nach oben

Cellulose

Erschienen in:

21.02.2020 | Original Research

Technical and environmental improvement of the bleaching sequence of dissolving pulp for fibre production

verfasst von: Carlos Arce, Tamara Llano, Pablo García, Alberto Coz

Erschienen in: Cellulose | Ausgabe 7/2020

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config

KI-gestützte Suche

Aus

Abstract

Reactivity of dissolving pulp is one of the main parameters to determine its availability to be transformed into viscose. It is related to the use of carbon disulphide (CS₂). An industrial sequential totally chlorine free bleaching process is used as case study. It is carried out in two stages: (1) Alkaline extraction (EOP) and (2) peroxide bleaching (PO). In order to assess how to decrease the use of carbon disulphide, several experiments were performed at laboratory scale for the two stages mentioned before by modifying the operating conditions: NaOH and H₂O₂ dosages, time and temperature. Reactivity using a modified Fock’s method and pentosan content was analysed along with quality pulp parameters: α-cellulose, viscosity and lignin content (kappa number). Results showed that reactivity increases through the bleaching process and varies with the chemical dosage in both stages. Pulp obtained at the best conditions had the following characteristics: reactivity, 95.3%; α-cellulose 91.17%; intrinsic viscosity, 448 mL/g; kappa number, 1.81 and pentosan content 2.86%, and as a result, CS₂ usage was reduced by 11.88%. At the best conditions obtained in this work, NaOH dosage in PO stage was reduced to zero and temperature was slightly lower, when compared with industrial operating conditions.

Vorheriger Artikel Changes in the chemical composition of young Chinese fir wood exposed to different soil temperature and water content

Nächster Artikel Development of sustainable and cost efficient textile foam-finishing and its comparison with conventional padding

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

über 67.000 Bücher
über 390 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Maschinenbau + Werkstoffe

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

über 102.000 Bücher
über 537 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Finance + Banking
Management + Führung
Marketing + Vertrieb
Maschinenbau + Werkstoffe
Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Bahrami B, Behzad T, Zamani A et al (2018) Optimal design of ozone bleaching parameters to approach cellulose nanofibers extraction from sugarcane bagasse fibers. J Polym Environ 26:4085–4094. https://doi.org/10.1007/s10924-018-1277-5 CrossRef

Borrega M, Larsson PT, Ahvenainen P et al (2018) Birch wood pre-hydrolysis vs pulp post-hydrolysis for the production of xylan-based compounds and cellulose for viscose application. Carbohydr Polym 190:212–221. https://doi.org/10.1016/j.carbpol.2018.02.064 CrossRefPubMed

Brice R (2012) High purity cellulose through 2020. In: The cellulose gap. Monte Carlo. http://csales.ch/cellulosegap2012_lineup.php

Chao JW, Shu FZ, Chuan ZS, Dai QW (2014) Improved reactivity of bamboo dissolving pulp for the viscose process: post-treatment with beating. BioResources 9:3449–3455. https://doi.org/10.15376/biores.9.2.3449-3455 CrossRef

Chen C, Duan C, Li J et al (2016) Cellulose (dissolving pulp) manufacturing processes and properties: a mini-review. BioResources 11:5553–5564. https://doi.org/10.15376/biores.11.2.Chen CrossRef

Christoffersson KE, Sjostrom M, Edlund U et al (2002) Reactivity of dissolving pulp: characterisation using chemical properties, NMR spectroscopy and multivariate data analysis. Cellulose 9:159–170. https://doi.org/10.1023/A:1020108125490 CrossRef

Dinand E, Vignon M, Chanzy H, Heux L (2002) Mercerization of primary wall cellulose and its implication for the conversion of cellulose I → cellulose II. Cellulose. https://doi.org/10.1023/A:1015877021688 CrossRef

Duan C, Li J, Ma X et al (2015) Comparison of acid sulfite (AS)- and prehydrolysis kraft (PHK)-based dissolving pulps. Cellulose 22:4017–4026. https://doi.org/10.1007/s10570-015-0781-1 CrossRef

Duan C, Verma SK, Li J et al (2016) Combination of mechanical, alkaline and enzymatic treatments to upgrade paper-grade pulp to dissolving pulp with high reactivity. Bioresour Technol. https://doi.org/10.1016/j.biortech.2015.10.067 CrossRefPubMed

