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2019 | OriginalPaper | Buchkapitel

TGA-DSC-MS Analysis of Pyrolysis Process of Various Biomasses with Isoconversional (Model-Free) Kinetics

verfasst von : Nebojsa Manic, Bojan Jankovic, Dragoslava Stojiljkovic, Vladimir Jovanovic

Erschienen in: Experimental and Numerical Investigations in Materials Science and Engineering

Verlag: Springer International Publishing

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Abstract

Slow pyrolysis characteristics of different biomasses (hazelnut shell (HS), sawdust (Beech), and sawdust chemically treated (SDCT)) were investigated by simultaneous thermal analysis (STA), coupled with mass spectrometry (MS). Thermal decomposition of these samples was divided into three stages corresponding to removal of water, devolatilization, and formation of bio-char. It was found that differences in thermal behavior of the samples are due to differences in their composition. Mass spectrometry results showed that H₂, CH₄, H₂O, CO₂ (C₃H₈), CO, and C₂H₆ were the main gaseous products released during pyrolysis. It was shown that HS could be a good fuel, since during its pyrolysis at high temperature, more gaseous products are released compared to other systems. Isoconversional (model-free) method was used in order to determine variation magnitudes of effective activation energy (E_a) values on conversion fraction (α) during pyrolysis. It was found that identified variations of E_a with α arise from the different chemical structures among cellulose, hemicelluloses and lignin in tested samples that may affect on their effective activation energies.

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Vorheriges Kapitel Thermal and Mechanical Characteristics of Dual Cure Self-etching, Self-adhesive Resin Based Cement

Nächstes Kapitel Thermal Energy Storage of Composite Materials Based on Clay, Stearic Acid, Paraffin and Glauber’s Salt as Phase Change Materials

Ohlström, M., Mäkinen, T., Laurikko, J., Pipatti, R.: New concepts for biofuels in transportation: biomass-based methanol production and reduced emissions in advanced vehicles. VTT Research Note 3-94, VTT (Technical Research Centre of Finland) Energy, Espoo (2001)

Saxena, R.C., Adhikari, D.K., Goyal, H.B.: Biomass-based energy fuel through biochemical routes: a review. Renew. Sustain. Energy Rev. 13, 167–178 (2009). https://doi.org/10.1016/j.rser.2007.07.011CrossRef

Maniatis, K.: Progress in biomass gasification: an overview. Prog. Thermochem. Biomass Convers. (2001). https://doi.org/10.1002/9780470694954.ch1CrossRef

Faaij, A.: Modern biomass conversion technologies. Mitig. Adapt. Strateg. Glob. Chang. 11, 343–375 (2006). https://doi.org/10.1007/s11027-005-9004-7CrossRef

Anwar, Z., Gulfraz, M., Irshad, M.: Agro-industrial lignocellulosic biomass a key to unlock the future bio-energy: a brief review. J. Radiat. Res. Appl. Sci. 7, 163–173 (2014). https://doi.org/10.1016/j.jrras.2014.02.003CrossRef

Garcia-Perez, M., Lewis, T., Kruger, C.E.: Methods for producing biochar and advanced biofuels in Washington State, Part 1: Literature review of pyrolysis reactors. First project report, Department of Biological Systems Engineering and the Center for Sustaining Agriculture and Natural Resources Washington State University, Pullman (2010)

Czajczyńska, D., Anguilano, L., Ghazal, H., Krzyżyńska, R., Reynolds, A.J., Spencer, N., Jouhara, H.: Potential of pyrolysis processes in the waste management sector. Therm. Sci. Eng. Prog. 3, 171–197 (2017). https://doi.org/10.1016/j.tsep.2017.06.003CrossRef

Jayaraman, K., Gökalp, I.: Pyrolysis, combustion and gasification characteristics of miscanthus and sewage sludge. Energy Convers. Manag. 89, 83–91 (2015). https://doi.org/10.1016/j.enconman.2014.09.058CrossRef

Alipour Moghadam, R., Yusup, S., Azlina, W., Nehzati, S., Tavasoli, A.: Investigation on syngas production via biomass conversion through the integration of pyrolysis and air-steam gasification processes. Energy Convers. Manag. 87, 670–675 (2014). https://doi.org/10.1016/j.enconman.2014.07.065CrossRef

10.

