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01.06.2020 | ORIGINAL PAPER

The impact of acetylation on physical and electrochemical characteristics of cellulose-based quasi-solid polymer electrolytes

verfasst von: Muhammad Hazwan Ahmad, Vidhya Selvanathan, Ahmad Danial Azzahari, Faridah Sonsudin, Nurshafiza Shahabudin, Rosiyah Yahya

Erschienen in: Journal of Polymer Research | Ausgabe 6/2020

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Abstract

Cellulose is widely appreciated amongst polymer scientists as the most abundant and cost-effective natural polysaccharide. Nonetheless, the non-dissolving property of cellulose has narrowed its potential from a broader range of applications. Hence, modification has to be made in order to improve its solubility. In this study, a simple, robust and rapid transesterification method using vinyl acetate was carried out by acetylating microcrystalline cellulose (MCC) to obtain cellulose acetate (CA). The solubility test showed an improvement of organosolubility for the modified cellulose. Series of CA powders at five different degrees of substitution (DS) were prepared by varying the composition of cellulose to vinyl acetate molar ratios. Successful acetylation of cellulose was confirmed through Fourier transform infrared (FTIR) and proton nuclear magnetic resonance (¹H NMR) spectroscopies. Physicochemical traits were studied by using X-ray diffraction (XRD) and thermogravimetric analysis (TGA). XRD and TGA measurements revealed that CA powders of different DS were less crystalline and more thermally stable than its native form. The CA powders were turned into quasi-solid polymer electrolytes (PEs) and the highest ionic conductivity reported in this study was 7.31 × 10⁻³ S cm⁻¹ with incorporation of 20 wt.% sodium iodide (NaI) salt. Rheology study was carried out to investigate the mechanical strength of the gels. Quasi-solid PEs were prepared for potential dye-sensitized solar cells (DSSCs) application.

Vorheriger Artikel Study on electrochemical properties of CMC-PVA doped NH4Br based solid polymer electrolytes system as application for EDLC

Nächster Artikel Synthesis of poly (hexamethylene terephthalamide)-co-polycaprolactam/modified montmorillonite nanocomposites with enhanced mechanical properties and lower water absorption rate by in-situ polymerization

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Ramesh S, Shanti R, Morris E (2013) Characterization of conducting cellulose acetate based polymer electrolytes doped with “green” ionic mixture. Carbohydr Polym 91(1):14–21. https://doi.org/10.1016/j.carbpol.2012.07.061 CrossRefPubMed

Das AM, Ali AA, Hazarika MP (2014) Synthesis and characterization of cellulose acetate from rice husk: eco-friendly condition. Carbohydr Polym 112:342–349. https://doi.org/10.1016/j.carbpol.2014.06.006 CrossRefPubMed

Chen YW, Lee HV, Juan JC, Phang S-M (2016) Production of new cellulose nanomaterial from red algae marine biomass Gelidium elegans. Carbohydr Polym 151:1210–1219. https://doi.org/10.1016/j.carbpol.2016.06.083 CrossRefPubMed

Mohammadkazemi F, Azin M, Ashori A (2015) Production of bacterial cellulose using different carbon sources and culture media. Carbohydr Polym 117:518–523. https://doi.org/10.1016/j.carbpol.2014.10.008 CrossRefPubMed

Dorez G, Ferry L, Sonnier R, Taguet A, Lopez-Cuesta JM (2014) Effect of cellulose, hemicellulose and lignin contents on pyrolysis and combustion of natural fibers. J Anal Appl Pyrolysis 107:323–331. https://doi.org/10.1016/j.jaap.2014.03.017 CrossRef

Stefanidis SD, Kalogiannis KG, Iliopoulou EF, Michailof CM, Pilavachi PA, Lappas AA (2014) A study of lignocellulosic biomass pyrolysis via the pyrolysis of cellulose, hemicellulose and lignin. J Anal Appl Pyrolysis 105:143–150. https://doi.org/10.1016/j.jaap.2013.10.013 CrossRef

