and chromium (III). Talanta 65, 938–945 (2005)CrossRef Baytak, S.; Turker, A.R.: The use of Agrobacterium tumefacients immobilized on Amberlite XAD-4 as a new bio sorbent for the column preconcentration of iron(III), cobalt(II), manganese(II) and chromium (III). Talanta 65, 938–945 (2005)CrossRef
16.
Zurück zum Zitat Baytak, S.; Balaban, A.; Türker, A.R.; et al.: Atomic absorption spectrometric determination of Fe(III), and Cr(III) in various samples after preconcentration by solid phase extraction with pyridine-2-carbaldehyde thiosemicarbazone. J. Anal. Chem. 61, 476–482 (2006)CrossRef Baytak, S.; Balaban, A.; Türker, A.R.; et al.: Atomic absorption spectrometric determination of Fe(III), and Cr(III) in various samples after preconcentration by solid phase extraction with pyridine-2-carbaldehyde thiosemicarbazone. J. Anal. Chem. 61, 476–482 (2006)CrossRef
17.
Zurück zum Zitat Ghaedi, M.K.; Niknam, K.; Taheri, K.; et al.: flame atomic absorption spectrometric determination of copper, zinc and manganese after solid-phase extraction using 2,6-dichlorophenyl-3,3-bis(indolyl)methane loaded on Amberlite XAD-16. Food Chem. Toxicol. 48, 891–897 (2010)CrossRef Ghaedi, M.K.; Niknam, K.; Taheri, K.; et al.: flame atomic absorption spectrometric determination of copper, zinc and manganese after solid-phase extraction using 2,6-dichlorophenyl-3,3-bis(indolyl)methane loaded on Amberlite XAD-16. Food Chem. Toxicol. 48, 891–897 (2010)CrossRef
18.
Zurück zum Zitat Vyas, D.J.; Makwana, B.A.; Bhatt, K.D.; et al.: Octa-O-methoxyresorcine [4] arene Amberlite XAD-4 polymeric chelating resin for solid phase extraction, preconcentration, separation and trace determination of Ni(II), Cu(II), Zn(II) and Cd(II) ions. Am. J. Anal. Chem. 4, 238–251 (2013)CrossRef Vyas, D.J.; Makwana, B.A.; Bhatt, K.D.; et al.: Octa-O-methoxyresorcine [4] arene Amberlite XAD-4 polymeric chelating resin for solid phase extraction, preconcentration, separation and trace determination of Ni(II), Cu(II), Zn(II) and Cd(II) ions. Am. J. Anal. Chem. 4, 238–251 (2013)CrossRef
19.
Zurück zum Zitat Oral, E.V.; Dolak, I.; Temel, H.; et al.: Preconcentration and determination of copper and cadmium ions with 1,6-bis(2-carboxy aldehyde phenoxy)butane functionalized Amberlite XAD-16 by flame atomic absorption spectrometry. J. Hazard. Mater. 186, 724–730 (2011)CrossRef Oral, E.V.; Dolak, I.; Temel, H.; et al.: Preconcentration and determination of copper and cadmium ions with 1,6-bis(2-carboxy aldehyde phenoxy)butane functionalized Amberlite XAD-16 by flame atomic absorption spectrometry. J. Hazard. Mater. 186, 724–730 (2011)CrossRef
20.
Zurück zum Zitat Guo, Y.; Din, B.J.; Liu, Y.W.; et al.: Preconcentration of trace metals with 2-(methylthio)aniline-functionalized XAD-2 and their determination by flame atomic absorption spectrometry. Anal. Chim. Acta 504, 319–324 (2004)CrossRef Guo, Y.; Din, B.J.; Liu, Y.W.; et al.: Preconcentration of trace metals with 2-(methylthio)aniline-functionalized XAD-2 and their determination by flame atomic absorption spectrometry. Anal. Chim. Acta 504, 319–324 (2004)CrossRef
21.