Dhaundiyal, A., Singh, S.B., Hanon, M.M., Rawat, R.: Determination of kinetic parameters for the thermal decomposition of Parthenium hysterophorus. Environ. Clim. Technol. 22(1), 5–21 (2018)CrossRef

11.

Wang, L., Lei, H., Liu, J., Bu, Q.: Thermal decomposition behavior and kinetics for pyrolysis and catalytic pyrolysis of Douglas fir. RSC Adv. 8, 2196–2202 (2018). https://doi.org/10.1039/C7RA12187CCrossRef

12.

Janković, B., Marinović-Cincović, M., Janković, M.: TG-DTA-FTIR analysis and isoconversional reaction profiles for thermal and thermo-oxidative degradation processes in black chokeberry (Aronia melanocarpa). Chem. Pap. 70(8), 1094–1105 (2016). https://doi.org/10.1515/chempap-2016-0046CrossRef

13.

Janković, B.: The comparative kinetic analysis of Acetocell and Lignoboost^® lignin pyrolysis: the estimation of the distributed reactivity models. Bioresour. Technol. 102(20), 9763–9771 (2011). https://doi.org/10.1016/j.biortech.2011.07.080CrossRef

14.

Várhegyi, G., Antal, M.J., Jakab, E., Szabó, P.: Kinetic modeling of biomass pyrolysis. J. Anal. Appl. Pyrolysis 42, 73–87 (1997). https://doi.org/10.1016/s0165-2370(96)00971-0CrossRef

15.

EN ISO 14780:2017: Solid biofuels – sample preparation. European Committee for Standardization (CEN), Brussels (2017)

16.

EN ISO 18134:2015: Solid biofuels – determination of moisture content – oven dry method – Part 1: Total moisture – reference method. European Committee for Standardization (CEN), Brussels (2015)

17.

EN ISO 16948:2015: Solid biofuels – determination of total content of carbon, hydrogen and nitrogen. European Committee for Standardization (CEN), Brussels (2015)

18.

EN ISO 17225-1:2014: Solid biofuels – fuel specifications and classes – Part 1: General requirements. European Committee for Standardization (CEN), Brussels (2015)

19.

EN ISO 18125:2017: Solid biofuels – determination of calorific value. European Committee for Standardization (CEN), Brussels (2015)

20.

Grǿnli, M.G., Várhegyi, G., Di Blasi, C.: Thermogravimetric analysis and devolatilization kinetics of wood. Ind. Eng. Chem. Res. 41(17), 4201–4208 (2002)CrossRef

21.

Hu, M., Wang, X., Chen, J., Yang, P., Liu, C., Xiao, B., Guo, D.: Kinetic study and syngas production from pyrolysis of forestry waste. Energy Convers. Manag. 135, 453–462 (2017). https://doi.org/10.1016/j.enconman.2016.12.086CrossRef

22.

Martín-Lara, M.A., Blázquez, G., Ronda, A., Calero, M.: Kinetic study of the pyrolysis of pine cone shell through non-isothermal thermogravimetry: effect of heavy metals incorporated by biosorption. Renew. Energy 96, 613–624 (2016). https://doi.org/10.1016/j.renene.2016.05.026CrossRef

23.

Kissinger, H.E.: Reaction kinetics in differential thermal analysis. Anal. Chem. 29, 1702–1706 (1957). https://doi.org/10.1021/ac60131a045CrossRef

24.

Akahira, T., Sunose, T.: Method of determining activation deterioration constant of electrical insulating materials. Res. Rep. Chiba Inst. Technol. (Sci. Technol.) 16, 22–31 (1971)

25.