Duan C, Wang X, Zhang YL et al (2017) Fractionation and cellulase treatment for enhancing the properties of kraft-based dissolving pulp. Bioresour Technol 224:439–444. https://doi.org/10.1016/j.biortech.2016.10.077 CrossRefPubMed

Fardim P (2011) Chemical pulping part 1 Fibre Chemistry and technology, 2nd edn. Åbo Akademi University, Turku

Fock W (1959) A modified method for determining the reactivity of viscose-grade dissolving pulps. Das Papier 13:92–95

FZ/T 51001-2009, Pulp Board for Viscose Fiber— Determination for Reaction Property. China National Standards Press, Beijing (2011)

Gehmayr V, Schild G, Sixta H (2011) A precise study on the feasibility of enzyme treatments of a kraft pulp for viscose application. Cellulose 18:479–491. https://doi.org/10.1007/s10570-010-9483-x CrossRef

Gondhalekar SC, Pawar PJ, Dhumal SS, Thakre SS (2019) Mechanism of xanthation reaction in viscose process. Cellulose 26:1595–1604. https://doi.org/10.1007/s10570-018-2213-5 CrossRef

Grönqvist S, Hakala TK, Kamppuri T et al (2014) Fibre porosity development of dissolving pulp during mechanical and enzymatic processing. Cellulose 21:3667–3676. https://doi.org/10.1007/s10570-014-0352-x CrossRef

Haule LV (2016) Iodine sorption value and surface chemical analysis of regenerated cellulosic fibres. J Text Sci Technol 02:37–45. https://doi.org/10.4236/jtst.2016.22006 CrossRef

Huang YM, Zhou MX, Xu CS et al (2012) Production practice of bagasse pulp ECF bleaching. Chung-Kuo Tsao Chih/China Pulp Pap 31(4):55–57

Iakovlev M, Sixta H, Van Heiningen A (2011) SO2–ethanol–water (SEW) pulping: II. Kinetics for spruce, beech, and wheat straw. J Wood Chem Technol 31:250–266. https://doi.org/10.1080/02773813.2010.523162 CrossRef

Ibarra D, Köpcke V, Ek M (2010) Behavior of different monocomponent endoglucanases on the accessibility and reactivity of dissolving-grade pulps for viscose process. Enzyme Microb Technol 47:355–362. https://doi.org/10.1016/j.enzmictec.2010.07.016 CrossRef

ISO 5351 (2010) Pulps—determinations of limiting viscosity number in cupriethylenediamine (CED) solution solution. International Organization for Standardization, Geneva

Ji L, Zhao L (2015) Current situation and future trend of the dissolving market in domestic and international. China Pulp Pap Indstry 36:41–45

Jour P, Halldén K, Wackerberg E (2015) Life cycle assessment of ECF bleaching sequences with focus on carbon footprint. Tappi J 14(1):17–24CrossRef

Kaur P, Bhardwaj NK, Sharma J (2017) Pentosan reduction from mixed hardwood kraft pulp with alkali treatment and its statistical optimization. Lignocellulose 6:23–35

Kolar J (1997) Mechanism of autoxidative degradation of cellulose. Restaurator 18:163–176. https://doi.org/10.1515/rest.1997.18.4.163 CrossRef

Köpcke V (2010) Conversion of wood and non-wood paper-grade pulps to dissolving-grade pulps. Doctoral Thesis, KTH Royal Institute of Technology in Stockholm, Sweden

Kotek R (2006) Regenerated cellulose fibers. In: Lewin M (ed) Handbook of fiber chemistry. Taylor & Francis Group, Boca Raton, FL, pp 667–772

Kumar H, Christopher LP (2017) Recent trends and developments in dissolving pulp production and application. Cellulose. https://doi.org/10.1007/s10570-017-1285-y CrossRef

Li H, Legere S, He Z et al (2018a) Methods to increase the reactivity of dissolving pulp in the viscose rayon production process: a review. Cellulose 25:3733–3753. https://doi.org/10.1007/s10570-018-1840-1 CrossRef

Li P, Hou Q, Zhang M, Li X (2018b) Environmentally friendly bleaching on bamboo (Neosinocalamus) kraft pulp cooked by displacement digester system. BioResources 13:450–461. https://doi.org/10.15376/biores.13.1.450-461 CrossRef