Cao X, Sun S, Peng X, Zhong L, Sun R, Jiang D (2013) Rapid Synthesis of Cellulose Esters by Transesterification of Cellulose with Vinyl Esters under the Catalysis of NaOH or KOH in DMSO, vol 61. doi:https://doi.org/10.1021/jf3055104

Tian D, Han Y, Lu C, Zhang X, Yuan G (2014) Acidic ionic liquid as “quasi-homogeneous” catalyst for controllable synthesis of cellulose acetate. Carbohydr Polym 113:83–90. https://doi.org/10.1016/j.carbpol.2014.07.005 CrossRefPubMed

Jogunola O, Eta V, Hedenström M, Sundman O, Salmi T, Mikkola J-P (2016) Ionic liquid mediated technology for synthesis of cellulose acetates using different co-solvents. Carbohydr Polym 135:341–348. https://doi.org/10.1016/j.carbpol.2015.08.092 CrossRefPubMed

10.

Isik M, Sardon H, Mecerreyes D (2014) Ionic liquids and cellulose: dissolution, chemical modification and preparation of new cellulosic materials. Int J Mol Sci 15(7):11922–11940. https://doi.org/10.3390/ijms150711922 CrossRefPubMedPubMedCentral

11.

Mondal MIH, Yeasmin MS, Rahman MS (2015) Preparation of food grade carboxymethyl cellulose from corn husk agrowaste. Int J Biol Macromol 79:144–150. https://doi.org/10.1016/j.ijbiomac.2015.04.061 CrossRefPubMed

12.

Abdel-Halim ES (2014) Chemical modification of cellulose extracted from sugarcane bagasse: preparation of hydroxyethyl cellulose. Arab J Chem 7(3):362–371. https://doi.org/10.1016/j.arabjc.2013.05.006 CrossRef

13.

Shanks RA (2015) 18 - isolation and application of cellulosic fibres in composites. In: Faruk O, Sain M (eds) Biofiber Reinforcements in Composite Materials. Woodhead Publishing, pp 553–570. https://doi.org/10.1533/9781782421276.5.553

14.

Aoki D, Teramoto Y, Nishio Y (2007) SH-containing cellulose acetate derivatives: preparation and characterization as a shape memory-recovery material. Biomacromolecules 8(12):3749–3757CrossRef

15.

Rodríguez FJ, Galotto MJ, Guarda A, Bruna JE (2012) Modification of cellulose acetate films using nanofillers based on organoclays. J Food Eng 110(2):262–268CrossRef

16.

Law RC 5. Applications of cellulose acetate 5.1 Cellulose acetate in textile application. In: Macromolecular Symposia, 2004. vol 1. Wiley Online Library, pp 255–266

17.

Candido RG, Godoy GG, Gonçalves AR (2017) Characterization and application of cellulose acetate synthesized from sugarcane bagasse. Carbohydr Polym 167:280–289. https://doi.org/10.1016/j.carbpol.2017.03.057 CrossRefPubMed

18.

Pang J, Liu X, Yang J, Lu F, Wang B, Xu F, Ma M, Zhang X (2016) Synthesis of highly polymerized water-soluble cellulose acetate by the side reaction in carboxylate ionic liquid 1-ethyl-3-methylimidazolium acetate. Sci Rep 6:33725. https://doi.org/10.1038/srep33725 CrossRefPubMed

19.

Cao J, Sun X, Lu C, Zhou Z, Zhang X, Yuan G (2016) Water-soluble cellulose acetate from waste cotton fabrics and the aqueous processing of all-cellulose composites. Carbohydr Polym 149:60–67. https://doi.org/10.1016/j.carbpol.2016.04.086 CrossRefPubMed

20.

Chen C-Y, Chen M-J, Zhang X-Q, Liu C-F, Sun R-C (2014) Per-O-acetylation of cellulose in dimethyl sulfoxide with catalyzed transesterification. J Agric Food Chem 62(15):3446–3452CrossRef

21.

