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2020 | OriginalPaper | Buchkapitel

13. Synthetic Methods and Applications of Functional and Reactive Silicone Polymers

verfasst von : Kaleigh M. Ryan, Adam D. Drumm, Claire E. Martin, Anna-Katharina Krumpfer, Joseph W. Krumpfer

Erschienen in: Reactive and Functional Polymers Volume One

Verlag: Springer International Publishing

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Abstract

Siloxane polymers (widely known as silicones) are ubiquitous materials with a wide range of applications, from pharmaceuticals and medical devices to nautical sealants and high temperature lubricants. This is due to its robust and advantageous properties as an inorganic-organic polymer, which differ widely from traditional polyolefin materials. In this chapter, the unique and remarkable properties of siloxane polymers will be analyzed, as well as the synthetic strategies for the preparation of traditional and functional silicones. An examination of the functions of siloxane polymers and copolymers in various industries, such as polyurethane foams and fluorosilicone lubricants, is presented. Traditional methods for crosslinking of siloxane polymers and the resulting coatings and bulk materials will be compared with recent advances in silicone coupling reactions, such as the Piers-Rubinsztajn and ‘click’ reactions. Finally, we examine the new emerging approach on the siloxane bond as a reactive functional group in its own right for the preparation of advanced non-stick resins and surfaces.

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Literatur
Zurück zum Zitat Brook, M. A. (2000). Silicon in organic, organometallic, and polymer chemistry. New York: John Wiley & Sons. ISBN: 978-0-471-19658-7. Brook, M. A. (2000). Silicon in organic, organometallic, and polymer chemistry. New York: John Wiley & Sons. ISBN: 978-0-471-19658-7.
Zurück zum Zitat Clarson, S. J., & Semlyen, J. A. (1993). Siloxane polymers. Prentice Hill: Englewood Cliffs. ISBN: 978-0138163150. Clarson, S. J., & Semlyen, J. A. (1993). Siloxane polymers. Prentice Hill: Englewood Cliffs. ISBN: 978-0138163150.
Zurück zum Zitat Longenberger, T.B., Krumpfer, J.W., (n.d.) Unpublished results. Longenberger, T.B., Krumpfer, J.W., (n.d.) Unpublished results.
Zurück zum Zitat Mathew, A., Kurmvanshi, S., Mohanty, S., & Nayak, S. K. (2018). Sustainable production of polyurethane from castor oil, functionalized with epoxy- and hydroxyl-terminated poly(dimethyl siloxane) for biomedical applications. Journal of Materials Science, 53(5), 3119–3130. https://doi.org/10.1007/s10853-017-1757-3.CrossRef Mathew, A., Kurmvanshi, S., Mohanty, S., & Nayak, S. K. (2018). Sustainable production of polyurethane from castor oil, functionalized with epoxy- and hydroxyl-terminated poly(dimethyl siloxane) for biomedical applications. Journal of Materials Science, 53(5), 3119–3130. https://​doi.​org/​10.​1007/​s10853-017-1757-3.CrossRef
Zurück zum Zitat Müller, R., German Patent No. C57411, 1942. Müller, R., German Patent No. C57411, 1942.
Zurück zum Zitat Nasir, I. A. A., Alis, A., Mohamad, Z., Che Man, S. H., & Majid, R. A. (2016). Rigid polyurethane foam from palm oil polyol-polyethylene glycol blend. Journal of Polymer Materials, 33, 629–637. ISSN: 09738622. Nasir, I. A. A., Alis, A., Mohamad, Z., Che Man, S. H., & Majid, R. A. (2016). Rigid polyurethane foam from palm oil polyol-polyethylene glycol blend. Journal of Polymer Materials, 33, 629–637. ISSN: 09738622.
Zurück zum Zitat Okamoto, Y., Crossan, D., Ferrigno, K., & Nakos, S. (1988). Ultraviolet curable siloxane polymers. In L. H. Lee (Ed.), Adhesives, sealants, and coatings for space and harsh environments (Polymer science and technology) (Vol. 37). Boston: Springer. isbn:978-1-4613-1047-1. Okamoto, Y., Crossan, D., Ferrigno, K., & Nakos, S. (1988). Ultraviolet curable siloxane polymers. In L. H. Lee (Ed.), Adhesives, sealants, and coatings for space and harsh environments (Polymer science and technology) (Vol. 37). Boston: Springer. isbn:978-1-4613-1047-1.
Zurück zum Zitat Peters, M. A., Belu, A. M., Linton, R. W., Dupray, L., & Meyer, T. J. (1995). Termination of living anionic polymerizations using chlorosilane derivatives: A general synthetic methodology for synthesis of end-functionalized polymers. Journal of the American Chemical Society, 117, 3380–3388. https://doi.org/10.1021/ja00117a008.CrossRef Peters, M. A., Belu, A. M., Linton, R. W., Dupray, L., & Meyer, T. J. (1995). Termination of living anionic polymerizations using chlorosilane derivatives: A general synthetic methodology for synthesis of end-functionalized polymers. Journal of the American Chemical Society, 117, 3380–3388. https://​doi.​org/​10.​1021/​ja00117a008.CrossRef
Zurück zum Zitat Plueddemann, E. W. (1991). Silane coupling agents (2nd ed.). Plenum: New York. isbn:978-1-4899-2070-6.CrossRef Plueddemann, E. W. (1991). Silane coupling agents (2nd ed.). Plenum: New York. isbn:978-1-4899-2070-6.CrossRef
Zurück zum Zitat Post, H. W. (1949). Silicones and other organosilicon compounds. New York: Reinhold. Post, H. W. (1949). Silicones and other organosilicon compounds. New York: Reinhold.
Zurück zum Zitat Rambarran, T., Gonzaga, F., Brook, M. A., Lasowski, F., & Sheardown, H. (2015). Amphiphilic thermoset elastomers from metal-free, click crosslinking of PEG-grafted silicone surfactants. Journal of Polymer Science: Part A, 53(9), 1082–1093. https://doi.org/10.1002/pola.27539.CrossRef Rambarran, T., Gonzaga, F., Brook, M. A., Lasowski, F., & Sheardown, H. (2015). Amphiphilic thermoset elastomers from metal-free, click crosslinking of PEG-grafted silicone surfactants. Journal of Polymer Science: Part A, 53(9), 1082–1093. https://​doi.​org/​10.​1002/​pola.​27539.CrossRef
Zurück zum Zitat Rochow, E. G. (1946). Introduction to the chemistry of the silicones. New York/London: John Wiley & Sons, Chapman & Hall. ISBN: 978-1298498397.CrossRef Rochow, E. G. (1946). Introduction to the chemistry of the silicones. New York/London: John Wiley & Sons, Chapman & Hall. ISBN: 978-1298498397.CrossRef
Zurück zum Zitat This is noted on page (n.d.) 262 of Reference 3. This is noted on page (n.d.) 262 of Reference 3.
Metadaten
Titel
Synthetic Methods and Applications of Functional and Reactive Silicone Polymers
verfasst von
Kaleigh M. Ryan
Adam D. Drumm
Claire E. Martin
Anna-Katharina Krumpfer
Joseph W. Krumpfer
Copyright-Jahr
2020
DOI
https://doi.org/10.1007/978-3-030-43403-8_13

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