Liu Y, Shi L, Cheng D, He Z (2016) Dissolving pulp market and technologies: Chinese prospective—a mini-review. BioResources 11:7902–7916. https://doi.org/10.15376/biores.11.3.Liu CrossRef

Llano T, Arce C, Ruiz G et al (2018) Modelling and optimization of the last two stages of an environmentally-compatible TCF bleaching sequence. BioResources 13:6642–6662. https://doi.org/10.15376/biores.13.3.6642-6662 CrossRef

Loureiro PEG, Domingues EF, Evtuguin DV, Carvalho MGVS (2010) ECF bleaching with a final hydrogen peroxide stage: impact on the chemical composition of Eucalyptus globulus kraft pulps. BioResources 5:2567–2580

Martínez AT (2016) How to break down crystalline cellulose. Science 352:1050–1051. https://doi.org/10.1126/science.aaf8920 CrossRefPubMed

Miao Q, Tian C, Chen L et al (2015) Combined mechanical and enzymatic treatments for improving the Fock reactivity of hardwood kraft-based dissolving pulp. Cellulose 22:803–809. https://doi.org/10.1007/s10570-014-0495-9 CrossRef

Nayeem J, Sarkar M (2017) High purity dissolving pulp from jute. Nordic Pulp Pap Res J. https://doi.org/10.3183/NPPRJ-2017-32-04-p623-629 CrossRef

Östberg L, Håkansson H, Germgård U (2012) Some aspects of the reactivity of pulp intended for high-viscosity viscose. BioResources 7:743–755

Payne CE, Wolfrum EJ (2015) Rapid analysis of composition and reactivity in cellulosic biomass feedstocks with near-infrared spectroscopy. Biotechnol Biofuels. https://doi.org/10.1186/s13068-015-0222-2 CrossRefPubMedPubMedCentral

Quintana E, Valls C, Vidal T, Roncero MB (2015) Comparative evaluation of the action of two different endoglucanases. Part I: on a fully bleached, commercial acid sulfite dissolving pulp. Cellulose 1:2. https://doi.org/10.1007/s10570-015-0623-1 CrossRef

Rebuzzi F, Evtuguin DV (2006) Effect of glucuronoxylan on the hornification of Eucalyptus globulus bleached pulps. Macromol Symp 232:121–128. https://doi.org/10.1002/masy.200551414 CrossRef

Roselli A, Hummel M, Monshizadeh A et al (2014) Ionic liquid extraction method for upgrading eucalyptus kraft pulp to high purity dissolving pulp. Cellulose 21:3655–3666. https://doi.org/10.1007/s10570-014-0344-x CrossRef

Salazar C, Mendonça RT, Baeza J, Freer J (2012) Polpação kraft e branqueamento ECF de eucalyptus globulus pretratado pelo fungo de degradação branca ceriporiopsis subvermispora. Acta Sci Technol 34:277–281. https://doi.org/10.4025/actascitechnol.v34i3.12410 CrossRef

Sango C, Kaur P, Bhardwaj NK, Sharma J (2018) Bacterial cellulase treatment for enhancing reactivity of pre-hydrolysed kraft dissolving pulp for viscose. 3 Biotech 8:1–7. https://doi.org/10.1007/s13205-018-1293-0 CrossRef

Sixta H (2006) Pulp properties and applications. In: Sixta H (ed) Handbook of pulp. Wiley-VCH, Weinheim, pp 1009–1067CrossRef

Sixta H, Schild G (2009) A new generation kraft process. Lenzinger Berichte 87:26–37

Sixta H, Iakovlev M, Testova L et al (2013) Novel concepts of dissolving pulp production. Cellulose 20:1547–1561. https://doi.org/10.1007/s10570-013-9943-1 CrossRef

Strunk P (2012) Characterization of cellulose pulps and the influence of their properties on the process and production of viscose and cellulose ethers. Doctoral dissertation, Umeå University, Sweden

TAPPI T203 cm-99 (1999) Alpha-, beta- and gamma-cellulose in pulp, TAPPI Test Methods. TAPPI Press, Atlanta

TAPPI T205 sp-02 (2002) Forming handsheets for physical test of pulp. TAPPI Test Methods. TAPPI Press, Atlanta