Çetin NS, Tingaut P, Özmen N, Henry N, Harper D, Dadmun M, Sèbe G (2009) Acetylation of cellulose Nanowhiskers with vinyl acetate under moderate conditions. Macromol Biosci 9(10):997–1003. https://doi.org/10.1002/mabi.200900073 CrossRefPubMed

22.

Cao N, Yang X, Fu Y (2009) Effects of various plasticizers on mechanical and water vapor barrier properties of gelatin films. Food Hydrocoll 23(3):729–735. https://doi.org/10.1016/j.foodhyd.2008.07.017 CrossRef

23.

Sharma N, Purkait MK (2017) Impact of synthesized amino alcohol plasticizer on the morphology and hydrophilicity of polysulfone ultrafiltration membrane. J Membr Sci 522:202–215. https://doi.org/10.1016/j.memsci.2016.08.068 CrossRef

24.

Suyatma NE, Tighzert L, Copinet A, Coma V (2005) Effects of hydrophilic plasticizers on mechanical, thermal, and surface properties of chitosan films. J Agric Food Chem 53(10):3950–3957CrossRef

25.

Chen J, Xu J, Wang K, Cao X, Sun R (2016) Cellulose acetate fibers prepared from different raw materials with rapid synthesis method. Carbohydr Polym 137:685–692. https://doi.org/10.1016/j.carbpol.2015.11.034 CrossRefPubMed

26.

Fan G, Liao C, Fang T, Luo S, Song G (2014) Amberlyst 15 as a new and reusable catalyst for the conversion of cellulose into cellulose acetate. Carbohydr Polym 112:203–209CrossRef

27.

Ass BAP, Frollini E, Heinze T (2004) Studies on the homogeneous acetylation of cellulose in the novel solvent dimethyl Sulfoxide/Tetrabutylammonium fluoride Trihydrate. Macromol Biosci 4:1008–1013. https://doi.org/10.1002/mabi.200400088 CrossRefPubMed

28.

Clough MT, Geyer K, Hunt PA, Son S, Vagt U, Welton T (2015) Ionic liquids: not always innocent solvents for cellulose. Green Chem 17(1):231–243CrossRef

29.

Roy D, Semsarilar M, Guthrie JT, Perrier S (2009) Cellulose modification by polymer grafting: a review. Chem Soc Rev 38(7):2046–2064CrossRef

30.

Lindman B, Karlström G, Stigsson L (2010) On the mechanism of dissolution of cellulose. J Mol Liq 156(1):76–81. https://doi.org/10.1016/j.molliq.2010.04.016 CrossRef

31.

Rodrigues Filho G, Monteiro DS, Meireles CS, de Assunção RMN, Cerqueira DA, Barud HS, Ribeiro SJL, Messadeq Y (2008) Synthesis and characterization of cellulose acetate produced from recycled newspaper. Carbohydr Polym 73(1):74–82. https://doi.org/10.1016/j.carbpol.2007.11.010 CrossRef

32.

Fan G, Wang M, Liao C, Fang T, Li J, Zhou R (2013) Isolation of cellulose from rice straw and its conversion into cellulose acetate catalyzed by phosphotungstic acid. Carbohydr Polym 94(1):71–76. https://doi.org/10.1016/j.carbpol.2013.01.073 CrossRefPubMed

33.

Candido RG, Gonçalves AR (2016) Synthesis of cellulose acetate and carboxymethylcellulose from sugarcane straw. Carbohydr Polym 152:679–686. https://doi.org/10.1016/j.carbpol.2016.07.071 CrossRefPubMed

34.

Cheng H, Dowd MK, Selling G, Biswas A (2010) Synthesis of cellulose acetate from cotton byproducts. Carbohydr Polym 80(2):449–452CrossRef

35.

Li Q, Renneckar S (2011) Supramolecular structure characterization of molecularly thin cellulose I nanoparticles. Biomacromolecules 12(3):650–659CrossRef

36.