Friedman, H.L.: Kinetics of thermal degradation of char-forming plastics from thermogravimetry. Application to a phenolic plastic. J. Polym. Sci. Part C Polym. Symp. 6, 183–195 (2007). https://doi.org/10.1002/polc.5070060121

26.

Venkatesh, M., Ravi, P., Tewari, S.P.: Isoconversional kinetic analysis of decomposition of nitroimidazoles: Friedman method vs Flynn–Wall–Ozawa Method. J. Phys. Chem. A 117(40), 10162–10169 (2013). https://doi.org/10.1021/jp407526rCrossRef

27.

Demirbas, A.: Hydrogen from mosses and algae via pyrolysis and steam gasification. Energy Sources Part A Recover. Util. Environ. Eff. 32, 172–179 (2009). https://doi.org/10.1080/15567030802464388CrossRef

28.

Mohan, D., Pittman, C.U., Steele, P.H.: Pyrolysis of wood/biomass for bio-oil: a critical review. Energy Fuels 20, 848–889 (2006). https://doi.org/10.1021/ef0502397CrossRef

29.

Hellier, P., Talibi, M., Eveleigh, A., Ladommatos, N.: An overview of the effects of fuel molecular structure on the combustion and emissions characteristics of compression ignition engines. Proc. Inst. Mech. Eng. Part D J. Automob. Eng. 232(1), 90–105 (2018). https://doi.org/10.1177/0954407016687453

30.

Song, H., Quinton, K.S., Peng, Z., Zhao, H., Ladommatos, N.: Effects of oxygen content of fuels on combustion and emissions of diesel engines. Energies 9, 28–39 (2016). https://doi.org/10.3390/en9010028CrossRef

31.

McKendry, P.: Energy production from biomass (part 1): overview of biomass. Bioresour. Technol. 83, 37–46 (2002). https://doi.org/10.1016/s0960-8524(01)00118-3CrossRef

32.

Ronsse, F., van Hecke, S., Dickinson, D., Prins, W.: Production and characterization of slow pyrolysis biochar: influence of feedstock type and pyrolysis conditions. GCB Bioenergy. 5, 104–115 (2012). https://doi.org/10.1111/gcbb.12018CrossRef

33.

Brownsort, P.A.: Biomass pyrolysis processes: review of scope, control and variability. Edinburgh Biochar Research Centre working paper 5, pp. 1–39, The University of Edinburgh, Newcastle University, Rothamsted Research, December 2009. www.biochar.org.uk

34.

Conesa, J.A., Caballero, J., Marcilla, A., Font, R.: Analysis of different kinetic models in the dynamic pyrolysis of cellulose. Thermochim. Acta 254, 175–192 (1995). https://doi.org/10.1016/0040-6031(94)02102-tCrossRef

35.

Caballero, J.A., Conesa, J.A., Font, R., Marcilla, A.: Pyrolysis kinetics of almond shells and olive stones considering their organic fractions. J. Anal. Appl. Pyrolysis 42, 159–175 (1997). https://doi.org/10.1016/s0165-2370(97)00015-6CrossRef

36.

Janković, B.: Kinetic and reactivity distribution behaviors during curing process of carbon/epoxy composite with thermoplastic interface coatings (T800/3900–2 prepreg) under the nonisothermal conditions. Polym. Compos. 39(1), 201–220 (2018). https://doi.org/10.1002/pc.23920CrossRef

37.

Yang, H., Yan, R., Chen, H., Lee, D.H., Zheng, C.: Characteristics of hemicellulose, cellulose and lignin pyrolysis. Fuel 86, 1781–1788 (2007). https://doi.org/10.1016/j.fuel.2006.12.013CrossRef

38.