Zurück zum Zitat Lemos, V.A.; Baliza, P.X.; Santos, J.S.; et al.: A new functionalized resin and its application in preconcentration system with multivariate optimization for nickel determination in food samples. Talanta 66, 174–180 (2005)CrossRef Lemos, V.A.; Baliza, P.X.; Santos, J.S.; et al.: A new functionalized resin and its application in preconcentration system with multivariate optimization for nickel determination in food samples. Talanta 66, 174–180 (2005)CrossRef
22.
Zurück zum Zitat Liu, Y.W.; Guo, Y.; Chang, X.J.; et al.: Column solid-phase extraction with 2-acetylmercaptophenyldiazoaminoazobenzene (AMPDAA) impregnated Amberlite XAD-4 and determination of trace heavy metals in natural waters by flame atomic absorption spectrometry. Microchim. Acta 149, 95–101 (2005)CrossRef Liu, Y.W.; Guo, Y.; Chang, X.J.; et al.: Column solid-phase extraction with 2-acetylmercaptophenyldiazoaminoazobenzene (AMPDAA) impregnated Amberlite XAD-4 and determination of trace heavy metals in natural waters by flame atomic absorption spectrometry. Microchim. Acta 149, 95–101 (2005)CrossRef
23.
Zurück zum Zitat Liu, Y.W.; Guo, Y.; Meng, S.M.; et al.: Online separation and preconcentration of trace heavy metals with 2,6-dihydroxyphenyl-diazoaminoazobenzene impregnated Amberlite XAD-4. Microchim. Acta 158, 239–245 (2007)CrossRef Liu, Y.W.; Guo, Y.; Meng, S.M.; et al.: Online separation and preconcentration of trace heavy metals with 2,6-dihydroxyphenyl-diazoaminoazobenzene impregnated Amberlite XAD-4. Microchim. Acta 158, 239–245 (2007)CrossRef
24.
Zurück zum Zitat Kadirvelu, K.; Thamaraiselvi, K.; Namasivayam, C.: Adsorption of nickel(II) from aqueous solution onto activated carbon prepared from coirpith. Sep. Purif. Technol. 24, 497–505 (2001)CrossRef Kadirvelu, K.; Thamaraiselvi, K.; Namasivayam, C.: Adsorption of nickel(II) from aqueous solution onto activated carbon prepared from coirpith. Sep. Purif. Technol. 24, 497–505 (2001)CrossRef
25.
Zurück zum Zitat Zolghanein, J.; Shahmoradi, A.; Sangi, M.R.: Optimization of Pb(II) biosorption by Robinia tree leaves using statistical design of experiments. Talanta 76, 528–532 (2008)CrossRef Zolghanein, J.; Shahmoradi, A.; Sangi, M.R.: Optimization of Pb(II) biosorption by Robinia tree leaves using statistical design of experiments. Talanta 76, 528–532 (2008)CrossRef
26.
Zurück zum Zitat Kumar, J.; Balomajumder, C.; Mondal, P.: Application of agro-based biomasses for zinc removal from wastewater—a review. CLEAN Soil Air Water 39, 641–652 (2011)CrossRef Kumar, J.; Balomajumder, C.; Mondal, P.: Application of agro-based biomasses for zinc removal from wastewater—a review. CLEAN Soil Air Water 39, 641–652 (2011)CrossRef
27.
Zurück zum Zitat Sanchez, M.J.; Beltran, H.J.; Carmona, M.C.: Adsorbents from Schinopsisbalansae: optimisation of significant variables. Ind. Crops Prod. 33, 409–417 (2011)CrossRef Sanchez, M.J.; Beltran, H.J.; Carmona, M.C.: Adsorbents from Schinopsisbalansae: optimisation of significant variables. Ind. Crops Prod. 33, 409–417 (2011)CrossRef
28.