Wan Daud WR, Djuned FM (2015) Cellulose acetate from oil palm empty fruit bunch via a one step heterogeneous acetylation. Carbohydr Polym 132:252–260. https://doi.org/10.1016/j.carbpol.2015.06.011 CrossRefPubMed

37.

Nishino T, Kotera M, Suetsugu M, Murakami H, Urushihara Y (2011) Acetylation of plant cellulose fiber in supercritical carbon dioxide. Polymer 52(3):830–836CrossRef

38.

Shaikh HM, Pandare KV, Nair G, Varma AJ (2009) Utilization of sugarcane bagasse cellulose for producing cellulose acetates: novel use of residual hemicellulose as plasticizer. Carbohydr Polym 76(1):23–29. https://doi.org/10.1016/j.carbpol.2008.09.014 CrossRef

39.

Cao X, Peng X, Zhong L, Sun S, Yang D, Zhang X, Sun R (2014) A novel transesterification system to rapidly synthesize cellulose aliphatic esters. Cellulose 21(1):581–594CrossRef

40.

Barud HS, de Araújo Júnior AM, Santos DB, de Assunção RM, Meireles CS, Cerqueira DA, Rodrigues Filho G, Ribeiro CA, Messaddeq Y, Ribeiro SJ (2008) Thermal behavior of cellulose acetate produced from homogeneous acetylation of bacterial cellulose. Thermochim Acta 471(1–2):61–69CrossRef

41.

Azzahari AD, Abdul Mutalib NF, Rizwan M, Naceur Abouloula C, Selvanathan V, Sonsudin F, Yahya R (2018) Improved ionic conductivity in guar gum succinate–based polymer electrolyte membrane. High Performance Polymers 30(8):993–1001CrossRef

42.

Jr. REB, Thomas CR (1964) Glass transition and ionic conductivity in cellulose acetate. J Appl Phys 35 (1):87–94. https://doi.org/10.1063/1.1713104

43.

Ramesh S, Liew C-W (2012) Rheological characterizations of ionic liquid-based gel polymer electrolytes and fumed silica-based composite polymer electrolytes. Ceram Int 38(4):3411–3417. https://doi.org/10.1016/j.ceramint.2011.12.053 CrossRef

44.

Selvanathan V, Halim MNA, Azzahari AD, Rizwan M, Shahabudin N, Yahya R (2018) Effect of polar aprotic solvents on hydroxyethyl cellulose-based gel polymer electrolyte. Ionics 24(7):1955–1964CrossRef

45.

Mezger TG (2011) The rheology handbook: for users of rotational and oscillatory Rheometers. Vincentz Network,

46.

Mezger TG (2014) Applied rheology: with Joe flow on rheology road. Anton Paar,

47.

Selvanathan V, Azzahari AD, Halim AAA, Yahya R (2017) Ternary natural deep eutectic solvent (NADES) infused phthaloyl starch as cost efficient quasi-solid gel polymer electrolyte. Carbohydr Polym 167:210–218CrossRef

48.

Ibrahim S, Johan MR (2012) Thermolysis and conductivity studies of poly (ethylene oxide)(PEO) based polymer electrolytes doped with carbon nanotube. Int J Electrochem Sci 7:2596–2615

Titel: The impact of acetylation on physical and electrochemical characteristics of cellulose-based quasi-solid polymer electrolytes
verfasst von: Muhammad Hazwan Ahmad
Vidhya Selvanathan
Ahmad Danial Azzahari
Faridah Sonsudin
Nurshafiza Shahabudin
Rosiyah Yahya
Publikationsdatum: 01.06.2020
Verlag: Springer Netherlands
Erschienen in: Journal of Polymer Research / Ausgabe 6/2020
Print ISSN: 1022-9760
Elektronische ISSN: 1572-8935
DOI: https://doi.org/10.1007/s10965-020-02102-8

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