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2018 | OriginalPaper | Buchkapitel

10. The Application of Computational Thermodynamics to the Cathode-Electrolyte in Solid Oxide Fuel Cells

verfasst von : Shadi Darvish, Mohammad Asadikiya, Mei Yang, Yu Zhong

Erschienen in: Nanostructured Materials for Next-Generation Energy Storage and Conversion

Verlag: Springer Berlin Heidelberg

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Abstract

The fundamentals of solid oxide fuel cell (SOFC) and computational thermodynamics, using the CALPHAD (CALculation of PHAse Diagrams) approach, are reviewed in this chapter. The thermodynamic database development for perovskites and fluorites is especially discussed. In addition, the application of computational thermodynamics to the cathode and electrolyte of SOFC is also discussed in detail including the defect chemistry and quantitative Brouwer diagrams, electronic and ionic conductivity, cathode-electrolyte triple phase boundary (TPB) stability, thermomechanical properties of perovskite cathode, the effect of gas impurities like CO₂ to the phase stability of cathode, and phase diagram development for nano (n-)yttria-stabilized zirconia (YSZ) particles.

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Titel: The Application of Computational Thermodynamics to the Cathode-Electrolyte in Solid Oxide Fuel Cells
verfasst von: Shadi Darvish
Mohammad Asadikiya
Mei Yang
Yu Zhong
Verlag: Springer Berlin Heidelberg
Buch: Nanostructured Materials for Next-Generation Energy Storage and Conversion
Print ISBN: 978-3-662-56363-2

Electronic ISBN: 978-3-662-56364-9

Copyright-Jahr: 2018
DOI: https://doi.org/10.1007/978-3-662-56364-9_10

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