Zurück zum Zitat Memon, S.Q.; Hasany, S.M.; Bhanger, M.I.; et al.: Enrichment of Pb(II) ions using phthalic acid functionalized XAD-16 resin as a sorbent. J. Colloid Interface Sci. 291, 84–91 (2005)CrossRef Memon, S.Q.; Hasany, S.M.; Bhanger, M.I.; et al.: Enrichment of Pb(II) ions using phthalic acid functionalized XAD-16 resin as a sorbent. J. Colloid Interface Sci. 291, 84–91 (2005)CrossRef
29.
Zurück zum Zitat Ruthven, D.M.: Principles of Adsorption and Adsorption Processes. Wiley, New York (1985) Ruthven, D.M.: Principles of Adsorption and Adsorption Processes. Wiley, New York (1985)
30.
Zurück zum Zitat Ajmal, M.R.; Rao, J.A.; Anwar, R.; et al.: Adsorption studies on rice husk: removal and recovery of Cd (II) from wastewater. Bioresour. Technol. 86, 147–149 (2003)CrossRef Ajmal, M.R.; Rao, J.A.; Anwar, R.; et al.: Adsorption studies on rice husk: removal and recovery of Cd (II) from wastewater. Bioresour. Technol. 86, 147–149 (2003)CrossRef
31.
Zurück zum Zitat Ulmanu, M.; Maranon, E.; Fernandez, Y.; et al.: Removal of copper and cadmium ions from diluted aqueous solutions by low cost and waste material adsorbents. Water Air Soil Pollut. 142, 357–373 (2003)CrossRef Ulmanu, M.; Maranon, E.; Fernandez, Y.; et al.: Removal of copper and cadmium ions from diluted aqueous solutions by low cost and waste material adsorbents. Water Air Soil Pollut. 142, 357–373 (2003)CrossRef
32.
Zurück zum Zitat Bulut, Y.; Tez, Z.: Removal of heavy metals from aqueous solution by sawdust adsorption. J. Environ. Sci. 19, I60–I166 (2007)CrossRef Bulut, Y.; Tez, Z.: Removal of heavy metals from aqueous solution by sawdust adsorption. J. Environ. Sci. 19, I60–I166 (2007)CrossRef
33.
Zurück zum Zitat Mohammad, W.A.; Khalili, F.I.; Awwad, A.M.: Adsorption of lead, zinc, and cadmium ions on polyphosphate-modified Kaolinite clay. J. Environ. Chem. Ecotoxicol. 2, 1–8 (2010) Mohammad, W.A.; Khalili, F.I.; Awwad, A.M.: Adsorption of lead, zinc, and cadmium ions on polyphosphate-modified Kaolinite clay. J. Environ. Chem. Ecotoxicol. 2, 1–8 (2010)
34.
Zurück zum Zitat Denizli, A.; Sanli, N.; Garipcan, B.; et al.: Methacryloylamidoglutamic acid incorporated porous poly(methyl methacrylate) beads for heavy-metal removal. Ind. Eng. Chem. Res. 43, 6095–6101 (2004)CrossRef Denizli, A.; Sanli, N.; Garipcan, B.; et al.: Methacryloylamidoglutamic acid incorporated porous poly(methyl methacrylate) beads for heavy-metal removal. Ind. Eng. Chem. Res. 43, 6095–6101 (2004)CrossRef
Metadaten
Titel
Synthesis of Trifluoroacetylacetone Resin Through Schiff’s Base Reaction for Treatment of Cadmium-Contaminated Water
verfasst von
Abdul Majid Channa
Saima Qayoom Memon
Muhammad Yar Khuhawar
Sıtkı Baytak
Publikationsdatum
10.04.2020
Verlag
Springer Berlin Heidelberg
Erschienen in
Arabian Journal for Science and Engineering / Ausgabe 6/2020
Print ISSN: 2193-567X
Elektronische ISSN: 2191-4281
DOI
https://doi.org/10.1007/s13369-020-04504-8

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