Sonobe, T., Pipatmanomai, S., Worasuwannarak, N.: Pyrolysis characteristics of Thai-agricultural residues of rice straw, rice husk, and corncob by TG-MS technique and kinetic analysis. In: Proceedings of 2nd Joint International Conference on Sustainable Energy and Environment (SEE 2006), 21–23 Nov 2006, Bangkok, Thailand, C-044, pp. 1–6 (2006)

39.

Domingues, R.R., Trugilho, P.F., Silva, C.A., de Melo, I.C.N.A., Melo, L.C.A., Magriotis, Z.M., Sánchez-Monedero, M.A.: Properties of biochar derived from wood and high-nutrient biomasses with the aim of agronomic and environmental benefits. PLoS ONE 12(5), e0176884 (2017). https://doi.org/10.1371/journal.pone.0176884CrossRef

40.

Gómez, C.J., Mészáros, E., Jakab, E., Velo, E., Puigjaner, L.: Thermogravimetry/mass spectrometry study of woody residues and an herbaceous biomass crop using PCA techniques. J. Anal. Appl. Pyrolysis 80, 416–426 (2007). https://doi.org/10.1016/j.jaap.2007.05.003CrossRef

41.

Janković, B.: Estimation of the distribution of reactivity for powdered cellulose pyrolysis in isothermal experimental conditions using the Bayesian inference. Cellulose 22(4), 2283–2303 (2015). https://doi.org/10.1007/s10570-015-0653-8CrossRef

42.

Özveren, U., Özdoğan, Z.S.: Investigation of the slow pyrolysis kinetics of olive oil pomace using thermo-gravimetric analysis coupled with mass spectrometry. Biomass Bioenerg. 58, 168–179 (2013). https://doi.org/10.1016/j.biombioe.2013.08.011CrossRef

43.

Jakab, E., Faix, O., Till, F.: Thermal decomposition of milled wood lignins studied by thermogravimetry/mass spectrometry. J. Anal. Appl. Pyrolysis 40–41, 171–186 (1997). https://doi.org/10.1016/s0165-2370(97)00046-6CrossRef

44.

Lin, Y.-C., Cho, J., Tompsett, G.A., Westmoreland, P.R., Huber, G.W.: Kinetics and mechanism of cellulose pyrolysis. J. Phys. Chem. C 113, 20097–20107 (2009). https://doi.org/10.1021/jp906702pCrossRef

45.

Antal, M.J., Várhegyi, G., Jakab, E.: Cellulose pyrolysis kinetics: revisited. Ind. Eng. Chem. Res. 37, 1267–1275 (1998). https://doi.org/10.1021/ie970144vCrossRef

46.

Janković, B.: The pyrolysis process of wood biomass samples under isothermal experimental conditions—energy density considerations: application of the distributed apparent activation energy model with a mixture of distribution functions. Cellulose 21(4), 2285–2314 (2014). https://doi.org/10.1007/s10570-014-0263-xCrossRef

47.

Orfão, J.J.M., Antunes, F.J.A., Figueiredo, J.L.: Pyrolysis kinetics of lignocellulosic materials—three independent reactions model. Fuel 78, 349–358 (1999). https://doi.org/10.1016/s0016-2361(98)00156-2CrossRef

48.

Grønli, M.G., Várhegyi, G., Di Blasi, C.: Thermogravimetric analysis and devolatilization kinetics of wood. Ind. Eng. Chem. Res. 41, 4201–4208 (2002). https://doi.org/10.1021/ie0201157CrossRef

Titel: TGA-DSC-MS Analysis of Pyrolysis Process of Various Biomasses with Isoconversional (Model-Free) Kinetics
verfasst von: Nebojsa Manic
Bojan Jankovic
Dragoslava Stojiljkovic
Vladimir Jovanovic
Verlag: Springer International Publishing
Buch: Experimental and Numerical Investigations in Materials Science and Engineering
Print ISBN: 978-3-319-99619-6

Electronic ISBN: 978-3-319-99620-2

Copyright-Jahr: 2019
DOI: https://doi.org/10.1007/978-3-319-99620-2_2

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