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Erschienen in: Journal of Materials Science 14/2021

05.01.2021 | Metals & corrosion

The high-temperature oxidation resistance properties of magnesium alloys alloyed with Gd and Ca

verfasst von: Jiajia Wu, Yuan Yuan, Xiaowen Yu, Tao Chen, Dajian Li, Liang Wu, Bin Jiang, Andrej Atrens, Fusheng Pan

Erschienen in: Journal of Materials Science | Ausgabe 14/2021

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Abstract

This work studied the high-temperature oxidation resistance properties of Mg alloys with Gd and Ca. The oxidation property of Mg-3.5Gd-xCa (x = 0, 0.5, 1.0 and 3.0 wt%) alloys followed parabolic oxidation kinetics at 500 °C. A stable oxide film was formed on the alloy surface and limited further oxidation. The oxide film was composed of Gd2O3, MgO and MgCO3 for Mg-3.5Gd and was mainly CaO and CaCO3 with increasing Ca content for Mg-3.5Gd-xCa alloys. The high oxidation affinity of Ca caused it to be oxidized preferentially and the fast diffusion of Ca in Mg alloys provided a source for the continuous oxidation of Ca at the surface. The parabolic rate constant, grains size and surface roughness of the oxide film increased with the increasing Ca content in Mg-3.5Gd-xCa alloy. The understanding of multi-element alloying on the oxidation behavior of Mg alloy is helpful for the design of multi-element oxidation-resistant Mg alloys.

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Metadaten
Titel
The high-temperature oxidation resistance properties of magnesium alloys alloyed with Gd and Ca
verfasst von
Jiajia Wu
Yuan Yuan
Xiaowen Yu
Tao Chen
Dajian Li
Liang Wu
Bin Jiang
Andrej Atrens
Fusheng Pan
Publikationsdatum
05.01.2021
Verlag
Springer US
Erschienen in
Journal of Materials Science / Ausgabe 14/2021
Print ISSN: 0022-2461
Elektronische ISSN: 1573-4803
DOI
https://doi.org/10.1007/s10853-020-05758-1

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