TAPPI UM 246 (1991) “Micro kappa number”, TAPPI useful methods 1991. TAPPI Press, Atlanta, pp 43–44

Tian C, Zheng L, Miao Q et al (2013) Improvement in the Fock test for determining the reactivity of dissolving pulp. Tappi J 12:21–26CrossRef

Tian C, Zheng L, Miao Q et al (2014) Improving the reactivity of kraft-based dissolving pulp for viscose rayon production by mechanical treatments. Cellulose 21:3647–3654. https://doi.org/10.1007/s10570-014-0332-1 CrossRef

Tripathi SK, Bhardwaj NK, Ghatak HR (2019) Effect of introducing ozone prior to elemental chlorine free bleaching of wheat straw pulp on pulp, paper and effluent properties. Cellul Chem Technol 53:105–112CrossRef

Wang H, Pang B, Wu K et al (2014) Two stages of treatments for upgrading bleached softwood paper grade pulp to dissolving pulp for viscose production. Biochem Eng J 82:183–187. https://doi.org/10.1016/j.bej.2013.11.019 CrossRef

Wang X, Duan C, Zhao C et al (2018) Heteropoly acid catalytic treatment for reactivity enhancement and viscosity control of dissolving pulp. Bioresour Technol 253:182–187. https://doi.org/10.1016/j.biortech.2018.01.022 CrossRefPubMed

Yadollahi R, Dehghani Firouzabadi M, Resalati H et al (2018) SO2–ethanol–water (SEW) and kraft pulping of giant milkweed (Calotropis procera) for cellulose acetate film production. Cellulose 25:3281–3294. https://doi.org/10.1007/s10570-018-1802-7 CrossRef

Yamamoto M, Iakovlev M, van Heiningen A (2014) Kinetics of SO2–ethanol–water (SEW) fractionation of hardwood and softwood biomass. Bioresour Technol 155:307–313. https://doi.org/10.1016/j.biortech.2013.12.100 CrossRefPubMed

Yang S, Wen Y, Zhang H et al (2018) Enhancing the Fock reactivity of dissolving pulp by the combined prerefining and poly dimethyl diallyl ammonium chloride-assisted cellulase treatment. Bioresour Technol 260:135–140. https://doi.org/10.1016/j.biortech.2018.03.119 CrossRefPubMed

Yaqoob N, Stack K, Nguyen KL (2010) TCF bleaching of Eucalypt kraft pulp with oxone. Appita J 63:381–386

Zhao H, Kwak JH, Wang Y, Franz JA, White JM, Holladay JE (2006) Effects of crystallinity on dilute acid hydrolysis of cellulose by cellulose ball-milling study. Energy Fuels 20(2):807–811CrossRef

Zhu S, Wu Y, Chen Q et al (2006) Dissolution of cellulose with ionic liquids and its application: a mini-review. Green Chem 8:325–327. https://doi.org/10.1039/b601395c CrossRef

Titel: Technical and environmental improvement of the bleaching sequence of dissolving pulp for fibre production
verfasst von: Carlos Arce
Tamara Llano
Pablo García
Alberto Coz
Publikationsdatum: 21.02.2020
Verlag: Springer Netherlands
Erschienen in: Cellulose / Ausgabe 7/2020
Print ISSN: 0969-0239
Elektronische ISSN: 1572-882X
DOI: https://doi.org/10.1007/s10570-020-03065-1

Springer Professional

Abstract

Bitte loggen Sie sich ein, um Zugang zu Ihrer Lizenz zu erhalten.

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Technik"

Springer Professional "Wirtschaft+Technik"

Weitere Artikel der Ausgabe 7/2020

Hydrophobic and flame-retardant finishing of cotton fabrics for water–oil separation

The synergy between cellulose nanofibrils and calcium carbonate in a hybrid composite system

Chitosan-modified nitrocellulose membrane for paper-based point-of-care testing

The use of aminated cotton fibers as an unconventional sorbent to remove anionic dyes from aqueous solutions

Carbonization of electrospun polyacrylonitrile (PAN)/cellulose nanofibril (CNF) hybrid membranes and its mechanism

Carboxymethyl cellulose structured nano-adsorbent for removal of methyl violet from aqueous solution: isotherm and kinetic analyses